The radiation crosslinking and scission of ethylene-propylene copolymers studied by solid-state nuclear magnetic resonance

Methyl groups from chain scission and H-crosslinks have been identified by solid-state nuclear magnetic resonance in amorphous ethylene-propylene copolymers containing 23 and 36 mole % propylene after γ-irradiation to 10 MGy at 30°C. G (scission) and G (crosslink) values determined from the n.m.r. spectra and by extraction are in agreement, which suggests that the crosslinks are not clustered. This may differ from the situation in polyethylene where there is a substantial crystalline content. G(S). G(X) and the ratio G(S)/G(X) increase with increasing propylene content of the copolymers.     

X射线三轴晶衍射法测量半绝缘GaAs单晶的化学配比

采用X射线三轴晶衍射法,根据As间隙原子对作为过量As在GaAs单晶材料中存在的主要形式的模型,可以无损、高精度测量半绝缘GaAs单晶的化学配比.并探讨了引起晶格变化的原因及其与熔体组分的关系,对于制备高质量GaAs单晶及其光电器件具有重要的意义.     

UV-LIGA深度光刻机平滑衍射技术研究

UV-LIGA深度光刻技术是加工微型机电系统的一项重要的微细加工技术。介绍了一种平滑衍射效应的位错强度叠加原理，它采用了蝇眼积分透镜去平滑衍射，并模拟数值计算了硅片表面的光强分布，最后给出了光刻结果。     

X射线衍射线形Fourier变换

采用计算机辅助实验技术，研究X射线衍射线开在仪器宽化修正过程中Fourier系数变化的规律及其影响，结果表明，只要实测线形接近Gauss 分布，Fourier变换就会导致弯勾效应；Forier变换可引起真实线形的尾部波动及大于实际值的宽化，引入边界条件可予以消除，Kα双线形经过Fourier变换后，Fourier纱数与真实Fourier系数存在着一定的差异。通过真实线形的Fourier变换可以修正。     

Preparation and characterization of organic-inorganic poly(ethylene glycol)/WS2 nanocomposite

Layered nanocomposite PEG/WS₂, intercalating oligomeric poly(ethylene glycol) (PEG6000) into the tungsten disulfide host galleries, was synthesized using the exfoliation-adsorption technique. X-ray diffraction revealed that the intercalated oligomer within the host galleries is in a double-layer arrangement with an interlayer expansion of about 8.8 Å. The optimum conditions were explored to prepare the single-phase product with a composition of Li_0.12(PEG)_1.51WS₂. Thermal analyses suggested that the resulting material shows good thermal stability, with the decomposition of the interacted oligomeric chains within the disulfide galleries occurring at around 258 °C. Despite high conductivity of the host material, those of the PEG/WS₂ nanocomposite were found to be high in the order of 1 × 10⁻² S cm⁻¹ at ambient temperature, resulted from the host guest-host charge transfers.     

金属/聚合物复合材料对中能电子的屏蔽作用研究

运用MULASSIS计算程序模拟计算了不同组成的屏蔽材料对空间辐射环境的屏蔽效果,在此基础上进行屏蔽材料的初步设计,并制备了一系列不同组成的金属/聚合物复合材料,结合中能电子照射的实验结果,讨论了组成对金属/聚合物复合材料的屏蔽效果的影响.研究发现,高原子序数和低原子序数金属混合添加的复合物样品具有较好的屏蔽效果.     

无线随钻测量技术的应用现状与发展趋势

目前,无线随钻测量技术是石油工程技术发展的一个主要方向。详细介绍了无线随钻测量仪器的传输方式、国内外无线随钻测量技术的主要进展和应用现状,指出了国内外无线随钻测量仪器的优缺点和应用范围,分析了无线随钻测量技术的发展趋势,并提出我国应在借鉴国外先进的无线随钻测量技术的基础上,研制具有自主知识产权的无线随钻测量仪器,以加快我国无线随钻测量技术的发展,缩短与国际先进水平的差距。     

Influence of the Preheat Treatment on the Microstructure and Properties of X37CrMoV5-1 Steel

The technological properties of the hot-work tool steels depend on their microstructural quality induced by the production process and the heat treatment. One of the frequently applied methods to improve microstructure is preheat treatment. The treatment of carbonitriding X37CrMoV5-1 steel has been investigated in fluidized bed furnaces. Thickness and phase composition have been conducted using optical microscopy Neophot 32 and scanning microscopy, JEOL 5400, after etching in nital.     

A novel technique to prepare LiNbO3 at low temperature

Fresh niobium hydroxide was first precipitated from NbF₅ solution using an aqueous ammonium hydroxide under basic conditions. Then a simple procedure of mixing lithium and niobium hydroxides together and heating at a low temperature (400 °C) produced pure ultrafine single phase LiNbO₃ (LN). In the literature, this is the lowest temperature so far reported on the formation of LN. The phase content and lattice parameters are determined by X-ray diffraction (XRD). The average particle size and morphology were studied by transmission electron microscopy (TEM).     

Effect of C/Ti ratio on the laser ignited self-propagating high-temperature synthesis reaction of Al-Ti-C system for fabricating TiC/Al composites

TiC/Al composite was successfully synthesized utilizing laser ignited self-propagating high-temperature synthesis (SHS) of Al-C-Ti system with the different C/Ti molar ratio. When the molar ratio of C to Ti is below 1:1 in the starting materials, in addition to fine TiC particulates, a large amount of Al₃Ti phase was found in the composites; however, when the molar ratio of C to Ti is 1:1 in the starting materials, the Al₃Ti phase was almost completely eliminated and the distribution of TiC particulates generally appeared to be more homogeneous throughout the products synthesized.