0.42THz频率连续可调同轴回旋管

作为目前工作在太赫兹频段输出功率最大的辐射源之一回旋管的功率可达到数十千瓦. 传统太赫兹回旋管一般为点频工作,难以满足动态核极化核磁共振等多方面技术需要。采用机械调节的方式,实现了带宽为2GHz中心频率为0.42THz二次谐波频率连续可调同轴回旋管,通过非线性理论分析发现,在不改变工作磁场条件下,在调节带宽范围内,可实现大于8kW的功率输出.     

基于TeO_2晶体的声光可调谐滤波器消色散设计

声光可调谐滤波器(AOTF)是一种新型的色散元件,被广泛应用到光谱成像领域,但由于其在调谐时,衍射角会随着波长的变化而变化,造成图像漂移。为了解决AOTF光谱相机晶体色散引起的图像漂移问题,采用了在晶体出射面外添加棱镜的方法。通过分析晶体旋光性对介质外衍射角的影响,比较发现当入射光极角很大时,必须考虑晶体的旋光性对介质外衍射角的影响,在此基础之上分析棱镜偏折角与棱镜顶角和材料的关系,当入射光极角为28°时,添加顶角为10.1°的棱镜可得到0.0007°的消色散偏差。由此说明,在光路中添加材料和顶角合适的棱镜,可以很好地消除AOTF光谱相机中晶体的色散。     

GaP：（N）的背景光谱和发光尖峰

获得高分辨ＧａＰ（Ｎ）光致发光光谱，观察到等电子陷陆束缚激子发光中ＬＯ和ｌｏｃ多声子发射，其强度分布答合泊松分布。将声子伴带区分为直接光跃迁和间接光跃迁，并进行了相应讨论，还观察到局域声子效应－－光谱相似定律和相当显著的背景光谱。     

用窄带滤光片作为调谐元件的外腔半导体激光器

分析了窄带滤光片的调谐原理，拟合了一块实际滤光片的透射率函数，它是理论的透射率函数和一个洛仑兹函数的乘积。利用１．３μｍ的外腔式调谐激光器实现了１２７２．５ｎｍ至１２９１．７ｎｍ范围内的不连续宽带调谐。     

探讨半导体发光二极管及其照明的应用

现阶段,随着我国社会主义市场经济飞速发展,人们生活水平和生活质量不断提高,因此对照明事业提出了更高的要求,半导体发光二极管具备了良好的节能、环保性能,使用时间较长,具有良好的高效性,因此而被大量使用于室内外的照明当中,本文通过对发光二极管原理进行分析,探讨其照明的应用。     

Mg掺杂AlGaN的特性研究

采用金属有机物化学气相淀积方法在Al2O3衬底上生长不同浓度Mg掺杂的AlxGa1-xN合金薄膜,并在750℃、N2气氛下对Mg进行热退火激活。用X射线衍射ω-2θ扫描计算确定样品的Al组分,发现Mg摩尔掺杂浓度和退火对Al组分均未产生明显影响。X射线衍射摇摆曲线与原子力显微镜扫描表明随Mg摩尔掺杂浓度增加,样品晶体质量下降,样品表面凹坑增加,但热退火对薄膜表面形貌有明显的改善。阴极射线发光测量发现带边峰强度随掺杂浓度增加而减弱,退火后样品的施主-受主对复合发射与导带受主的复合发射均有增强,验证了热退火对钝化受主杂质的激活作用,对实现高效AlGaN的p型掺杂具有重要意义。     

Surface Regulation Towards Stimuli‐Responsive Luminescence of Ultrasmall Thiolated Gold Nanoparticles for Ratiometric Imaging

The surface chemistry of the ultrasmall thiolated gold nanoparticles (AuNPs, < 3.0 nm) plays key roles in both governing the intrinsic emission and establishing interfaces surrounded by various amine‐containing biomolecules in the biomedical applications such as imaging, targeting, and diagnostics. However, a fundamental understanding of the surface ligand's role in the stimuli‐responsive emissions of AuNPs toward the amine molecules is currently lacking. Here, through investigation of the thiolate surface and exotic amine structures, it is discovered that the nucleophilic amines tend to closely bind the electrophilic gold surface, generating a high‐energy stimuli‐responsive emission from the low‐energy intrinsically emitting AuNPs. Both the intrinsic and stimuli‐responsive emissions show a unique amine concentration‐dependent ratiometric pattern for quantitative assessments of important biogenic amines in the biological samples. This discovery opens a new pathway to the design of stimuli‐responsive AuNPs, and would promote more experimental and theoretical research on the application‐driven surface engineering for advanced biological applications.     

丙丁烷TDLAS测量系统的吸收峰自动检测

基于丙丁烷在3.37μm处的基频吸收峰,使用相应中心波长的连续带间级联激光器和长光程吸收池,研制了基于波长调制技术的丙丁烷气体检测系统。为自动确定波长调制过程中的锯齿波中心值参数,基于电流与输出光频率的线性关系,通过均匀增加激光器驱动电流获得直接吸收光谱。使用基于洛伦兹线型的拟合算法确定吸收峰值对应电流,使锯齿波输出光以其为中心覆盖吸收峰。实验证明,以拟合结果31.94mA为中心值的锯齿波,在叠加频率为20 000Hz、幅值为0.03V的高频正弦调制波后,系统二次谐波峰值超过100mV。算法全过程不依赖标气和F-P标准具等精密光学器件,可适应实际生产条件下的系统自动定参。     

可调谐双耦合场作用下的电磁诱导负折射特性

建立了可调谐双耦合场作用下的A型四能级系统模型,研究了系统的介电常数和磁导率随耦合场参数的变化规律,并由此探讨了满足负折射的条件.结果表明,固定耦合场的拉比频率,当两个耦合场中的一个共振、另一个失谐,或两个耦合场均失谐时满足负折射条件,但它们呈现不同的负折射特性.     

Cancer‐Targeting Graphene Quantum Dots: Fluorescence Quantum Yields,Stability, and Cell Selectivity

Folic acid, due to its high affinity toward folate receptors (FR), is recognized as one of the most promising cancer targeting vectors. However, the inherent defects of low water solubility (1.6 µg mL^?1), high sensitivity toward photo‐bleaching, low fluorescent quantum yields (QYs, <0.5%) seriously limit its practical application. Herein, ultrastable, highly luminescent graphene quantum dots (GQDs) that selectively target diverse cancer cells are prepared and tested. The new GQDs present step changes compared to common folic acid through an ≈6250 times increase in water solubility (to ≈10 mg mL^?1), more than 150 times in QYs (up to ≈77%), while maintaining luminescence stability up to 98% when subjected to UV, visible light, and heating over 360 min. It is shown that the suppression of nonradiative transitions by amino groups pyrolyzed from pterin plays a key role in the mechanism of high QYs and excellent stability. The functional groups that are likely responsible for the selective targeting of cancer cells with different levels of folate receptor expression on the surface are identified. Collectively with these promising properties, the new functional graphene quantum dots may open a new avenue for cancer diagnosis, drug delivery, and therapies.