制氢尾气二氧化碳回收装置设计

对制氢尾气二氧化碳的回收装置进行了简捷设计，流程分析，并对换热装置的换热量和传热面积给出了算法和有关数据。     

熔敷金属扩散氢逸出特性研究

采用酒精法测量扩散氢 ,研究了焊条熔敷金属扩散氢含量以及在测氢过程中扩散氢逸出量与逸出时间的关系 (逸出特性 )。研究结果表明 ,熔敷金属扩散氢逸出特性受扩散氢含量、焊道数、熔敷金属化学成分和表面状态等多种因素的影响。熔敷金属扩散氢 (HDo)可以分为快速逸出扩散氢 (HDq)和慢速逸出扩散氢(HDs)两部分     

Z417/Z418蒸汽转化催化剂在镇海炼化公司制氢装置中的应用

介绍了中国石化齐鲁分公司研究院开发的新型烃类蒸汽转化催化剂Z417/Z418的性能以及在镇海炼化股份公司制氢装置上的工业应用结果。应用结果表明：使用Z417/Z418催化剂，催化剂装填密度低。装填量小；原料消耗，能耗低，适于高负荷生产；转化炉出口甲烷含量低，氢纯度高。其应用性能优于Z402/Z405G转化催化剂。     

纳秒级上升时间的高压脉冲群电源

按照IEC 61000-4-4/GB 17626.4—1998的要求，首先应用PSPICE仿真确定电路中各元件的参数值，然后基于拉普拉斯变换用MATLAB求解二阶电路验证各元件参数。在此基础上研制了一台以开关电源作为高压直流电源、以氢闸流管作为主控开关的脉冲群电源。该电源体积小、重量轻、效率高、成本低廉。试验结果表明，其输出信号符合标准要求，可用于快速瞬变脉冲群抗扰度试验。     

负载型金属催化剂上甲醇液相重整制氢研究

研究了Pt,Ru,Ni为活性金属的负载型催化剂上甲醇质量分数为5%的水溶液的液相重整反应。在合适的温度、体积空速下，Pt基催化剂表现出较好的反应性能，甲醇转化率可达99%，H2选择性达98%以上，产物中CO体积分数小于0.01%。Ni/Al2O3催化剂可使甲醇转化率最高达到98%以上，H2选择性随转化率升高而下降，但不低于80%。Ru/Al2O3催化剂上甲醇的转化率最高，可达到98%以上，但其H2选择性随着转化率的升高，从68%快速下降至20%，明显与Pt、Ni基催化剂上的反应机理不同。根据反应条件和产物组成变化，进一步探讨甲醇反应路径，当产物中H2与CH4选择性比值高于2/3时，反应路径以重整制氢为主；当比值低于2/3时，反应路径以甲烷化为主。     

Study of miscibility enhancement in poly(styrene‐co‐4‐vinylphenol)/poly(ethylene oxide) blends by the spin labelling method

The electron spin resonance (ESR) spectra of end‐group spin labelled poly(ethylene oxide) (SLPEO) using 2,2,6,6‐tetramethyl‐piperdine‐1‐oxyl nitroxide and its blends with poly(styrene‐co‐4‐vinylphenol) (STVPhs) of different hydroxyl contents were recorded over a wide temperature range. For a blend of SLPEO and pure polystyrene (PS), the ESR spectrum was composed of a single motion component, indicating that PS was immiscible with PEO. For blends composed of SLPEO and different‐hydroxyl‐content STVPhs, two spectral components with different motion rates were observed over a certain temperature range. The difference between the motion rates should be attributed to micro‐heterogeneity in the blends, with the faster rate corresponding to a nitroxide radical motion trapped in the PEO‐rich domain and the slower rate corresponding to a nitroxide radical motion trapped in the STVPh‐rich domain. Variations in the values of a number of the ESR parameters (T_a, T_d and T_50G) and the apparent activation energy (E_a) with hydroxyl content in the blends indicated that the miscibility of the blends increased with increasing hydrogen‐bonding density due to specific interactions between the hydroxyl groups in STVPh and the ether oxygens in PEO. Copyright © 2004 Society of Chemical Industry     

Estimation of errors of hydrogen standard time scale preservation taking account of systematic frequency changes

Metrological characteristics of active hydrogen frequency standards are investigated on the basis of internal and external comparisons. The stability of random changes and drift of hydrogen frequency standards and also the potential capabilities of time scale preservation with effective consideration of systematic changes in their frequency are demonstrated. __________ Translated from Izmeritel’naya Tekhnika, No. 3. pp. 42–45, March, 2007.     

CO毒化AB5型合金分形特征研究

研究了三种贮氢合金 L a Ni5、L a Ni4 .7Al0 .3、Ml Ni4 .5Al0 .5被 10 0× 10 - 6 CO毒化后的分形特征 ,求出这三种合金在含 10 0× 10 - 6 CO的氢中循环 ,分维分别为 0 .2 5 4 7、0 .170 9、0 .0 72 5。可以较好的解释合金被毒化的宏观现象。     

Photocatalytic degradation of methyl tert‐butyl ether (MTBE) in contaminated water by ZnO nanoparticles

BACKGROUND: Over the past several decades methyl tert‐butyl ether (MTBE) as additive to gasoline, intended to either boost ratings of fuel or to reduce air pollution, has been accepted worldwide. Since MTBE has high water solubility, the occurrence of fuel spills or leaks from underground storage tanks or transferring pipeline has led to the contamination of natural waters. In this study the degradation of aqueous MTBE at relatively high concentrations was investigated by a UV‐visible/ZnO/H₂O₂ photocatalytic process. The effects of important operational parameters such as pH, amount of H₂O₂, catalyst loading and irradiation time were also investigated. Concentration of MTBE and intermediates such as tert‐butyl formate and tert‐butyl alcohol were measured. RESULTS: Time required for complete degradation increased from 20 to 150 min when the initial concentration was increased from 10 to 500 mg L^?1. The first‐order rate constants for degradation of MTBE were estimated to be 0.183–0.022 min^?1 as the concentration increased from 10 to 500 mg L^?1. Study of the overall mineralization monitored by total organic carbon analysis showed that at an initial concentration of 100 mg L^?1 MTBE complete mineralization was obtained after 100 min under UV‐visible/ZnO/H₂O₂ photocatalysis. CONCLUSION: The data presented in this paper clearly indicated that UV‐visible/ZnO/O₂ as an advanced oxidation process provides an efficient treatment alternative for the remediation of MTBE‐contaminated waters. Copyright © 2008 Society of Chemical Industry     

钒-氢反应规律与钒基固溶体贮氢合金开发

钒基固溶体贮氢合金是近年来开发的一种新型高性能贮氢材料。文中介绍了钒—氢反应的基本规律及钒基因溶体贮氢材料的特点，并对钒基因溶体贮氢合金的研究及开发现状进行了综述。