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51.
An FTIR experiment especially designed to study the growth of an organosilane layer at the interface between a solution and a flat silica surface is presented. High sensitivity is achieved by using the attenuated total reflection (ATR) technique in a liquid flow cell. The ATR crystal, either silicon or germanium, is covered with a very thin silica layer. Chemical reactions of a mono-and a di-hydrolyzable silane with the silica substrate have been investigated. The grafting of a submonolayer of the first reagent has been monitored by following the C-H and SiO-H vibrations. The density of grafted molecules has been estimated and information on the nature of the chemical bonding has been achieved. Evidence for the chain-polymerization of the dihydrolyzable silane at the substrate/solution interface has been inferred from the appearance of a Si-O-Si absorption band. 相似文献
52.
钻井工程固井胶结界面研究现状 总被引:8,自引:4,他引:4
固井质量问题在石油勘探开发中备受关注,对特殊工艺井钻井、油水井开采寿命和勘探开发效益有直接的影响。对固井胶结界面的研究是从根本上提高固井质量的一项基础性研究工作。为了推动固井胶结界面研究工作的开展,分析了国内外近年来有关固井界面研究的文献,阐述了开展固井胶结界面基础研究工作的意义,着重分析了这一研究领域目前所采用的研究方法,以及提高固井界面胶结强度的主要途径。在分析文献的基础上,提出今后深入开展固井界面研究工作的重点是:1)继续完善研究方法;2)重视动态研究;3)从胶结界面的微观结构和钻井工程整体系统的角度开展研究工作;4)注重改善胶结界面水化产物的微观结构和钻井工作液之间的协调增强作用。 相似文献
53.
原木板材的窑式干燥 总被引:1,自引:0,他引:1
R.B.Keey 《武汉化工学院学报》1992,(Z1)
本文综述了canterbury大学近年来关于新西兰木材窑式干燥的研究。有些硬木单纯窑式干燥是困难的,但利用太阳能窑式风干则有可能;轮回操作可以减小干燥应力从而减小产品性能的退化程度。种植生产为主的软木干燥较容易,从经济考虑应采用高温干燥,以减少干燥时间。高温操作时对流传递显得相当重要。实验表明,当空气流过板面时,不同点处的传质系数有显著差异。湿分在木板中移动的模型可假定为:随着干燥进行蒸发面向中心退缩。但心材和边材的行为有所不同:边材中的水份可在相邻脉管间迁移,但在心材中则不可能。正是这种差异导致干燥时间和干燥温度曲线不同。 相似文献
54.
In this work a treatment for surface preparation to improve mechanical resistance in adhesive bonding of plastic composites reinforced with fibres and metallic material, has been performed using an excimer laser. The following couplings have been selected to reproduce joints commonly used in the aerospace and automotive industry: CFC (carbon fibre composite) with CFC, CFC with Al 2024T3, Al 99% with Al 99%, GFC (glass fibre composite) with zinc-coated sheet in low carbon steel FeP01. The surfaces have been prepared using an excimer laser, adopting several values of laser parameters. The obtained surfaces have been examined by optical and scanning electron microscope: comparative measures of wetting and roughness have been performed to obtain an accurate characterisation and to select the proper finishes suitable to improve the mechanical resistance of the joints. The results obtained show that laser treatment always improves the final resistance of the joint; notable increases, and no significant surface damages have been highlighted. Better results have been obtained with the Al 99% with Al 99% joints which, with a low number of pulses treatment, have shown an increase of mechanical resistance up to the 70%. 相似文献
55.
项敏 《网络安全技术与应用》2012,(4):66-68
本文介绍了网卡绑定技术在音频工作站网络中的应用和实施,解决了网络存在的现实问题,给进一步完善安全播出提供了新途径。 相似文献
56.
Ibrahim M. Alarifi 《乙烯基与添加剂工艺杂志》2021,27(1):77-88
This study aims to examine the morphology and mechanical properties (tensile, flexural, and compressive) of epoxy composites reinforced with epoxy date palm leaves (EDPL), epoxy date palm branch (EDPB), and epoxy/hardener date palm core shell (EDPC) fibers (particle size <1 μm depend on the date palm fibers). A three-step technique was used to obtain the composites. The EDPL composites showed a maximum tensile strength of 3.45 MPa, while the EDPB composites showed maximum compressive and flexural rigidity of 9.46 and 5.55 MPa, respectively, owing to the good compatibility of fiber-matrix bonding. In this work, epoxy composites reinforced with date palm fibers (DPF) leaves, branches, and core shell were recycled using a cost-effective and easily reproducible three-step technique. EDPC fibers fabricated with 64.65% weight carbon fibers content demonstrated improved tensile strengths and stiffness properties. The three samples of palm date composites revealed mechanical properties that could be used to trial these fibers for manufacturing purposes, and to exploit their extraordinary mechanical properties shown in current results. 相似文献
57.
退火温度对Ag/Cu层复合板分离强度的作用 总被引:3,自引:0,他引:3
对轧制复合的Ag Cu双金属薄板采用不同温度的退火处理 ,研究了结合面分离强度随退火温度变化的规律 ,讨论了影响分离强度的因素。结果表明 ,在 40 0℃以下随退火温度的升高 ,由于原子扩散及再结晶晶界的形成趋于充分而导致分离强度升高 ,40 0℃时分离强度达到最大值。当退火温度超过 40 0℃后 ,由于结合面的异类原子不等量对流而导致结合面形成空洞 ,从而使分离强度下降。 750℃退火时分离强度达到最低值。退火温度进一步上升到 80 0℃时可使结合面发生局部熔合 ,使分离强度又有小幅度回升 相似文献
58.
59.
Within the bonded interface of metal bars joint produced by conventional solid state bonding process ( such as flash welding, resistance butt welding, friction welding and so on), the inclusions are often present, which degrade the ductility of joint. A new process of transformation-diffusion brazing is proposed, in which an amorphous foil containing melting point depressant is preplaced between the interfaces to be joined, and the assembly is repeatedly heated/cooled without holding time at peak temperature. A low carbon steel bars, BNi-2 amorphous foil and resistance butt welding machine were used. The results show that surfuce contamination can be disrupted by the dissolution of base metal into molten interlayer in comparison with conventional process, and the ductility of joint can be improved by increasing the times of temperature cycles on line. In addition, transformation-diffusion brazing can be done with relatively simple and inexpensive system in comparison with transient liquid phase bonding. 相似文献
60.
Crosslinking modification can effectively improve the water resistance of soy protein isolate (SPI) adhesive, but it often depends on petroleum-based reagents, violating the concept of green environmental protection. Here, inspired by the breaking and recombination of the disulfide bond in the perm process, a high-performance wood adhesive is prepared by incorporation of SPI (modified by sodium sulfite to cleave the disulfide bonds of protein chains) and feather keratin (FK, extracted from waste chicken feathers by breaking the disulfide bond) without using any other crosslinkers. The crosslinking reaction occurs by disulfide bonds derived from the sulfhydryl group of FK and SPI. Thus the wet shear strength of the SPI/FK-20 adhesive is improved from 0.57 to 1.18 MPa, an increment of 107%. This study provides a green strategy to prepare high-performance protein-based adhesive from the waste products-chicken feathers, which will contribute to the development of the environmentally friendly wood adhesive industry. 相似文献