Validity of dynamic electrochemical impedance spectra of some amine corrosion inhibitors in petroleum/water corrosive mixtures by Kramers-Kronig transformation

In our previous works, the corrosion inhibition properties of propylamine (PA), iso-propylamine (i-PA), butylamine (BA), tert-butylamine (t-BA), hexylamine (HA), ethylenediamine (EDA), diethanolamine (DEA), 3-amino-1-propanol (3-AP), 2-dimethylethanolamine (2-DEA), cyclohexylamine (CHA), N-methylcyclohexylamine (N-MCA) and dicyclohexylamine (DCHA) have been investigated by means of electrochemical impedance spectroscopy (EIS) with a carbon steel rotating disc electrode in some petroleum/water corrosive mixtures containing acetic acid and NaCl at 25 °C. In this work, the Kramers-Kronig transformations (KKTs) were applied to evaluate the validity of the impedance data of these amine compounds in hydrodynamic condition. The results obtained showed that experimental impedance data did not satisfy in K-K relations completely viz. indicated some errors. These errors were related to stray capacitances, external transmission line effects, pits formation and change in interface during data acquisition at high and low frequencies regions. In addition, the selection of a suitable equivalent circuit strongly emphasized to better interpret of EIS data which in turn cause better resulted KKTs spectra. With considering obtained transformations, more effective inhibitor was selected with regard to its charge transfer resistance, the corrosion capacitance and well satisfying in K-K relations.     

点阵式液晶显示模块SMG12232A的原理及应用

介绍了点阵式液晶显示模块SMG12232A的原理及功能，给出了SMG12232A和单片机接口的硬件电路和软件设计方法，最后给出了一个具体的程序清单。     

含氨废水处理方法的探讨

对催化剂厂含氨废水的处理，提出了多种方法，着重分析了A/O生物法、膜分离法和汽提法，比较后确定采用汽提法处理该废水，建成投产达到预期效果。     

手套箱气氛中氚化水处理的工艺研究

分子筛吸附柱和热金属镁床是手套箱气氛中氚化水 (HTO)搜集和分解处理的一种有效手段。测试了分子筛柱对气氛中水的吸附性能和热金属镁床对HTO的分解性能。结果表明 :分子筛柱对气氛中水的吸附效率 >99 99% ,在空气中水含量为 3 4× 1 0 - 3～ 4 2× 1 0 - 3条件下 ,未发现吸附柱水的贯穿现象 ;热金属镁床对HTO的分解率 >99 9% ,当金属镁的消耗量大于 80 %时 ,未见分解率明显降低。     

改进渣浆泵过流件铸造工艺及硬度的措施

介绍了渣浆泵过流件材质的化学成分及其正交试验的优选过程，以及重新制定的铸造工艺。     

Films and fibers of oriented single wall nanotubes

As-produced nanotubes form a light, fragile and isotropic soot. Different efforts are made to process nanotubes into macroscopic forms of more practical use and more controlled properties. We briefly review in this paper two methods recently proposed to make films of magnetically aligned nanotubes and fibers by using an electrophoretic method. Preferential orientation of the nanotubes in the plane of the films or along the fiber axis is an important feature of the obtained materials. Then we describe in details a different, spinning like, process for making fibers out of single wall carbon nanotubes. This process consists of dispersing the nanotubes in a surfactant solution, re-condensing the nanotubes in the flow of a polymer solution to form a nanotube mesh, and then collating this mesh to a nanotube fiber. The behaviors of the surfactant-stabilized dispersions, which are also presented, are critical for this process. The degree of nanotubes alignment in dried fibers has been characterized by X-ray scattering. It is found to be smaller than the alignment obtained in the previous materials. However, the processing is simpler and faster and potentially scalable for large-scale production.     

文昌A凹陷油气成藏特征与分布规律探讨

文昌A凹陷位于珠江口盆地西部,是一个发育文昌组和恩平组两套湖相烃源岩复合成藏的油气区。根据特征生物标志化合物与碳同位素组成的油岩对比结果,可将文昌A凹陷发现的原油划分为两类,即文昌Ⅱ型和恩平型,前者来自文昌组浅湖相烃源岩,后者源于恩平组湖相烃源岩;天然气主要源于恩平组烃源岩,也可能有文昌组烃源岩凝析气或裂解气的贡献。文昌A凹陷油气两期成藏,早期成油,晚期聚气及轻质油,其油气分布主要受烃源岩有机相、热演化程度和运移分馏作用等因素的控制,凹陷中部以气为主,凹陷边缘气油共存,而凸起上以油为主。     

施加复合电磁搅拌对A357合金微观组织的影响

在半固态加工技术中，电磁搅拌是最早应用于制备非枝晶浆料的方法之一，同时也是半固态触变压铸技术最早获得工业应用的重要技术基础之一。采用自行开发的电磁搅拌器，研究了多种不同电磁搅拌方式在不同工艺条件下，单独施加或复合施加对A357合金微观组织的影响。试验结果表明：单一施加旋转感应电磁搅拌时，浆料径向组织很不均匀；单一施加无芯感应电磁搅拌。当搅拌电流较小时，径向组织也不均匀，增大电流，浆料质量有明显改善；采用（旋转感应＋无芯感应）复合电磁场进行复合电磁搅拌时，可在电流较小时获得满意的浆料质量。     

Dissolution of Ti wires in sulphuric acid and hydrochloric acid solutions

Ti wire electrodes were immersed in acidic solutions containing H₂SO₄ and HCl of various concentrations at 353 K to evaluate corrosion rate by measurement of electric resistance change (resistometry). Addition of hydrochloric acid to sulphuric acid solution promoted depassivation of Ti. After depassivation, the immersion potential dropped to the hydrogen evolution potential and a hydride layer was formed on the surface. The hydride layer dissolved continuously in the acidic solution. SEM observation showed that Ti wires dissolved almost uniformly in the early stage and that the dissolution then trace became irregular due to nonuniform growth of the hydride layer. Dissolution rate of a Ti wire was estimated almost accurately by resistometry.     

交流变频调速技术在二辊轧机压下系统中的应用

介绍一种采用变频调速技术控制的二辊轧机压下系统。该系统可控制轧机压下系统的速度在工艺要求的范围内无级可调，压下量以数字动态显示，控制准确、操作方便。文中对系统的组成及工作原理作了较详细的介绍。