聚合物-金属界面相形貌的研究

环氧树脂在 Al 合金表面生成纤维状的界面相结构,其形成、发展和特征与树脂的体系、交联反应条件以及 Al 合金的表面状态有关。环氧树脂的基础相为颗粒状的超结构组织。聚合物界面相的力学破坏表现为纤维体的拉伸、变形和断裂,而基础相在纯剪切受力时出现在45°方向的裂纹,并发展导致连接层的破坏。     

Electrical conductivity of ferroelectric sodium vanadate,rubidium vanadate,cesium vanadate and their solid solutions

The d.c. electrical conductivity of sodium vanadate, rubidium vanadate, cesium vanadate and their solid solutions sodium-rubidium vanadate and sodium-cesium vanadate were studied by a two-probe method in the temperature range covering their transition points. The electrical conductivity shows sharp change at the phase transition temperature of these materials. In NaVO₃, RbVO₃ and CsVO₃, increase in d.c. conductivity is observed in the ferroelectric region while nonlinearities are observed above transition temperatures. In solid solutions, the activation energy in the paraelectric state is higher than that in the ferroelectric state and depends upon sodium concentration.     

钛铜复合棒及其标准化

概述了钛铜复合棒研制开发及发展历程,并介绍了钛铜复合棒的主要性能,以及钛铜复合棒的标准化情况。     

注射成形Fe-50%Ni软磁合金的研究

Fe-50 %Ni合金是一种典型的高磁导率和低矫顽力的软磁材料,有着广阔的应用前景.本次实验采用注射成形方法制取Fe-50 %Ni,研究了在注射成形工艺中烧结工艺对最终产品性能及微观组织的影响,并分析了影响产品磁性能的一些主要因素.实验表明,烧结温度的提高和烧结时间的延长能够较好改善产品的力学性能;密度是影响产品磁性能的主要因素,杂质(主要指(C、O、N)的含量和晶粒尺寸对剩磁、磁导率和矫顽力也有较大的影响;通过注射成形方法制取的Fe-50 %Ni,其性能要优于采用传统粉末冶金方法制造的Fe-50 %Ni.     

Phase transition of LCP fluids confined in nanochannels through MD simulation

Manipulation of molecular orientation alignment in MCTLCPs (main-chain thermotropic liquid crystalline polymers) by pure shear at nano scale has been investigated for the first time using molecular dynamics (MD) simulation. Results indicate that high planar shear induces long-range uniform orientation ordering (liquid crystalline phase) of initially randomly orientated molecules of MCTLCP fluid confined in a nanochannel, which is confirmed by analyzing the orientation order parameter and the snapshots of MCTLCP liquid in a nanochannel under different shear rates. Insights into the origin of the phase transition phenomena are given at molecular level through investigating the thermodynamic density distribution of MCTLCP molecules in the nanochannel, suggesting that the energy shift due to a radical jump of system density affects both the magnitude and the orientation of the molecular ordering. Simulation results also show that there is a critical shear rate for transforming isotropic phase into liquid crystalline phase. The critical shear rate is dependent on the temperature of the MCTLCP system. Findings in this paper may present useful information for processing TLCP molecules at nano scale and the understanding of nanoflow.     

直流法测量钯氢化物电极电阻时的阻值偏移

讨论了直流法在线测量钯氢化物电极电阻时的电化学效应，计算了电解液的共导、测量电流与电解电流引起的浓差电池效应以及电极作为集流体引起的电阻贡献。结果表明：当电极具有高的长度与半径比值、粗糙的表面、高的溶液电导以及大的电解电流时容易引起显著的附加电阻。     

磷矿中七种金属元素的光谱法测定

研究了磷矿样品中7种金属元素锰、钴、镍，锌、铬、钼及铋的分析方法，选择了灵敏度高干扰少的谱线，绘制出工作曲线，对样品进行了科学处理，不必进行化学分离即可对七种元素同时测定，经合成样分析、回收实验及样品测定，证明此方法精确可靠，其回收率在98％-102％之间。     

Crack closure in fibre metal laminates

GLARE is a fibre metal laminate (FML) built up of alternating layers of S2-glass/FM94 prepreg and aluminium 2024-T3. The excellent fatigue behaviour of GLARE can be described with a recently published analytical prediction model. This model is based on linear elastic fracture mechanics and the assumption that a similar stress state in the aluminium layers of GLARE and monolithic aluminium result in the same crack growth behaviour. It therefore describes the crack growth with an effective stress intensity factor (SIF) range at the crack tip in the aluminium layers, including the effect of internal residual stress as result of curing and the stiffness differences between the individual layers. In that model, an empirical relation is used to calculate the effective SIF range, which had been determined without sufficiently investigating the effect of crack closure. This paper presents the research performed on crack closure in GLARE. It is assumed that crack closure in FMLs is determined by the actual stress cycles in the metal layers and that it can be described with the available relations for monolithic aluminium published in the literature. Fatigue crack growth experiments have been performed on GLARE specimens in which crack growth rates and crack opening stresses have been recorded. The prediction model incorporating the crack closure relation for aluminium 2024-T3 obtained from the literature has been validated with the test results. It is concluded that crack growth in GLARE can be correlated with the effective SIF range at the crack tip in the aluminium layers, if it is determined with the crack closure relation for aluminium 2024-T3 based on actual stresses in the aluminium layers.     

Effect of Rare Earth Element Cerium on Mechanical Properties and Morphology of TiN Coating Prepared by Arc Ion Plating

TiN coatings were deposited on polished substrates of W18Cr4V high speed steel by means of vacuum arc ion plating. The effect of cerium on adhesion between TiN coating and substrate was studied. The microstructures and composition of TiN coatings were also investigated by means of scanning electron microscope (SEM), Auger electron spectroscopy (AES), and X-ray diffraction (XRD) technique. It was found that cerium is an effective modifying agent and the addition of suitable amount of cerium to TiN coatings can produce relatively excellent properties such as micro-hardness, wear resistance, oxidation resistance and porosity. The experimental results show that the added cerium in TiN coatings makesa contribution to form the preferred direction along with a (111 ) or (222) close packed face, which may be one of the reasons that improves some properties mentioned above.