Processing and oxidation of co-deposited Ni-Al coatings

Electrodeposited Ni matrix/Al microparticles or nanoparticles dispersed composite coatings (termed as EMCCs or ENCCs) are developed from a Ni-based electrolyte bath. The Al microparticles are in a size range of 1 -5 μm and the Al nanoparticles in an average size of 75 nm. The Al content in coatings increases with increase in the particle content in the bath. Particle size effect on the degree of codeposition is not significant. However, codeposition of Al nanoparticles instead of microparticles promotes more homogenous growth of Ni deposits on {111}, {200} and {220} planes. The oxidation at 1 050 ℃ of the as-deposited composite coatings shows that at a comparable Al content, ENCC of Ni-Al exhibits a better oxidation resistance than EMCC of Ni-Al due to the fast formation of an alumina scale during the transient stage of oxidation.     

Oxidation of Hf2SnC and Nb2SnC in Air in the 400–600°C Temperature Range

The oxidation behavior in air of fully dense, predominantly (92+vol.%) single phase, samples of Nb₂SnC and Hf₂SnC was studied in the 400–600°C temperature range. The oxidation products in both cases were SnO, SnO₂ and either Nb₂O₅ or HfO₂. The oxidation is characterized by an initial incubation period, the duration of which decreased with increasing temperatures, followed by a period of near-linear oxidation kinetics. Oxidation at temperatures as low as 400°C for 72 hr resulted in the total disintegration of bulk samples, and their total conversion to oxides. Comparison with published results indicate that the oxidation kinetics of Hf₂SnC are poorer than those of Hf or HfC. Similarly, Nb₂SnC is more prone to oxidation than pure Nb metal.     

Ni-Cr-Mo三元系1358 K等温截面的测定

应用三元扩散偶技术测定了Ni-Cr-Mo三元系1358 K的等温截面,借助电子探针微区成分分析方法分析了Ni-Cr-Mo三元扩散偶的相区成分,并对其相关系进行了研究.测得Ni-Cr-Mo三元扩散偶在1358 K下存在一个中间化合物NiMo,Cr和Mo在扩散偶中形成连续固溶体,Ni和（Cr,Mo）有限固溶,扩散偶中未发现三元中间化合物.实验发现Ni-Cr-Mo三元系1358 K的等温截面存在一个三相区：Ni＋NiMo＋（Cr,Mo）.     

冷却速率对Al-Si-Mg三元合金凝固过程的影响

试验研究了冷却速率对Al-2.06%Si-1.58%Mg三元合金凝固过程的影响.同时通过热力学计算预测了不同冷却条件下Al-2.06%Si-1.58%Mg三元合金的凝固路径和相析出规律.试验及计算结果均表明,改变凝固速率可使Al-2.06%Si-1.58%Mg合金的凝固过程按照不同的路径进行,从而达到控制析出相种类的目的.在低的冷却速率下,相析出规律为:L→L1 Fcc_A1→L1 Fcc_A1 Si→L1 Fcc_A1 Si Mg2Si,而在较高的冷却速率下,相析出规律为:L→L1 Fcc_A1→L1 Fcc_A1 Mg2Si→L1 Fcc_A1 Si Mg2Si.     

Oxidation behavior of temary Fe- 15Cu-5Al and Fe-85Cu-5Al alloys in pure oxygen at 900℃

The oxidation of two two-phase ternary Fe-Cu-Al alloys containing about 5%（mole fraction） aluminium, one Fe-rich and one Cu-rich, has been studied at 900 ℃ in 1~105 Pa pure oxygen. The Fe-rich Fe-15Cu-5Al alloy presents two quasi-parabolic stages, with a large decrease of the parabolic rate constant after about 50min. The presence of 5% Al greatly reduces the oxidation rate of this alloy with respect to a binary Fe-Cu alloy of similar composition by forming an external protective Al203 layer, which is present near the scale/alloy interface. Due to the high stress-growth effect, this thin Al203 layer cannot completely prevent further oxidation of the alloy underneath. On the contrary, the Cu-rich Fe-85Cu-5Al alloy presents a single parabolic stage and forms a thick and porous external scale, coupled to the internal oxidation of Fe and Al. As a result, the oxidation of Cu-rich alloy at 900 ℃ is much faster than that of the Fe-rich alloy.     

Nacl—Bacl2—Srcl2三元熔盐相图的计算

本文运用作者提出的从三个对应的二元系的热力学性质预示三元溶液的热力学性质的新对称几何模型,推导得到三元溶液中三个组元的偏摩尔热力学性质的数学表达式。进而将这一结果应用于NaCl-BaCl_2-SrCl_2三元熔盐相图的计算中,得到此三元系的液相析出面及若干等温截面。计算所得结果与实测结果偏差小于5℃,说明此模型在一些熔盐体系中有较好的适用性。     

不对称性定量化的三元系热力学模型

本文提出了一个由二元系推算三元系热力学性质的新模型，此模型能自动用热力学准则来检查各二元系的对称性，并根据不对称程度来构筑权重函数，由于不需要事先选择不对称组元，消除了计算过程中的人为干扰。此模型的适用范围有所拓宽。     

Nonparametric Bayesian Image Segmentation

Image segmentation algorithms partition the set of pixels of an image into a specific number of different, spatially homogeneous groups. We propose a nonparametric Bayesian model for histogram clustering which automatically determines the number of segments when spatial smoothness constraints on the class assignments are enforced by a Markov Random Field. A Dirichlet process prior controls the level of resolution which corresponds to the number of clusters in data with a unique cluster structure. The resulting posterior is efficiently sampled by a variant of a conjugate-case sampling algorithm for Dirichlet process mixture models. Experimental results are provided for real-world gray value images, synthetic aperture radar images and magnetic resonance imaging data.     

三元硝酸熔盐高温粘度的计算

三元硝酸熔盐是一种重要的传热蓄热介质,粘度物性数据对其在工业中应用非常重要.但是由于硝酸熔盐熔点高,腐蚀性强,测试条件苛刻,粘度测量结果偏差较大,故利用计算方法确定熔盐粘度.本文首先通过大量实验数据拟合了纯物质KNO3,NaNO3和NaNO2的粘度,再利用Arrhenius混合规则确定的经验公式计算三元硝酸熔盐的粘度.与前人实际测量值进行比较.结果发现:利用简单经验公式估算的结果与实际测量值比较接近,表明这种熔盐热物性变化受外界影响较小,可以利用Arrhenius简单混合规则确定熔盐粘度.     

Isochoric (p-π-T) measurements on liquid and gaseous air from 67 to 400 K at pressures to 35 MPa

Comprehensive isochoricp--T measurements have been carried out on liquid and gaseous air along 16 isochores at densities ranging from 2 to 32 mol · dm^–3. The air mixture has a nominal composition of 0.7813 N₂ + 0.2096 O₂ + 0.0092 Ar. Thep--T data cover a temperature range from 67 to 400 K at pressures up to 35 MPa. Comparisons with experimental results from independent sources are presented using a fundamental equation of state based. in part, on thep--T data from this study.