耐盐性树脂PAA的合成及应用研究

以丙烯酸-丙烯酰胺为单体，过硫酸钾为引发剂，N，N-亚甲基双丙烯酰胺为交联剂。水浴阶梯升温共聚合成耐盐性树脂，采用正交试验通过分析，研究了主要因素对产物性能的影响，确定较佳反应条件：T=50℃(2h)～65℃(3h)，单体配比nAM：nAA=1：11，单体中和度[N]=90％～95％。引发剂浓度[I]=0．3％，单体浓度[M]=30％～35％，交联剂浓度[C]=0．025％～0．03％，并将此树脂作为缓释剂应用于固载二氧化氯中，取得了良好的效果。     

Effect of Pt Incorporation into Ni/ZrO2–SO 4 = /Al2O3 Catalyst for n-Butane Isomerization

Three Ni/ZrO₂–SO₄⁼/Al₂O₃ catalysts with different concentrations of platinum (0.2, 0.3 and 0.4 wt%) were prepare and tested for n-butane isomerization reaction at 338 K, in absence and in presence of hydrogen. The results shown that, at low temperature, platinum contributes to the olefin or butyl ion formation and the reaction follows a bimolecular pathway. However, when the reaction occurs in the presence of hydrogen, the formation of butyl ions is inhibited. The main feature of platinum addition is the stabilization of the catalytic activity, which is indicated by the slow deactivation constants compared to that of the unpromoted catalyst.     

聚己二酸1,2-环己二醇酯的合成

采用正交实验方法,分别以钛酸四丁酯和对甲苯磺酸为催化剂,合成了聚己二酸1,2 环己二醇酯,对其合成工艺条件进行了研究,得出了最佳工艺条件。并以所得聚酯合成了具有透明度高、硬度大、耐磨、玻璃化温度高等优异性能的聚氨酯材料。     

添加物对ZrO2系快离子导体烧结性能的影响

本文介绍了１３２０℃下，ＣａＯ，Ｙ２Ｏ３等稳定剂，低融物组成及１－６价阳离子化合物对ＺｒＯ２烧结性能的影响并列举出材料的晶型及某些主要性能。     

炭黑填充硬聚氯乙烯的改性

为使聚氯乙烯具有抗静电性能,采用加入具有导电性填料的方法,但加入大量的填料,会使硬聚氯乙烯的冲击性能降低,加工性能变差。本文是在以炭黑为填料的基础上,研究不同的改性剂和加工助剂改进硬聚氯乙烯的效果,结果表明,加入冲击改性剂和加工助剂后,大大增加了硬聚氯乙烯的冲击强度,且加工性能也得到改善,同时由于炭黑具有补强效果,其拉伸强度和弯曲强度在加入改性剂后也能满足使用要求。     

炭分子筛概述

阐述了炭分子筛分离的原理，并分别从其制备原料、制备方法、产品用途等方面综述了近年来炭分子筛的新进展。     

莫达非尼的绿色化学合成

采用[bm im]BF4离子液体作为反应溶剂,以二苯甲硫醇为原料,经醚化、氨解、氧化得到新型提神醒脑药物莫达非尼。讨论了不同的氯乙酸酯和反应温度对醚化反应收率的影响,讨论了不同的二苯甲硫乙酸酯对氨解反应收率的影响,及离子液体的回收使用。研究表明,采用氯乙酸甲酯作为醚化试剂,反应时间4 h,反应温度100℃,二苯甲硫醇∶氯乙酸甲酯=1∶1.5(摩尔比),室温下氨解反应20 h,二苯甲硫乙酰胺收率76%;采用过氧化氢作为氧化试剂,反应时间3 h,反应温度60℃,过氧化氢∶二苯甲硫乙酰胺=1∶1(摩尔比),莫达非尼收率79%,反应总收率可达48%。     

Fluor SOx净化工艺--为俄罗斯绿色环境开发的将SO2转化为元素硫的经济技术

Fluor公司开发的Fluor SO_2净化工艺具有广泛多样的工艺布局,可以通过经济的方式定制脱除烟气中的有害组成。该工艺几乎能去除全部SO_2并减少CO排放。Fluor SO_x净化工艺的主要步骤已在多套工业装置中得到成功的证实。除技术可行、经济合理之外,Fluor SO_x净化工艺不会产生任何有害副产物,也不会遇到与SO_3 有关的腐蚀问题。此外,该工艺生产高纯度可市售的元素硫。论述了Fluor SO_x净化工艺的特征、技术和成本优势、设计和操作的简易性以及实施的便利性。     

The influence of F doping on the activity of PbO2 film electrodes in oxygen evolution reaction

The PbO₂ and F⁻-doped PbO₂ (F-PbO₂) film electrodes have been prepared by an electrodeposition process onto platinum substrate. The changes of their electrochemical activity for oxygen evolution (OE) reaction with accelerated electrolysis time have been studied. The results show that the activity of the electrodes decreases with increasing electrolysis time. This can be attributed to the conductivity variations, which are caused by the decrease of the oxygen vacancy concentration in PbO₂ films during OE. The mechanism of the decrease of the oxygen vacancies has been investigated. For F-PbO₂ film electrodes, though its electrochemical activity is somewhat lower than that of undoped one, its activity stability is much higher in comparison with that of PbO₂. The influence of F⁻ doping on the activity of PbO₂ film electrodes has been also discussed.     

高硫石油焦燃烧固硫基础性研究及工业技术的进展

本文概述了高硫石油焦固硫的基础性研究及工业上的最新进展。