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21.
磷酸盐玻璃中Tb^3+离子的敏化发光与能量传递 总被引:5,自引:0,他引:5
研究了磷酸盐玻璃中Tb^+离子的敏化发光。结果表明;磷酸盐玻璃中Dy^3+,Ce^3+和Tb^3+产生敏化发光。确立了双掺Tb^3+和Dy^3+玻璃中Dy^3+-Tb^3+敏发化光的声子支助共振能量转移模型,双掺Tb^3+和Ce^3+玻璃中Ce^3+的激光发能通过无辐射能量共振转移每化发光,计算出Ce^3=-Tb^3+的有量传递效率,为确定最佳稀土离子掺加量提供了依据。 相似文献
22.
通过四川北川县体育场高空悬挑看台梁板支模工程的实践,验证了高大空间复杂外形工程条件下扣件式钢管脚手架的适用性.明确了脚手架结构验算的部位,表明了轴心受压对立杆稳定性的影响,指出了施工重点部位.扣件式脚手架用于复杂外形结构有易于操作、经济性好和适用性强的优点. 相似文献
23.
Oxidative polymerization of 1,4,5,8,9 pentamethylcarbazole with FeCl3 in chloroform solution, yields a new electroactive well-defined poly(3,6-carbazole) with a twisted structure due to steric hindrance of the adjacent monomer units. This non-coplanar structure allows, for the first time, to a carbazole compound to be converted in high polymer by the dehydrocoupling route using FeCl3 as the oxidizing agent. Soluble materials with molecular weights Mw around 104, high glass transition and thermal stability in air, were obtained. Electrochemical studies of polymer films exhibited one irreversible oxidation process at high potential consistent with a non-conjugation between the carbazole moities. Moreover, deviation from the coplanarity of consecutive rings of poly(1,4,5,8,9-pentamethyl-3,6-carbazolylene) permits these materials to emit a bright pure blue-violet light with no excimer formation, which can be interestingly used for the development efficient light-emitting diodes. 相似文献
24.
为了提高SrAl_2O_4∶Eu~(2+),Dy~(3+)荧光材料的发光强度和余辉时间,采用高温固相法合成了SrAl_2O_4∶Eu~(2+),Dy~(3+)荧光粉.利用X射线衍射仪、扫描电子显微镜和荧光光谱仪对产物的化学成份、结构、微观形貌和发光特性进行了分析.结果表明,SrAl_2O_4∶Eu~(2+),Dy~(3+)荧光粉的最佳煅烧温度为1 500℃,最佳煅烧时间为3 h.当Eu_2O_3的质量分数为2%时,Sr Al2O4∶Eu2+荧光粉的发光强度最大;当Eu_2O_3的质量分数为1.5%时,SrAl_2O_4∶Eu~(2+)荧光粉的余辉性能最好;当Eu_2O_3的质量分数为2%、Dy_2O_3的质量分数为4%时,SrAl_2O_4∶Eu~(2+),Dy~(3+)荧光粉的发光强度和余辉性能最好. 相似文献
25.
无源光网络是目前实现宽带接入的主流技术,正处于快速演进阶段。在比较下一代无源光网络备选技术的基础上,重点介绍多波长堆叠无源光网络的工作原理和关键实现技术,并综述了这种无源光网络的实验演示系统现状和低成本光网络单元研究进展。 相似文献
26.
Zhaowu Wang Haipeng Ji Zongtao Zhang Jian Xu Deliang Chen 《Journal of the American Ceramic Society》2021,104(10):5077-5085
The cation exchange method has been demonstrated to be efficient in doping Mn4+ ions into various fluorides to synthesize the red-emitting LED phosphors. This paper, however, reports the challenge in using this method to dope Mn4+ into the Na2SiF6 single crystals, to prepare the fluoride phosphor in single-crystal form, a state-of-the-art study in the white LED lighting field. The millimeter-sized Na2SiF6 single crystals with a uniform columnar morphology (2–3 mm in length) were successfully grown in solution by a slow cooling process after optimizing the precursors. Then, the crystals were soaked in the HF solution dissolved with K2MnF6 to implement Mn4+-doping via the cation exchange process. Evaluation of the Mn4+-doping behavior reveals that the Mn4+ ↔ Si4+ cation exchange is less efficient in the case of single crystal host compared with the polycrystalline powdery ones and by-reactions also occur which generates new phases. The Na2SiF6 single crystals doped with Mn4+ exhibit a series of discrete sharp peaks with intense zero phonon line emission at 617 nm under 450 nm blue irradiation. This study may trigger the exploration of new single crystal fluoride phosphor. 相似文献
27.
Mengya Zhang Zhijun Wang Xuejiao Wang Hao Suo Lingwei Cao Yao Yao Mingjie Zheng Jia Cui Zhibin Yang Panlai Li 《Journal of the American Ceramic Society》2021,104(10):5224-5234
Red/near infrared (NIR) long persistent phosphors have received extensive attentions in biomedical, food inspection, iris recognition, biological imaging, etc. Herein, a new phosphor, Li2ZnGe3O8:Cr3+, is reported with deep red persistent luminescence peaking at 708 nm. By adjusting the Cr3+ doping concentration, the competitive site occupation at [ZnO6] and [GeO6] polyhedral enables different traps behaviors including trap types, trap concentration and trap depth, which in turn leads to different afterglow duration time from 2 to 20 h. The persistent luminescence mechanisms originated from different trap models have been discussed, and it is found that they can cooperate or inhibit each other, enabling different luminescence depending on time. The dynamic anti-counterfeiting applications have been demonstrated, which provides a new way to rationally designing for multi-functional luminescent materials. 相似文献
28.
T. Aitasalo A. Durygin J. Hls M. Lastusaari J. Niittykoski A. Suchocki 《Journal of Alloys and Compounds》2004,380(1-2):4-8
The thermoluminescence (TL) of calcium aluminate persistent luminescence materials doped with Eu2+ and co-doped with R3+ ions were studied between 20 and 325 K. The basic material, CaAl2O4:Eu2+, showed three TL bands between 150 and 300 K in the glow curve. Changing the R3+ co-dopant to the adjacent element in the rare earth series affects significantly the thermoluminescence intensity and even the position of the glow curve maximum. The physical effect seemed to be removing the traps since the La3+, Y3+, and Lu3+ ions suppressed the thermoluminescence. The Pr3+, Ho3+, and Dy3+ co-doping enhanced mainly the low temperature traps and these materials have an intense but relatively short persistent luminescence at room temperature. The Nd3+ and Tm3+ ions enhanced the TL bands close to room temperature and are thus the most suitable co-dopants to induce intense and long persistent luminescence. The quenching of the thermoluminescence by Sm3+ was concluded to be due to the presence of Sm2+ that removes totally the traps. 相似文献
29.
YANG Shuijin YUAN Liangjie and SUN Jutang) Department of Chemistry Environmental Engineering Hubei Normal University Huangshi China) College of Chemistry Molecular Sciences Wuhan University Wuhan China 《稀有金属(英文版)》2003,22(2)
The Eu3+-doped Na24As2W22O83 phosphor has been prepared by solid state reaction from Na3AsO412H2O, Na2WO4 2H2O and WO3, and characterized by elemental analysis, infrared spectroscopy and powder X-ray diffractometry. According to the measurements with X-ray diffraction, this material belongs to orthorhombic system with its lattice constants: a = 1.4750 nm, b = 1.1944 nm, c = 1.1062 nm, it is consistent with space group D24-P212121 (No.19). The emission and excitation spectra were measured. The luminescent properties of Eu3+-doped Na24As2W22O83 and mechanism of energy transfer were discussed. 相似文献
30.