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31.
Magnetorheological materials have been used in many applications in recent years. To develop new materials, polyurethane and silicone polymer gels were investigated. Rheology is qualitatively controlled for each system by controlling the concentration of reactants and diluents. The resulting polymers have solid, gel, or liquid states, depending on the crosslinking and dilution. The gels were characterized through kinetic analysis. Differential scanning calorimetry (DSC) was used with analysis methods to find the kinetic properties for diluted and undiluted polyurethane systems. Heat of reaction, order of reaction, preexponential constant, and activation energy were obtained from the experimental DSC data. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2733–2742, 2002 相似文献
32.
A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the Tm and Tc of microPCMs were in the range of 29.8–31.0oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006 相似文献
33.
利用差示扫描量热仪、傅里叶红外光谱仪、广角X射线衍射仪研究了一种新型的以聚乙二醇为软段的聚氨酯相变储能材料。结果表明,当软段含量低于90%(质量分数,下同)时,即使温度高于聚乙二醇的熔点,此类材料仍不会熔化成液体,而表现出一种固-固相变行为。该聚氨酯储能材料相变焓较大,相变温度适中,且随着软段含量的减少,材料相变焓和相变温度呈递减趋势。其相变过程实质是聚氨酯软段聚乙二醇由结晶固态转变为无定形固态的过程。 相似文献
34.
35.
A series of polyesters was prepared to evaluate hydrolytic stability as a function of cyclohexyl dibasic acid content. The
three cyclohexyl dibasic acids: 1,2; 1,3; and 1,4 were formulated into polyesters with two glycols. The proportion of cis
and trans isomers was evaluated via 1H NMR. The hydrolytic stability of short chain polyesters was evaluated in an acetone/water mixture which solubilized the
polyesters to mimic oligoester behavior within a thermosetting polyester coating environment. The rate of hydrolysis was monitored
by acid titration and corroborated by GPC. Surprisingly, 1,2-cylohexyl diacid-based polyesters were robust, and 1,3-cyclohexyl
diacid-based polyesters were the most susceptible to hydrolysis. Evidently, a 1,2-anchimeric effect for cyclohexyl dibasic
acid polyesters was not an important consideration, while the 1,3-cyclohexyl ester interaction was. Consequently, an anomeric
effect was proposed.
Presented at the 81st Annual Meeting of the Federation of Societies for Coatings Technology, November 12–14, 2003, in Philadelphia,
PA. 相似文献
36.
A series of novel block polymers of polyurethane (PU) and chitosan have been prepared in two steps. The first step is the preparation of PU prepolymer, obtained from polytetramethylene oxide glycol (PTMO, Mn = 1000), isophrone diisocyanate (IPDI), and 2,2′-dimethylol propionic acid (DMPA), followed by ionizing PU prepolymer with triethylamine (TEA). The second step involves PU chain-extended by water-soluble chitosan of low molecular weight (Mn = 5000) by self-emulsion polymerization method. The sizes of the latex particles, morphology, and copolymer architecture have been characterized by dynamic light scattering (DLS), general tensile test, infrared spectroscopy (IR), surface contact angle measurement, and transmission electron microscopy (TEM). Furthermore, it shows that the addition of chitosan remarkably increases anticoagulative property of PU elastomers confirmed by the recalcification time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
37.
贮存稳定的聚氨酯干式复合胶粘剂的研究 总被引:4,自引:0,他引:4
研制了一种具有高固含量、低粘度的干式复合用双组分聚氨酯胶粘剂,考察了聚酯多元醇,扩链剂丙三醇/乙二醇(摩尔比)、NCO/OH(摩尔比),双组分胶配比以及缓凝剂等因素对该胶粘剂性能的影响,并用红外光谱对胶的固化过程进行了表征。结果表明,该胶粘剂具有较高的粘接强度,优良的低温流动性和贮存稳定性。 相似文献
38.
39.
This paper presents a novel process for the fabrication of pultruded polyurethane (PU) composites. The effects of the processing parameters on the mechanical properties (flexural strength and flexural modulus, etc.) and thermal properties (HDT) of the fibre reinforced PU composites by pultrusion have been studied. The processing parameters investigated include pulling rate (in-line speed), die temperature, filler type and content, and post-cure time and temperature. Results show that the composites possessed various optimum pulling rates at different die temperatures. On the basis of the DSC diagram, the swelling ratio, the mechanical properties and the thermal properties of composites, the optimum die temperature can be determined. It is found that the mechanical and thermal properties increase with filler content for various types of filler. The mechanical and thermal properties increase at a suitable post-cure temperature and time. Furthermore, the properties which decreased due to the degradation of composite materials for a long post-cure time will be discussed. 相似文献
40.
蒙脱土-有机硅复合改性硅烷化聚氨酯密封胶 总被引:2,自引:0,他引:2
采用2,4-甲苯二异氰酸酯、聚醚多元醇、蒙脱土、有机硅(α,ω-二羟基聚二甲基硅氧烷)和硅烷偶联剂为原料,制备了有机蒙脱土/聚醚多元醇复合物(OMMT/330N)-有机硅复合改性的硅烷化聚氨酯(SPU)密封胶。通过广角X射线衍射、透射电子显微镜和傅里叶变换红外光谱手段表征了蒙脱土在复合材料中的分散情况,表征结果显示,有机蒙脱土以平均层间距不小于4.12nm的宽分布分散在SPU基体中。同时对密封胶的力学性能进行测试,测试结果表明,经OMMT/330N-有机硅复合改性的SPU密封胶具有性能互补效果,当添加质量分数为5%(基于330N)的OMMT和8%的有机硅时,复合改性的SPU密封胶的拉伸强度和断裂伸长率比纯SPU密封胶提高了65.8%和71.6%。 相似文献