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71.
72.
H. Launay S. Loridant D.L. Nguyen A.M. Volodin J.L. Dubois J.M.M. Millet 《Catalysis Today》2007,128(3-4):176-182
New vanadium oxide supported on mesoporous silica catalysts for the oxidation of methane to formaldehyde were investigated by infrared and Raman spectroscopies to identify and characterize the molecular structure of the most active and selective catalytic sites. In situ and operando experiments have been conducted in order to understand the redox and hydroxylation/dehydroxylation processes of the vanadium species. (SiO)2VO(OH) species were identified in these catalysts in reaction conditions and shown to undergo a deprotonation at 580 °C under vacuum, leading to a site giving a photoluminescence band at 550 nm attributed to reverse radiative decay from the excited triplet state:
(V4+–O−)* (V5+O2−). An activation mechanism of vanadium monomeric species with electrophilic oxygen species is proposed. 相似文献
73.
核磁共振测井在致密含气砂岩中的应用 总被引:1,自引:0,他引:1
通过对核磁共振测井的T2谱及其T2截至值的合理选取,解释并获得了鄂尔多斯盆地西缘上古生界山西组、石盒子组致密砂岩储集层的总孔隙度、有效孔隙度、毛细管束缚水体积、可动水体积及渗透率等参数,据此预测的储集层孔隙结构特征与岩心分析测试结果很吻合。研究还发现,致密含气砂岩的T2谱具有分布范围窄-中等,波形及差谱分析谱位置明显后移、分布中等、呈单峰的典型特征。结合常规测井资料,综合研究了致密砂岩储层特征及其含气层的测井响应。经测试验证,致密含气砂岩储层的核磁共振测井解释结果十分可靠,表明核磁共振测井可用于该区致密含气砂岩复杂储集层评价。 相似文献
74.
A. Goldman 《Journal of Materials Engineering and Performance》1995,4(4):395-400
Iron-based metallic strip materials such as iron, silicon-iron, and amorphous metal are used for low frequency (50–60 Hz.
line) power applications. Low-loss Nickel-based alloys as high permeability strip or insulated powder cores are the choices
for stable, low-level higher frequency applications. Iron-based powder cores offer low cost as power supply filter chokes.
Ceramic ferrites combine highest frequency operation with low cost and reduced component size as transformers and chokes in
telecommunication and high frequency power supply applications. 相似文献
75.
主要介绍20.4K低温氦气经过加温后给液氧贮箱增压的试验技术。对试验设备、试验方法、试验过程及试验结果做了简要的介绍。 相似文献
76.
77.
在钼丝炉内氩气保护下,利用固体电解质定氧探头测定了含镓1.87%~6.21%范围内Fe-Ga-O三元系平衡时的氧活度,通过处理得到镓在铁液中的标准溶解自由能等热力学参数与温度的关系。 相似文献
78.
This paper concerns the stability analysis problem of discrete linear systems with state saturation using a saturation-dependent Lyapunov functional.We introduce a free matrix characterized by the sum of the absolute value of each elements for each row less than 1,which makes the state with saturation constraint reside in a convex polyhedron.A saturation-dependent Lyapunov functional is then designed to obtain a sufficient condition for such systems to be globally asymptotically stable.Based on this stability criterion,the state feedback control law synthesis problem is also studied.The obtained results are formulated in terms of bilinear matrix inequalities that can be solved by the presented iterative linear matrix inequality algorithm.Two numerical examples are used to demonstrate the effectiveness of the proposed method. 相似文献
79.
In this investigation we consider the formation of Cooper pairs near the oxygen-deficient sites in Y-Ba-Cu-O ceramic superconductors which would give rise to an energy-dependent potential as seen by conduction charge carriers. It is shown that Cooper pairs could be formed under such conditions, resulting in a supercurrent. We use the Bogoliubov transformation technique to calculate the energy gap, the energy difference, and the transition temperature of the model superconductor using certain data obtained from previous experiments. Numerical analysis shows that the superconducting current can be explained by the presence of such oscillating Cooper pairs. 相似文献
80.
Shyi‐Kae Yang 《Asian journal of control》2012,14(2):564-571
This paper presents a new strategy for suppressing the windup effect caused by actuator saturation in proportional–integral–derivative (PID) controlled systems. In the proposed approach, the windup effect is modeled as an external disturbance imported to the PID controller and an observer‐based auxiliary controller is designed to minimize the difference between the controller output signal and the system input signal in accordance with an H‐infinite optimization criterion. It is shown that the proposed anti‐windup (AW) scheme renders the performance of the controlled system more robust toward the effects of windup than conventional PID AW schemes and provides a better noise rejection capability. In addition, the proposed PID AW scheme is system independent and is an explicit function of the parameters of the original PID controller. As a result, the controller is easily implemented using either digital or analog circuits and facilitates a rapid, on‐line tuning of the controller parameters as required in order to prevent the windup effect. Copyright © 2010 John Wiley and Sons Asia Pte Ltd and Chinese Automatic Control Society 相似文献