聚氨酯干法涂层的应用

介绍了涂层织物的特点及聚氨酯在涂层整理中的作用,并对干法直接涂层工艺进行了探讨.     

Analysis of adhesive bonded composite lap joints with transverse stitching

The effect of transverse stitching on the stresses in the adhesive is investigated using an adhesive sandwich model with nonlinear adhesive properties and a transverse stitching model for adhesive bonded composite single-lap and double-lap joints. Numerical results indicate that, among all stitching parameters, thread pretension and stitch density have significant effect on the peel stresses in the adhesive; increase in the thread pretension and the stitch density leads to a decrease in peel stress in the adhesive, while an increase in other parameters generally results in a negligible reduction in peel stress. The effect of stitching was found to be negligible on the shear stresses in the adhesive. Thus it is concluded that stitching is effective for the joints where peel stresses are critical and ineffective for those where shear stresses are critical.     

新型缆用热熔胶的研制

分析了通信线缆用 YH- 4热熔胶组成原料的性能和作用 ,找出影响耐环境高温性能的主要原因 ,并对新研制出的耐环境高温性能 YH- 5热熔胶作了一些分析和探讨 .     

新型难燃输送带胶粘剂的研制

以改性氯丁橡胶为主料、多异氰酸酯为固化剂制成的新型难燃输送带胶粘剂,具有粘接强度高、耐热性好、干燥时间短、难燃等特点,在常温常压下粘接输送带接头,固化30min即可负荷运行。     

Development of sealing compositions with nanostructure iron-based fillers

The possibility of utilizing nanopowders of iron and Fe-Co-Ni produced bu a thermochemical method in the fabrication of sealing composition materials is investigated. It is established that such hermetic sealing composition materials function reliably under extremal conditions and guarantee elevated strength of adhesion to the surface of the metal and high corrosion and temperature stability. __________ Translated from Poroshkaya Metallurgiya, Nos. 3–4(448), pp. 112–117, March–April, 2006.     

Phase separation studies in RIM polyurethanes catalyst and hard segment crystallinity effects

Polyurethanes were prepared from pure 4,4′-diphenylmethane diisocyanate (MDI), 1,4-butane diol (BDO) or 1,2-ethane diol (EDO) and α,ω-hydroxyl poly(propylene oxide) (PPO) by reaction injection moulding (RIM). Hard segment (MDI + BDO or EDO) level was 45–50 wt%. The PPO had about 20% ethylene oxide copolymerized in at the chain ends to provide 80% primary OH end groups. M_n was varied from 2000 to 4000. Dibutyl tin dilaurate catalyst and mould temperature were varied. Dynamic mechanical, wide-angle X-ray, differential scanning calorimeter, molecular weight and tensile elongation measurements were made on the RIM polyurethanes. At low reaction rates (low catalyst or temperature) highly crystalline, well phase separated but low molecular weight polymers were produced. At high catalyst or temperature levels more poorly phase separated but high molecular weight, tough polymers resulted. Higher M_n PPO gave better phase separation and EDO gave higher melting temperatures. Preventing hard segment crystallinity by substituting asymmetric MDI or glycols resulted in phase compatibility.     

Hydrolytic stability and protective properties of polyurethane oligomers based on polyester/ether/polyols

The present study deals with effect of the type and chemical character of incorporated polyester/polyether blocks on the hydrolytic stability of crosslinked polyurethane oligomers. Diffusion parameters of the investigated polyurethane oligomers, giving information concerning chemical changes taking place in neutral, basic and acidic aqueous environments, have also been determined.     

水乳型丙烯酸酯建筑防水胶的研制(Ⅱ)

摘 要 研究水乳型丙烯酸酯建筑防水胶与水泥的配比及共混性能、共混固化物胶膜的力学性能、耐冷热性能及老化性能。     

瓦楞纸板用抗水淀粉胶配方及性能研究

简要分析了玉米淀粉胶的组成及对其质量的影响，重点对粘合剂的防水性进行了研究，叙述了瓦楞纸板用抗水粘合剂的配制及工艺过程，并与常规方法制备的粘合剂进行了性能比较，测定了抗水时间，得出了瓦楞纸板用抗水粘合剂的最佳配制比例。     

水性聚氨酯电导率与聚沉值的研究

研究了软（硬）段含羧基的水性阴离子纳米聚氨酯体系的n(NCO)/n(OH)比值，COOH的质量分类，反离子各类，合成方法与电导率关系及产生的原因；探讨了该体系的n(NCO)/n(OH)值，COOH的质量分数，合成方法与临界聚沉值（Cc.c)的关系和规律。并分析，比较了软（硬）段含羧基的水性阴离子聚氨酯体系电导率与Cc.c二者关系，得出了随COOH的质量分数升高，二者变化相同，随n(NCO)/n(OH)比值升高,二者变化相反的结论。