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91.
Exhaustive attempts are made in recent decades to improve the performance of thermoelectric materials that are utilized for waste heat‐to‐electricity conversion. Energy filtering of charge carriers is directed toward enhancing the material thermopower. This paper focuses on the theoretical concepts, experimental evidence, and the authors' view of energy filtering in the context of thermoelectric materials. Recent studies suggest that not all materials experience this effect with the same intensity. Although this effect theoretically demonstrates improvement of the thermopower, applying it poses certain constraints, which demands further research. Predicated on data documented in literature, the unusual dependence of the thermopower and conductivity upon charge carrier concentrations can be altered through the energy filtering approach. Upon surmounting the physical constraints discussed in this article, thermoelectric materials research may gain a new direction to enhance the power factor and thermoelectric figure of merit. 相似文献
92.
Parametric study on the thermoelectric conversion performance of a concentrated solar‐driven thermionic‐thermoelectric hybrid generator 下载免费PDF全文
A concentrated solar‐driven thermionic‐thermoelectric hybrid generator composed of solar heat collector, thermionic generator (TIG), thermoelectric generator (TEG), and radiator is introduced in this paper. A theoretical model of thermoelectric conversion performance for the hybrid generator is built up based on the heat source of the concentrated solar radiation rather than isothermal heat source. Based on the model, the impacts of related parameters on the internal temperature distributions, output power, and efficiency have been discussed. Moreover, the optimal operating conditions of the TIG‐TEG hybrid device at its maximum output power and efficiency have been determined. Results show that when cascading the TEG with the TIG, there is very little change of the TIG cathode temperature in most conditions, namely, TC ≈ TC′. Meanwhile, the anode temperature becomes higher, and the TEG cold end temperature T2 is close to the anode temperature TA′ for the single TIG system, ie, TA > TA′ ≈ T2. In theory, the optimal concentrated solar radiation I0 for the maximum output power Pmax and the maximum efficiency ηmax differs, which are I0,P = 2.5 × 106 W/m2 and I0,η = 2 × 106 W/m2, respectively, whereas the output power and efficiency of the TIG‐TEG hybrid system simultaneously reach their maximum values when the optimal TIG anode temperature TA,opt = 1025 K, the optimal TIG output voltage Vopt = 2 V, and the optimal ratio of load resistance to internal resistance (R2/R)opt = 2. However, in practice, the parameter values of I0, ΦA, and TA should be strictly controlled under 1.8 × 106 W/m2, 1.4 eV, and 660 K, respectively. Generally, the maximum output power and efficiency of the hybrid TIG‐TEG system are, respectively, 35% and 4% higher than that of the single TIG. 相似文献
93.
Parameter extraction of the five-parameter single-diode model of solar cells and modules from experimental data is a challenging problem. These parameters are evaluated from a set of nonlinear equations that cannot be solved analytically. On the other hand, a numerical solution of such equations needs a suitable initial guess to converge to a solution. This paper presents a new set of approximate analytical solutions for the parameters of a five-parameter single-diode model of photovoltaic (PV) cells and modules. The proposed solutions provide a good initial point which guarantees numerical analysis convergence. The proposed technique needs only a few data from the PV current-voltage characteristics, i.e. open circuit voltage Voc, short circuit current Isc and maximum power point current and voltage Im; Vm making it a fast and low cost parameter determination technique. The accuracy of the presented theoretical I–V curves is verified by experimental data. 相似文献
94.
Yuan Yu Matteo Cagnoni Oana Cojocaru‐Mirdin Matthias Wuttig 《Advanced functional materials》2020,30(8)
Thermoelectric materials have attracted significant research interest in recent decades due to their promising application potential in interconverting heat and electricity. Unfortunately, the strong coupling between the material parameters that determine thermoelectric efficiency, i.e., the Seebeck coefficient, electrical conductivity, and thermal conductivity, complicates the optimization of thermoelectric energy converters. Main‐group chalcogenides provide a rich playground to alleviate the interdependence of these parameters. Interestingly, only a subgroup of octahedrally coordinated chalcogenides possesses good thermoelectric properties. This subgroup is also characterized by other outstanding characteristics suggestive of an exceptional bonding mechanism, which has been coined metavalent bonding. This conclusion is further supported by a map that separates different bonding mechanisms. In this map, all octahedrally coordinated chalcogenides with good performance as thermoelectrics are located in a well‐defined region, implying that the map can be utilized to identify novel thermoelectrics. To unravel the correlation between chemical bonding mechanism and good thermoelectric properties, the consequences of this unusual bonding mechanism on the band structure are analyzed. It is shown that features such as band degeneracy and band anisotropy are typical for this bonding mechanism, as is the low lattice thermal conductivity. This fundamental understanding, in turn, guides the rational materials design for improved thermoelectric performance by tailoring the chemical bonding mechanism. 相似文献
95.
In Spain, solar electricity (photovoltaic and thermoelectric) has reached a stable annual capacity factor above 20% since 2009; while wind achieved 23% since more than 10 years ago. This is the demonstration of an ongoing transition towards a more sustainable energy mix, further corroborated by the reduction of the capacity factor of gas-fired technology, which has seen a decline to values lower than 10% after an initial promising rise; this is a very low value for a fossil-fuel technology. Additionally, hydro installed capacity, which has been stable for the past 20 years, have demonstrated that can be used as a back-up power source in combination with solar and wind electricity, and it is capable of producing energy peaks that may increase from a stable base of 2000 GWh/month up to 6000 GWh/month and therefore meet demand at some particular times when solar and wind are generating less electricity without the need of installing new additional capacity at national level. 相似文献
96.
Investigation of solar hybrid system with concentrating Fresnel lens,photovoltaic and thermoelectric generators 下载免费PDF全文
F. J. Willars‐Rodríguez E. A. Chávez‐Urbiola P. Vorobiev Yu. V. Vorobiev 《国际能源研究杂志》2017,41(3):377-388
An experimental model of a solar hybrid system including photovoltaic (PV) module, concentrating Fresnel lens, thermoelectric generator (TEG), and running water heat extracting unit was created and studied. The PV module used was of c‐Si and TEG of Bi2Te3; the Fresnel lens (solar concentrator) and TEG share an optical train, whereas PV module was illuminated separately with non‐concentrated light. Heat extracting unit operated in thermo siphon mode. In climatic conditions of Mexico (Queretaro, 20o of North latitude, summer time), the Fresnel lens accepted 120 W of solar radiation power, and the system generated 7.0 W of electric power and 30 W of thermal one. The discussion is made of the possible characteristics of a hypothetical hybrid system where all its elements share the same optical train. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
97.
Developing a modular system that properly supports a range of security models is challenging. The work presented here details our experiences with the modular Linux security framework called Linux Security Modules, or LSMs. Throughout our experiences we discovered that the developers of the LSM framework made certain tradeoffs for speed and simplicity during implementation, and consequently leaving the framework incomplete. Our experiences show at which points the theory of the LSM differs from reality, and details how these differences play out when developing and using a custom LSM. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
98.
Two 20 W copper indium gallium diselenide photovoltaic modules were subjected to a thorough indoor assessment procedure, followed by outdoor deployment at the Nelson Mandela Metropolitan University as part of an ongoing study. The initial indoor measurement of maximum power output (PMAX) of one of the modules was considerably higher than the manufacturer's rating (E.E. van Dyk, C. Radue and A.R. Gxasheka, Thin Solid Films 515 (2007) 6196). The modules were deployed on a dual-axis solar tracker and current-voltage characteristics were obtained weekly. In addition to the normal PV parameters of short-circuit current, open-circuit voltage, PMAX, fill factor and efficiency, shunt and series resistances were also monitored. The performances of the two modules are compared and analyzed and the results presented in this paper. 相似文献
99.
热电材料,是一种能实现电能与热能交互转变的材料,可用于温差发电、热电制冷等。到目前为止,所研究的热电材料一般都为固体材料或者高温条件下的液态金属,尚未见文献在电解质溶液热电性能方面有过报道。相关的研究表明,低维度纳米多孔化结构可能成为提高材料热电性能的重要途径,为此,进行了以碳纳米管(canbon nanotubes,CNTs)堆积床为骨架,在其中注入电解质溶液的试验研究,发现其表观塞贝克系数(Seebeck,S)可提高一个数量级,而导电系数在碳纳米管体积分数较小的情况下几乎保持不变,从而可能使热电材料的热电优值ηZT(themoelectric figure of merit,ZT)再提高1~2个数量级,而ηZT直接决定热电设备的转换效率。 相似文献
100.