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11.
钛容器的特点 总被引:2,自引:1,他引:1
黄嘉琥 《石油化工设备技术》1996,17(5):19-24
根据钛材的化学、物理、力学和工艺性能介绍了钛容器在设计、制造、检验和应用方面的特点。 相似文献
12.
We have used x-ray phase analysis to study the composition of the products of reaction between oxygen and nanocrystalline
powders with particle sizes 15, 40, 55, and 80 nm, and also specimens pressed (and sintered) from them. The powders were oxidized
in air at 100°C (400 h) to 500°C (5 min), while the sintered specimens were oxidized at 600–900°C for 15, 120, and 240 min.
In all cases, in the initial oxidation step the oxynitride Ti(OxNy) is formed, which over time is oxidized to TiO, Ti2O3, Ti3O5, TiO2 (anatase) and TiO2 (rutile). In the range 600–800°C, formation of a continuous oxide layer and conversion of anatase to rutile slows down diffusion
of oxygen in the scale. We have established that at 900°C, the growth rate of the scale thickness increases and so the reflections
from the oxynitride are barely noticeable on the diffraction patterns taken from the surface of the oxidized specimen. In
these diffraction patterns, along with strong reflections from the rutile, we also observed weak reflections from lower oxides
and anatase, which may be due to reaction between oxygen and the titanium ions diffused to the scale surface. We have concluded
that at T > 850°C, the mechanism for oxidation of TiN changes. This is due to superposition of counterdiffusion of titanium
ions on the diffusion of oxygen.
__________
Translated from Poroshkovaya Metallurgiya, Nos. 3–4(448), pp. 72–78, March–April, 2006. 相似文献
13.
在聚全氟乙丙烯(FEP)中添加 TiO_2和 Al_2O_3,通过热压成型的方法制备了 FEP/TiO_2复合材料和 FEP/Al_2O_3复合材料,研究了氧化物添加量对复合材料介电常数、介电损耗和高频击穿性能的影响。结果表明,随氧化物含量的增加,复合材料的介电常数和介电损耗均增加;在同一添加量下,TiO_2对复合体系的介电性能影响较大。FEP/TiO_2复合材料的高频击穿性能随 TiO_2含量的增加而下降,在 TiO_2含量为4.0%(质量分数,下同)时,复合材料的损伤阈值已降为 FEP 材料损伤阈值的48.9 %。而 FEP/Al_2O_3复合材料的高频击穿性能随 Al_2O_3含量的增加而升高,当 Al_2O_3含量为1.2%时,复合材料的损伤阈值已增大到 FEP 材料损伤阈值的2倍,达到313 J/m~2。 相似文献
14.
This paper presents the current understanding of the flame retardant mechanism of Casico?. The study includes the flame retardant effect of each individual component: ethylene–acrylate copolymer, chalk and silicone elastomer, as well as the formation of an intumescent structure during heating. The flame retardant properties were investigated by cone calorimetry and oxygen index tests. To obtain insight into the flame retardant mechanism, heat treatment under different conditions has also been performed. The results indicate that the flame retardant mechanism of Casico is complex and is related to a number of reactions, e.g. ester pyrolysis of acrylate groups, formation of carbon dioxide by reaction between carboxylic acid and chalk, ionomer formation and formation of an intumescent structure stabilized by a protecting char. Special emphasis is given to the formation of the intumescent structure and its molecular structure as evaluated from 13C MAS‐NMR and 29Si MAS‐NMR, ESCA and XRD analysis. After treatment at 500°C the intumescent structure consists mainly of silicon oxides and calcium carbonate and after treatment at 1000°C the intumescent structure consists of calcium silicate, calcium oxide and calcium hydroxide. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
15.
钛合金的银脆,镉脆敏感性及其控制 总被引:4,自引:0,他引:4
利用慢应变速率拉伸技术(SSRT),并结合恒载实验,较全面地研究了Ti-6Al-4V合金的银脆行为、固态与液态镉脆行为,确定了应变速率、接触条件、热处理制度、试样取向、温度等因素对Ti-6Al-4V合金银脆与镉脆敏感性的影响,探讨了Ni阻挡层对控制Ti-6Al-4V合金和TC11合金银脆开裂的作用。 相似文献
16.
Intercalation of poly[oligo(oxyethylene) methacrylates] onto sodium montmorillonite (MMT) clay has been investigated. A polymer–clay hybrid has been synthesized through intercalation of the monomer followed by its solution free‐radical polymerization. Eight polymer–clay hybrids were prepared using different weight ratios of clay, different oligo(oxyethylene) lengths and different proportions of crosslinker. Evidence of the development of nanostructures is obtained from scanning electron microscopy, and wide‐angle X‐ray diffraction studies support these results which show disappearance of the peak characteristic to d001 spacing. In this hybrid MMT is dispersed homogeneously in the polymer matrix. © 2003 Society of Chemical Industry 相似文献
17.
Takaaki Wajima Tomoe Shimizu Yasuyuki Ikegami 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(6):921-927
BACKGROUND: This study aimed to investigate the synthesis of zeolites from paper sludge ash (PSA) with added diatomite to remove both NH4+ and PO43? for water purification. The PSA had low Si and significant Ca contents. Four types of diatomite: white (T‐W) and brown (T‐B) from deposits of marine origin in Takanosu, and white (S‐W) and gray (S‐G) from lacustrine deposits in Shonai, were added to NaOH solution to increase the Si content and thereby synthesize zeolites with high cation exchange capacity (CEC). RESULTS: The order of the amounts of Si extracted from the diatomite to the alkali solution was S‐W > T‐W = T‐B > S‐G, which correlates with the amorphous SiO2 content of diatomite. The original ash without addition of diatomite yielded hydroxysodalite with CEC of about 1.0 mmol g?1. For all samples, the addition of diatomite to the solution yielded zeolite‐P with a higher CEC, but the addition of excess Si inhibited the synthesis of zeolite‐P, and the CEC of the product was low. A product with high CEC including zeolite‐P was obtained in a solution with around 500 mmol L?1 of Si concentration, and had the ability to remove both NH4+ and PO43?. CONCLUSION: Diatomite has the potential for used as an additive for the synthesis of high CEC zeolite from PSA. The product with zeolite‐P exhibited relatively high CEC, capacity for NH4+ uptake, and the ability to remove PO43? by precipitation, which is preferable for water purification applications. Copyright © 2008 Society of Chemical Industry 相似文献
18.
19.
Peichun Li Amar Zerroukhi Jianding Chen Yvan Chalamet Thomas Jeanmaire Zhean Xia 《应用聚合物科学杂志》2008,110(6):3990-3998
Chemical shrinkage was used for the in situ measurement of the progressing chemical stabilization reactions and the influence of ozone during the stabilization of polyacrylonitrile. A method for evaluating the activation energy through the sensitivity temperature is presented. The calculated results show that the activation energies were 161.57 kJ/mol in air and 181.23 kJ/mol in ozone-enriched air. Therefore, the chemical reactions were postponed during stabilization in ozone-enriched air. Ozone seemed to act in three ways: first, ozone promoted the formation of the serious skin–core structure. Second, ozone accelerated the chemical reactions and shortened the stabilization time at lower heating rates. Third, ozone postponed the chemical reactions. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
20.