C60辅助下ZnNiS光催化分解水制备氢气的研究

通过在光催化剂掺杂ZnS中加入球笼化合物富勒烯C60,提高了光催化水分解的效率.并采用气相色谱法跟踪反应,发现氢气释放量是未加C60时的4倍多.同时,对该催化反应的机理进行了初步的探讨.     

固定化微生物脱除工业酸性废气中H_2S的研究

以H 2软性填料作为氧化亚铁硫杆菌的固定化载体 ,构成了固定床生物反应器。在一定操作条件下 ,考察了固定床生物反应器对Fe2 +的氧化速率 ,最大可达 7.6 7g/ (L·h)。并对固定床生物反应器运行中在载体表面形成的络合物进行了研究 ,X射线衍射证明此络合物为黄钾铁矾 [KFe3(SO4 ) 2 (OH) 6]。     

Simultaneous sulfide and acetate oxidation under denitrifying conditions using an inverse fluidized bed reactor

BACKGROUND: Simultaneous removal of sulfur, nitrogen and carbon compounds from wastewaters is a commercially important biological process. The objective was to evaluate the influence of the CH₃COO^?/NO₃^? molar ratio on the sulfide oxidation process using an inverse fluidized bed reactor (IFBR). RESULTS: Three molar ratios of CH₃COO^?/NO₃^? (0.85, 0.72 and 0.62) with a constant S^2?/NO₃^? molar ratio of 0.13 were evaluated. At a CH₃COO^?/NO₃^? molar ratio of 0.85, the nitrate, acetate and sulfide removal efficiencies were approximately 100%. The N₂ yield (g N₂ g^?1 NO₃^?‐N consumed) was 0.81. Acetate was mineralized, resulting in a yield of 0.65 g inorganic‐C g^?1 CH₃COO^?‐C consumed. Sulfide was partially oxidized to S⁰, and 71% of the S^2? consumed was recovered as elemental sulfur by a settler installed in the IFBR. At a CH₃COO^?/NO₃^? molar ratio of 0.72, the efficiencies of nitrate, acetate and sulfide consumption were of 100%, with N₂ and inorganic‐C yields of 0.84 and 0.69, respectively. The sulfide was recovered as sulfate instead of S⁰, with a yield of 0.92 g SO₄^2?‐S g^?1 S^2? consumed. CONCLUSIONS: The CH₃COO^?/NO₃^? molar ratio was shown to be an important parameter that can be used to control the fate of sulfide oxidation to either S⁰ or sulfate. In this study, the potential of denitrification for the simultaneous removal of organic matter, sulfide and nitrate from wastewaters was demonstrated, obtaining CO₂, S⁰ and N₂ as the major end products. Copyright © 2008 Society of Chemical Industry     

Sensitometric characteristics of an all‐solid‐state photoelectrochromic pixel for an electrochromic light‐addressable display

Abstract— An all solid‐state photoelectrochromic element (PECE) was developed on the basis of electrochromic layers of WO₃ and polyaniline with a layer of polymer electrolyte placed on a base of polyamidosulfoacid, in which a thin‐film CdS_xSe_1?x photoresistor was used as an electronic key. The dependence of the sensitometric characteristics of the PECE on the applied voltage was studied.     

不同锌钛比对纳米钛酸锌（ZnO—TiO2）体系成分的影响

以工业偏钛酸、硫酸锌、氨水为主要原料，用直接沉淀法并进行热处理得到钛酸锌粉体，并用XRD对产物成分进行了检测。结果表明，不同的锌钛比对钛酸锌（ZnO-TiO2）体系的成分有较大影响。     

氧化铝/锌合金复合材料界面的SEM观察

利用挤压铸造制备氧化铝／锌合金复合材料，在扫描电镜（ＳＥＭ）上观察复合材料的界面。结果表明，在复合材料中纤维与基体间存在致密界面层，合金元素通过适当的化学反应可改善纤维与基体间的结合；在凝固过程中，纤维／基体界面上的硅在共晶体的共生生长过程中起了领先相作用，导致复合材料的共晶转变是由铝硅共晶转变和锌铝共晶转变两者组成。     

钻井过程中硫化氢的处理工艺

目的：防止钻井过程中出现的硫化氢对人身安全和钻具造成危害。方法：分析氢脆破坏机理和处理硫化氢的化学原理。结果：提出了处理硫化氢的关键技术，并结合塔中162井的实钻经验，总结出了钻井过程中对硫化氢的几点认识。结论：提高泥浆pH值、加入除硫剂及提高泥浆密度等措施是钻井过程中处理硫化氢的关键技术，从而有利于富含硫化氢的灰岩、白云岩等裂缝性油气藏的钻井生产。     

Organic Electroluminescent Thin Film Using 8—hydroxyquinoline Zinc as Emitting Layer

Organic electroluminescent thin film using Znq2(Znq2) as the emitting layer material with structure of glass/ITO/Znq2/Al(cell) was fabricated.The V-I curve ,V-B curve and electroluminescent spectra of the cell were measured.Meanwhile the fluorescent spectra, excited spectra and absorption spectra of Znq2 with power and film states were also measured.     

3#大布袋收尘器更新改造方案的探讨

通过对3^#大布袋收尘器更新改造方案的对比分析，探讨适合工艺条件的最佳收尘器的选择途径。     

ZRS-6.72-3型电收尘器技术改造

ZRS-6．72—3型电收尘器原设计用于13．8kt／a锌冶炼烟气收尘制酸工艺中，因电收尘器使用时间长，电源控制柜故障率高和沸腾炉扩大更新，对电收尘器同步进行配套技术改造。改造为CRS-8．24—3型电收尘器后，又陆续使用了HL-Ⅲ型恒流源控制电柜，投产后的电收尘器具有收尘效率高、电场运行稳定等特点。