高温合金表面激光熔敷热障涂层组织结构与氧化性能

采用 5KW连续CO2 激光器对Ni基高温合金上二次重熔NiCoCrAlY和ZrO2 陶瓷层进行了研究。结果表明 :激光快速熔化和凝固获得定向外延生长、紧密堆积的柱状晶氧化锆陶瓷层。NiCoCrAlY结合层与柱状晶之间存在氧化铝层 ,保证了柱状晶与NiCoCrAlY层的联结。扫描电镜和电子探针联合分析发现 ,氧化锆层与NiCoCrAlY结合层、结合层与基体间均为冶金结合。采用化学改性氧化锆消除了涂层裂纹。高温氧化性能测试得出激光重熔试样氧化动力学近似地遵守抛物线速率方程。在 12 0 0℃ ,空气下激光熔敷TBCs 抗氧化性明显高于等离子喷涂TBCs。     

A study of neutron and gamma radiation effects on transmission of various types of glasses, optical coatings, cemented optics and fiber

A study of radiation effects on various types of glasses, dielectric optical coatings, cemented optics and fiber was undertaken with a view to select them for extreme radiation environments. Samples were exposed to different radiation doses in the Pakistan Research Reactor-I (PARR-I) for neutron and Cobalt 60 source for gamma irradiation. Transmissions were measured before and after irradiation. The dielectric coatings were subjected to additional tests (adhesion, abrasion and humidity, etc.) as per MIL-M-13508C and MIL-C-675C. All 15 glasses studied showed varying amounts of transmission loss as expected, with negligible degradation for three types. Recovery of transmissions with time/ageing was also studied, with more or less complete recovery with temperature annealing. A faster bleaching of darkened/brown glasses was achieved by using UV lamps or UV laser. The dielectric coatings (HR, AR) and one of the two commercial optical cements showed excellent resistance to neutrons and gamma radiations, and could be good candidates for the fabrication and utilization of optical components in extreme radiation environments. The data allowed several Chinese glasses to be studied for the first time.     

Optimisation of metallic pigments in coatings by an electrochemical technique and an investigation of manganese powder as pigment for metal rich primers

Zinc dust and manganese powder as pigments were incorporated in epoxy-polyamide and butyl titanate medium, with different pigment volume concentration (PVC) ranging from 20 to 74. These protective coatings were coated on sand blasted mild steel substrates and immersed in 3 wt.% sodium chloride solution and the corrosion current was measured by the Tafel extrapolation method. From the corrosion current produced by these primers, the optimum level of the pigments in these binders was identified. Thus the protective performance of optimised primers was evaluated on a sand blasted mild steel surface by the Tafel polarisation method in 3 wt.% sodium chloride solution, over different periods of time. The results were found to be comparable with the salt spray test and galvanic current measurements. The manganese powder used for this investigation showed that it could be used as an alternative to zinc powder for metal rich primers.     

化学镀Ni-P-PTFE复合镀层的性能

本文对化学镀ＮｉＰＰＴＦＥ复合镀层的性能作了测定和评价。实验表明，用优化的镀液配方和工艺可获得含ＰＴＦＥ粒子２５～３０％ｖｏｌ的ＮｉＰＰＴＦＥ复合镀层。这种镀层具有优良的结合力和良好的耐蚀性，其硬度随ＰＴＦＥ含量增加而降低，其特别突出的性能是优异的减摩性和耐磨性，是一种具有自润滑功能的表面复合材料。     

钛酸酯催化环氧树脂固化动力学研究

用FTIR“原位”技术,研究了钛酸酯(Tc-114)偶联剂对环氧E-44和二氨基二苯基甲烷(DDM)固化反应的催化作用,得出固化程度与时间的关系曲线。又根据DSC曲线,分别算出加有Tc-114和不加Tc-114的两个固化体系的反应表观活化能和反应级数。结果表明,Tc-114的存在使环氧固化反应活化能降低,催化作用明显。     

Advanced Coatings on Furnace Wall Tubes

Nickel-based self-fluxing alloy coating extends the service life of furnace wall tubes at waste incineration plants due to its excellent corrosion resistance and heat resistance. Fusing of such coatings by induction heating offers improved efficiency and reliability of products. Compared with conventional plasma, flame, and high-velocity oxy-fuel spraying thermal-sprayed coatings, induction-fused coatings provide a far stronger metallurgical bond at the interface, while minimizing the inclusion of pores. In addition, the tubes are less costly than those with welded coatings, and the process reduces the distortion of the products, facilitating easier final assembly. A successful experimental application of 11 units in a waste incinerator revealed virtually no corrosion on the exposed surfaces, and showed an improved water heating efficiency over that of the original tubes. Such units are now being employed in four incinerators in Taiwan, and continuing tests are showing great promise.     

UV-固化光纤色标油墨

报导了一类新型的化学功能材料———ＵＶ固化光纤色标油墨。该材料由可ＵＶ固化的有机硅环氧安息香酸丙烯酸酯（ＳＥＢＡ）和脂环族环氧丙烯酸酯（ＡＣＥＡ）两种光敏预聚物为基料，以自行合成的光敏染料———分散红氨基甲酸酯丙烯酸酯（ＲＵＡ）、分散蓝氨基甲酸酯丙烯酸酯（ＢＵＡ）和吖啶黄氨基甲酸酯丙烯酸酯（ＹＵＡ）为着色剂，加入必要的添加剂配制而成的ＵＶ固化光纤色标油墨。该色标油墨已在光纤生产中得到应用。     

Evaluation of different coating systems by electrochemical methods

Corrosion protection of organic coated steel is determined by free corrosion potential measurements and impedance spectroscopy. The results are classified by means of very basic considerations and evaluation figures are developed. These electrochemical data are correlated with the extent of the corrosion for each coating system. The evaluation figures are used for ranking coating systems and this ranking is correlated with the ranking with reference to the results of standardized and exposure tests.     

改性己二胺制备TG301环氧树脂室温固化剂

已二胺经与环氧树脂进行羟烷基化及与丙烯腈进行氰乙基化反应达到改善低熔点低毒性．低脆性的综合效果．文中介绍了改性乙二胶固化剂的制备方法，质量指标和有关固化特性等．