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介绍了液体通过核孔膜规律方面取得的新认识,包括:(1)纯净液体通过核孔膜的规律;(2)核孔膜测定液体粘滞系数的各种方法;(3)各种物质溶液浓度的核孔膜测定;(4)液相混合物快速分离和化学分离;(5)流体中固体微粒对核孔膜的堵塞及其公式;(6)用核孔膜滤除液中各各斩规律。 相似文献
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We have studied the CO2/CH4 mixed gas permeation through hollow fiber membranes in a permeator. An approach to characterize the true separation performance of hollow fiber membranes for binary gas mixtures was provided based on experiments and simulations. Experiments were carried out to measure the retentate and permeate flow rates and compositions at each outlet. The influences of pressure drop within the hollow fibers, non-ideal gas behavior in the mixture and concentration polarization were taken into consideration in the mathematics model. The calculation results indicate that the net influence of the non-ideal gas behavior, competitive sorption and plasticization yields the calculated CO2 permeance in a mixed gas permeator close to that obtained in pure gas tests. Whereas the CH4 permeance is higher in the mixed gas tests than that in the pure gas tests, as the plasticization caused by CO2 dominates the permeation process. As a result, the CO2/CH4 mixed gas selectivity is smaller than those obtained in pure gas tests at equivalent pressures.The calculated membrane performance shows little changes with stage cut if the effect of concentration polarization is accounted for in the calculation. The integration method developed in this study could provide more accurate characterizations of mixed gas permeance of hollow membranes than other estimation methods, as our model considers the roles of non-ideal gas behavior and concentration polarization properly. 相似文献
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P. Bocchetta C. Sunseri A. Bottino G. Capannelli G. Chiavarotti S. Piazza F. Di Quarto 《Journal of Applied Electrochemistry》2002,32(9):977-985
Alumina membranes were fabricated by anodizing aluminium metal in 0.15 M oxalic acid. The growth kinetics of the porous layer were investigated in the temperature range –1 to 16 °C using linear potential scans up to 70 V. The faradaic efficiencies of metal oxidation and of porous layer formation, determined by applying Faraday's law, were found to be independent of both temperature and electrical charge. SEM analysis of the metal-side and solution-side surfaces revealed different morphologies. After dissolution of the barrier layer in phosphoric acid, the metal-side surface showed circular pores whose size of about 90 nm was found to be uniform and independent of temperature. The pore population was also practically independent of temperature and a value of about 4 × 1013 pores m–2 was determined. On the solution-side surface the presence of a deposit partially occluding the mouths of pores was observed. This coating could be removed by chemical etching in NaOH or thermal treatment at 870 °C, where decomposition of oxalate occurs. This supports the hypothesis that the deposit consists of an aluminium salt containing oxalate anions precipitated from the solution. The results show that it is possible to control the morphological characteristics of the anodic alumina membranes by careful choice of experimental conditions. 相似文献
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Wrinkling is a well known phenomenon experimented by tension membranes in Civil Engineering applications. This paper will
present an efficient numerical technique for the computational simulation of such wrinkles in a prestressed membrane. In particular,
the relaxed energy approach (Pipkin in IMA J Appl Math 36:85–99, 1986) is particularized for prestressed membranes (Gil in
Textile composites and inflatable structures, CIMNE, 2003) undergoing moderate strains. Wrinkling conditions in terms of the
Euler-Lagrange finite deformation tensor along principal directions will be obtained. This will provide a framework to describe
properly the initial instant when wrinkles start to be encountered in a prestressed Saint Venant–Kirchhoff hyperelastic membrane.
Subsequently, a modified Helmholtz’s free energy functional will be introduced with the purpose of describing the modified
constitutive behaviour of the continuum after the onset of wrinkling. Consistent derivations of the stress tensor as well
as the constitutive tensor will de depicted. The results will be particularized for membranes and cables in a Finite Element
discretization basis. Some numerical examples will prove the accuracy and robustness of the described algorithm. 相似文献
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超高分子量聚乙烯衬板在煤仓中的应用 总被引:2,自引:0,他引:2
介绍了井底煤仓溜煤斜面采用超高分子量聚乙烯衬板安装及应用情况 ,对井底煤仓棚煤原因及解决办法进行了探讨 相似文献
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