重金属污染物动态吸附试验及数学模拟

本文采用泥沙动力学中Ｒｏｕｓｅ等人用来研究泥沙浓度沿垂线分布的装置。对泥沙吸附重金属污染物进行了动态模拟。试验分有底泥和无底泥两种情况。研究中发现在Ｒｏｕｓｅ装置的水力、泥沙条件下泥沙吸附重金属污染物达到平衡状态需要６小时以上，由极坐标下的重金属迁移转化数学模型方程，在本文具体试验条件下进行数值求解，计算结果和试验结果合良好，说明数学模型是正确合理的试验是可靠的。计算时依据室内静态试验结果，对动态     

载体及反应条件对Pt/BaKL沸石催化剂芳构化性能的影响

研究了γ-Al_2O_3或SiO_2载体,以及反应条件对Pt/BaKL沸石催化剂芳构化性能的影响。发现经过碱化或负载Sn的γ-Al_2O_3作为载体,能够较好地保持该催化剂在正己烷芳构化反应中的高活性和高选择性,并有益于改善Pt/BaKL沸石催化剂的抗硫性能。     

Nitrogen dioxide effect in the reduction of nitric oxide by propane in oxidizing atmosphere

The role of nitrogen dioxide in the selective reduction of NO by propane over a Cu-MFI zeolite is investigated. NO₂ and NO reductions were carried out under similar conditions of reaction. In the presence of oxygen, the reduction of NO by C₃H₈ does not differ significantly from that of NO₂. In the absence of oxygen, the reduction of NO₂ by propane occurs with a partial decomposition of the nitric dioxide molecule. Such a decomposition leads to the formation of oxygen, which is responsible for the increase in catalytic activity by comparison with the same reaction performed with NO. NO₂ formed and released in the gas phase during the reduction of NO by propane in the presence of oxygen does not play a predominant role in the catalytic process.     

吸附法脱除乙烯中少量氧气的吸附剂研究

采用重量法在电子天平上研究了Ｃ２Ｈ４和Ｏ２单组份在５Ａ、１３Ｘ、丝光沸石和碳分子筛等不同吸附剂上的吸附平衡性质和扩散动力学性质。结果表明，在沸石类吸附剂上，Ｃ２Ｈ４的平衡吸附量远大于Ｏ２的平衡吸附量，Ｃ２Ｈ４的吸附扩散速率也大于Ｏ２的扩散速率；在碳分子筛吸附剂上Ｃ２Ｈ４的平衡吸附量大于Ｏ２的平衡吸附量，但Ｏ２的吸附扩散速率远大于Ｃ２Ｈ４的扩散速率，其扩散系数是Ｃ２Ｈ４的２３９倍。单柱评价结果表明，Ｃ２Ｈ４－Ｏ２混合组份通过该碳分子筛吸附剂时，Ｏ２的破点时间长，Ｃ２Ｈ４的纯度可达１００％。加压有利于选择吸附Ｏ２，而且加压吸附、常压脱附再生性能好。该碳分子筛是脱除高浓度乙烯中少量氧气的理想吸附剂。     

Optimizing Naphtha Utilization Based on Molecular Scale Management

The technology of separating normal paraffins from naphtha through adsorption using 5A molecular sieves was studied. The separation efficiency of the normal paraffins was above 99.99%. Using the desorption oil as the feedstock of steam cracking, the ethylene yield increased from 29.7-35.0% to 41.4-49.2% compared to that of the naphtha. The research octane number of the raffinate oil reached more than 85 units with an increase of 20 units compared to that of naphtha.     

超细分子筛材料的合成与应用研究进展

综述了近几年超细分子筛的合成与应用方面的研究进展,重点介绍了几种常用且研究较多的分子筛,主要包括Y,ZSM-5,β,Silicalite-1,ZSM-35,MCM-22等分子筛。对超细分子筛的合成方法及其在石化、环保和生物等领域的应用进行了介绍,并对分子筛复合材料的研究及应用的最新动态进行了评述,说明超细分子筛材料的应用领域仍在不断拓宽,超细分子筛复合材料的研究将会成为分子筛材料领域未来的重要发展方向。     

Propane conversion over zeolite catalysts: Comments on the role of Ga

The activation of propane using zeolite H-Y and Ga³⁺ exchanged zeolite Y indicates that in the presence of Ga³⁺ the mechanism of propane activation is changed from a cracking pathway to a dehydrogenation pathway. The presence of both Ga³⁺ and H⁺ are required to achieve this effect.     

IR spectroscopic study of Pt/Kl zeolites using adsorption of CO as a molecular probe

FTIR spectra of CO adsorbed on Pt/KL catalysts show that the relative band intensities and the total dispersion markedly depend on the catalyst preparation method (ion exchange, incipient wetness impregnation or co-impregnation with KCl). The CO stretching frequency of the dominant band for linear CO is shifted to higher wavenumbers, parallel with the proton concentration in the reduced catalyst, which is derived independently from the intensity of the IR bands of the OH groups. The results are in accordance with the model that electron-deficient platinum particles are platinum-proton adducts.On leave from: N.D. Zelinsky Institute of Organic Chemistry, Academy of Sciences, Moscow, USSR.     

天然高分子吸附剂研究Ⅱ．镍离子模板壳聚糖树脂的合成及特性

以镍离子为模板剂，合成了乙醇双环氧丙基醚交联的壳聚糖树脂，研究了其对Ｃｕ（Ⅱ）、Ｎｉ（Ⅱ）、Ｃｏ（Ⅱ）离子的吸附性能。结果表明，该法合成的树脂对Ｎｉ（Ⅱ）离子具有较强的“记忆”和“识别”能力，其对Ｃｕ（Ⅱ）、Ｎｉ（Ⅱ）、Ｃｏ（Ⅱ）的吸附量分别达２．２１、２．１３、１．４０ｍｍｏｌ／ｇ树脂。     

多层气敏薄膜表面吸附及界面扩散的研究

制备了ＳｎＯ３／ＺｎＯ及ＺｎＯ／ＳｎＯ３多层结构的气敏薄膜，用能谱结合氩离子刻蚀的方法及Ｘ射线衍射法，对薄膜的表面吸附。膜间的相互与组成等进行了研究，结果表明：薄膜表面存在少量的吸附多层膜中锌的扩散远比锡一个模型，对吸附现象作了初步的解释，讨论了造成锌锡扩散的原因。