宽温耐硫变换催化剂制备工艺研究

利用催化剂活性评价、催化剂活性组分含量测定、Ｘ—光衍射等手段，研究了共浸法制备宽温耐硫变换催化剂制备工艺过程中载体氧化铝的吸水率、浸渍条件、煅烧温度等对催化剂性能的影响。     

Catalyst’s Sulfur Displacement by Thiophene, as Monitored by Exchange of 35S Radiotracer

The isotopic exchange has been studied between catalyst radiosulfur and H₂S, formed in thiophene hydrodesulfurization (HDS) (named S-displace) on alumina supported molybdena, on CoMoO_x, PdMoO_x, PtMoO_x and on silica–alumina supported NiWO_x. S-displace was compared with radiosulfur exchange data between catalyst radiosulfur and gas phase H₂S (S^exc) determined previously. The extent of S^exc was higher than that of the S-displace for Mo, CoMo in and NiW, whereas the extent of S-displace from PdMoO and PtMoO was significantly higher, than that of S^exc. Thiophene HDS product distribution data are discussed in terms of increased C=C hydrogenation and C–C hydrogenolysis activity, explained by increasing H₂S production with longer circulation time of the thiophene/H₂ mixture, The C₁/C₃<1 ratios among C₄-hydrogenolysis products indicate some coke formation. The decrease of thiophene HDS activity is presumably a consequence of increasing site-blocking with the formation of more H₂S and coke with longer duration of thiophene treatment.     

球形和圆柱形变换催化剂宏观活性评价新方法

运用“ 催化反应单元” 概念提出了球形私圆柱形变换催化剂的宏观活性评价新方法, 即催化剂分层整齐排列各粒、各层间填充细小惰性颗粒的排列方式和消除了内外扩散影响的反应器结构以这种方法所做的活性评价试验结果置信度高, 其二级反应速率常数k_T有解析解, 可以此作为变换催化剂宏观活性评价标准与催化剂的填充层数无关.     

Biodesulfurization of dibenzothiophene sulfone by Arthrobacter sp. and studies with oxidized Illinois No. 6 coal

A bacterium identified as Arthrobacter sp. was grown on dibenzothiophene (DBT) sulfone as a sole source of sulfur, producing sulfite and sulfate. Sulfur in DBT sulfone (1.0 mM) was nearly quantitatively converted to sulfate by the organism. The organism could also use DBT sulfone as a sole source of carbon and energy. There was evidence for transient accumulation of benzoic acid in the culture medium after growth of the cells slowed. The DBT sulfoxide analogue 9-fluorenone was converted by resting cells to a product identified as 1,10-dihydroxy-1,10-dihydrofluoren-9-one, suggesting that DBT sulfone may be metabolized via an angular hydroxylation resulting in carbon- sulfur bond cleavage. This strain of Arthrobacter showed no ability to desulfurize oxidized Illinois No. 6 coal.     

过磷酸钙喷涂法生产硫基复合肥工艺研究

简述了过磷酸钙喷涂法生产硫基复合肥的反应原理及工艺方案、实施方案的确定。给出了该工艺较传统工艺的优势及特点。     

抗地震结构的服役费用函数及其建立方法

讨论了服役工程结构的经济性问题 ,包括 :抗地震结构在服役过程中为完成预定功能所需要的经济花费、这些花费同结构抗震可靠度的函数关系以及它们的建立方法。形成的服役费用函数可以作为决策结构最佳抗震设防标准的依据。     

改进行移编码的文本数字水印算法研究

研究了文本数字水印在追溯涉密纸质文档中的重要意义,介绍了常见的文本数字水印技术,分析了Brassil经典行移编码文本数字水印技术,在算法的标记策略中引入检验编码,文本行分割划段和引入基调行三个方面进行改进,改进后算法具有更大水印信息容量,更强的鲁棒性和可控的计算量.     

Corrosion-resistant lightweight metallic bipolar plates for PEM fuel cells

Corrosion resistant treated metal bipolar plates with higher rigidity and electrical conductivity than graphite were developed and tested for PEM fuel cell applications. Six replicas of single cells were used three of which were made of graphite composites bipolar plates and the other three of the treated metallic plates. A Membrane Electrode Assembly (MEA) with 5.55 cm² active electrode areas, 0.3 mg cm^–2 Pt loading and Nafion membrane 115 was fitted to each cell and operated under identical conditions. The experimental testing was conducted at room temperature (20 °C). The average value of the data obtained for the three graphite cells was plotted. Similarly, the average value of the data obtained for the three treated metal cells was plotted on the same graph for comparison. Generally, the treated metal bipolar plate provided at least 12% saving in hydrogen consumption in comparison to graphite. This is attributed to the lower bulk and surface contact resistance of the metal used in this study in relation to graphite. The results of lifetime testing, conducted at room temperature under variable loading showed no indication of power degradation due to metal corrosion for at least 1500 hours.     

耐水性木材用脲醛粘合剂的研究

研究了改进胶合板用脲醛粘合剂的耐水性的方法。针对脲醛粘合剂耐水性低的原因,提出在胶液中添加碱性物质——耐水添加剂,可显著改善胶合板的耐水性,几种添加剂并用,胶合板可达一级耐水板的水平。