一类关于鲁棒性和敏感性的泛函的优化

本文给出了一类泛函的优化方法.这类泛函包括反映系统鲁棒性和敏感性的目标函数. 其优化是通过-Rm×n→Rm×n的映射来实现的.该映射将所有配置系统极点的反馈矩阵参数 化为一自由矩阵变量的函数.     

A novel method for determination of polyester end-groups by NMR spectroscopy

An efficient, convenient and quantitative method for characterising polyester end-groups is described. We have found that trichloroacetyl isocyanate (TAI) reacts rapidly and quantitatively with both carboxyl [C(O)OH] and hydroxyl (OH) chain ends to form derivatives that can be readily determined by ¹H NMR spectroscopy. The TAI capped end-groups give rise to characteristic imidic NH resonances in a normally clear region of the ¹H NMR spectrum [δ∼10-11.5 for C(O)-O-C(O)-NH-C(O)CCl₃ from C(O)OH, δ∼8-9 for O-C(O)-NH-C(O)CCl₃ from OH]. The method has been successfully applied to quantitative determination of the end-groups of a wide variety of oligomeric polyesters. It has also been applied to higher molecular weight polyesters including commercial, bottle grade, poly(ethylene terephthalate) (PET) and PET based copolyesters (e.g. PETG).     

Geochemical characteristics of the Yufuin outflow plume, Beppu hydrothermal system, Japan

Thermal water at Yufuin (Kyushu Island, Japan) is tapped through about 820 shallow wells and used mainly for hot-spring bathing purposes. Chemical and isotopic data for fluids from wells and fumaroles in Yufuin and Beppu indicate that the thermal activity at Yufuin represents a dilute, westward-flowing hydrothermal outflow plume from the Beppu hydrothermal system. Two other (eastward-flowing) outflow plumes have long been recognized at Beppu, but the Yufuin outflow plume is first recognized here. The Yufuin outflow plume is apparently a mixture of two end-member fluids: (1) deep high-temperature (250–300°C) fluid from the Beppu system having high chloride concentration (1400–1600 mg/L) and a δ¹⁸O value near −6.0%, and (2) meteoric water having low chloride concentration (≤7 mg/L) and a δ¹⁸O value near −9.2%.A permeable conduit for the vertical and lateral transport of deep fluid from the Beppu system is provided by the Yufuin Fault zone, which extends westward from the southern flank of Mt. Tsurumi volcano to the town of Yufuin. Stable isotope ratios and chloride concentrations for shallow groundwaters near the eastern end of the fault, at an elevation near 700 m, are consistent with those required for the low-chloride meteoric end-member of the Yufuin thermal waters. Recharge of this meteoric water, as well as mixing with the Beppu deep fluid, may occur along the Yufuin Fault. Enthalpy-chloride relations indicate additional conductive heating of the Yufuin waters, in the amount of 350–500 kJ/kg beyond that which can be accounted for by mixing between Beppu deep fluid and meteoric water. This could be a result of conductive heating with convection to a depth of 1–2 km. Estimates of the magnitude of the heat source for the Beppu hydrothermal system should take into account the heat being discharged at Yufuin.     

[NZP]陶瓷零膨胀性能的设计

研究了「ＮＺＰ」材料的零膨胀性能，并尝试对零膨胀的「ＮＺＰ」陶瓷作了设计，从晶体结构、原子复合、各向异性、显微结构和复合材料等方面提出了设计思路。     

温和条件下碳氢单键直接官能团化的新方法

介绍了近年来国内外在温和条件下碳氢单键直接官能团化反应的最新进展。官能团化反应的特点是，在常温常压和紫外光促进下，用过渡金属配合物催化碳氢单链活化，使烷烃、芳烃等烃类的碳氢单键直接官能团化，从而达到直接利用各种烷烃及芳烃作为化工原料合成有机化工产品的目的。通过紫外光催化可以使反应在常温常压下进行，能克服传统工艺能耗高、选择性差的缺陷。经不断深入研究，该反应可望在２１世纪成为环境友好的有机合成工艺。     

AHMED experiments on hygroscopic and inert aerosol behaviour in LWR containment conditions: experimental results

Hygroscopic NaOH, CsI, CsOH and inert Ag aerosol behaviour at different temperatures and relative humidities (RH) has been studied in a well instrumented and controlled vessel of 1.81 m³ total free volume. Homogeneous thermal-hydraulic conditions for aerosol measurement in the vessel were achieved. The aerosol number and mass concentration were measured continuously during the experiments using a Condensation Nucleus Counter and a Tapered Element Oscillating Microbalance. The particle size distribution and chemical composition in the test conditions were measured by Berner low pressure impactors. In the case of NaOH the half life of the aerosol mass concentration was more than four times longer at low RH (22%) as compared to high RH (96%). The half lives of the CsOH and CsI aerosols were only twice as long at low RH as compared to high RH. Thus at high RH (96–97%) the half lives of CsOH and CsI were twice as long as the half life for the NaOH aerosol. The faster decay of the NaOH aerosol is due to the smaller density decrease of NaOH during water condensation. CsOH particles grew rapidly to their equilibrium size at all humidities. The measured equilibrium size for CsOH aerosol agree well with the calculated particle size at different RHs. Experimental results were also compared with calculations obtained by severe accident computer codes. These calculated results will be presented in a later paper.     

面向对象的三次参数样条曲线技术

本文利用Ｃ＋＋面向对象的特征，对三次参数样条曲线的定义和生成过程进行封装，从而极大地简化了三次参数样条曲线的定义和绘制过程     

蒸汽压法测定导热油热分解温度的研究

根据克拉贝龙—克劳修斯方程，建立了国内外文献未见报道的测定导热油热分解温度的试验装置和试验方法，测定了大量国内外导热油的热分解温度，数据表明该法具有准确、简单、实用、省时、省力等优点     

热分层流动计算中若干差分格式的比较

本文应用常规的守恒方程及湍流模型，对二维池内热分层流动建立了数学模型，并在Ｐａｔａｎｋａｒ的压力校正法基础上对该数学模型进行了数值计算，计算中的差分格式为乘方格式、一阶迎风、二阶迎风和ＱＵＩＣＫ。通过与实验的比较分析，建议计算应采用ＱＵＩＣＫ格式，并在进行风格独立性试验的基础上使用加密网络。