合金元素对镁合金的性能影响研究

研究了新型镁铝锌合金的性能,分析了不同含量的Al、Zn、Pb等元素对镁合金性能的影响.结果表明,随着Al含量的增加,合金的冲击韧性下降而硬度提高;随着Zn含量的增加,冲击韧性和硬度都下降;而随着Pb含量的增加,合金的冲击韧性和硬度都提高.     

New high-temperature copper alloys

New high-strength, high-temperature Cu-Ni-Si alloys have been developed using additions of Cr, Zr, and/or Ti. These new alloys remain as precipitation hardenable as the base alloy, but the main strengthening phase may be different than Ni₂Si (e.g., Cr₂Ti). Substantial increases in mechanical strength were observed at both room and high temperature (773 K) when additions of Cr+Zr+Ti and Cr+Zr were made. Industrial testing of these alloys indicated a sevenfold increase in the lifetime of lateral blocks in continuous casting equipment of copper alloys.     

Effects of CeF3 on properties of self-shielded flux cored wire

0 IntroductionSelf-shielded flux cored wire is a newly developedwelding material used without gas protection. Use of suchcored wires has grown rapidly in developed countriesbecause of the following advantages: simple use, goodwind resistance ability, lower cost resulted from highproductivity and strong desulfurization ability[1]. Self-shielded flux cored wires are preferred for on-site weldingsuch as ship and barge building, storage tank, bridge,offshore oil platform buildings and so on[2 -3].…     

Carboxyl‐terminated butadiene–acrylonitrile rubber modified cyanate ester resin

The carboxyl‐terminated butadiene‐a‐acrylonitrile rubber (CTBN) has been proved to be the most effective toughener for cyanate ester (CE) resin. This work mainly focuses on the different modification effects caused by the addition of CTBN with different acrylonitrile content. The phase separation, morphology of fracture surface, and physical properties of the blends are studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), dynamic mechanic analysis (DMA), and thermogravimetric analysis (TGA). It is testified that the compatibility and toughness between CE and CTBN had a positive correlation with the acrylonitrile content of CTBN. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

A study on the effect of new cyanate and phenoxy polymer on TGDDM/DDS/GMP formulations

An attempt was made on the modification of the tetraglycidyl‐4,4′‐diaminodiphenyl methane/diaminodiphenyl sulfone (TGDDM/DDS) system to improve properties for several industrial applications. Epoxy resins [TGDDM and 1‐glycidyloxy‐4‐methoxy phenol (GMP)] were synthesized in the laboratory. Also, a new cyanate ester and phenoxy polymer were synthesized and characterized by FTIR, ¹H‐/¹³C‐NMR, and thermal studies. GMP was added as a diluent and a new cyanate ester (DCDPT) was introduced to reduce the tight crosslinking density. Further, a new phenoxy polymer was added to improve the toughness property. A variety of neat resin casts using different compositions of the blends were made and their physical, chemical, thermal, and mechanical properties were evaluated to study the effect of GMP as a diluent, cyanate ester as a comonomer, and phenoxy polymer as a toughener. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2963–2973, 2003     

The effect of specific β‐nucleation on morphology and mechanical behavior of isotactic polypropylene

The commercial grade of isotactic polypropylene was modified by a specific β‐nucleating agent in a broad concentration range. The supermolecular structure of the specimens prepared by injection molding was characterized by X‐ray scattering and correlated with mechanical behavior. It was found that at a critical nucleant concentration of 0.03 wt % the content of the β‐modification virtually reaches a saturation level. With further addition of the nucleant, the β‐phase content increases only slightly. The long period passes through a distinct maximum at the same nucleant concentration. This singularity in structure remarkably correlates with a minimum of the yield stress and maxima of strain at break and fracture toughness. Such general behavior is also reflected in the correlation between the β‐phase concentration and fracture toughness profiles along the injection‐molded bars. It is suggested that in the critically nucleated material an optimum thickness of the amorphous interlayer with connecting chains between the β‐crystallites is established, rendering the material the highest possible ductility and toughness. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1174–1184, 2002     

On Modulus and Fracture Toughness of Rigid Particulate Filled High Density Polyethylene

A Kaolin-filled, high-density polyethylene (HDPE) system was used to illustrate the influence of particulates on modulus and toughness of the bulk material. A variation of filler content, particulate size and coupling quality for two HDPE-matrix systems with different viscosity led to a strong dependency of elastic modulus and fracture toughness under various testing conditions, e.g. static loading, fatigue and impact.

A stiffness improvement with increasing filler content was achieved by all coupling qualities. The developed Kaolin reinforcement of HDPE with optimised coupling offers an improvement of the stiffness and toughness under all investigated loading conditions. The degree of improvement depends on the particulate size and matrix viscosity. The energy dissipation mechanisms were investigated by fractographic analysis.     

陶瓷材料断裂韧性测试新技术：静态爆破剂预制裂纹的研究

准确测试陶瓷材料断裂韧性Ｋ１Ｃ的关键是预制具有原生裂纹的试样。本文以单边切口梁法测试Ｋ１Ｃ为基础，提出了一种简便而有效的陶瓷材料原生裂纹的预制方法－静态膨胀法。研究结果表明：静态膨胀法中裂纹的扩展是稳态的；通过调节影响微裂纹产生与扩展的多种因素，可以准确地控制裂纹扩展的深度，预制出合适的原生裂纹，为准确评价结构陶瓷的断裂韧性提供了一种有效可行的方法。     

氮化硅反应烧结的研究进展

氮化硅作为高温功能陶瓷性能优越，但将其制备成陶瓷零件比较困难，目前一般用反应烧结法制备氮化硅陶瓷零件。此外，反应烧结制备氮化硅陶瓷还具有成本低、烧结温度低、产品成型好、陶瓷高温性能好等优点。综述了氮化硅陶瓷反应烧结工艺流程和工艺的优缺点，着重介绍了氮化硅反应烧结在成型工艺、烧结工艺、原材料影响、后处理和陶瓷增韧等方面所取得的进展。     

加快创新开发,开拓聚氯乙烯压力管道系统的新局面

近年来聚氯乙烯管道取得了重大进步。PVC-M管材(改性聚氯乙烯管材)、PVC-O管材(取向聚氯乙烯管材)兼有非凡的强度和韧度,和传统的硬聚氯乙烯管材比可以采用较高的设计应力,显著地节约材料。