Synthesis of Chelating Resin PETU and Its Adsorption to Ag(I)

A novel chelating resin (PETU) with thiourea groups in its main chain was synthesized by the reaction of O,O'-butane-1,4-diyl dicarbonisothiocyanatidate and triethylene tetraamine. The adsorption of Ag(I) on PETU was investigated by batch tests. The results showed that adsorption data fitted Boyd's diffusion equation of liquid film and the adsorption was controlled by liquid film diffusion. Under the temperatures between 15~60℃, the adsorption capacity decreased with the increase of temperature, and increased with the increase of initial concentration of Ag(I). The experimental data fitted Langmuir and Freundlich equations, and the correlation coefficients for Langmuir equation were between 0.9965~0.9998, and those for Freundlich equation were between 0.8211~0.9810, and increased with the adsorption temperature. DH, DG and DS calculated by thermodynamic formulae were all negative, which meant that the adsorption process was exothermic and spontaneous, and the entropy decreased during the process. XPS results showed that N, S and O atoms were the electron donors to coordinate with Ag.     

DOC-Ⅰ降烯烃催化剂小型提升管反应性能评价

采用小型提升管催化裂化试验装置评价研制的DOC-Ⅰ降烯烃催化剂的催化裂化反应性能。结果表明,在反应温度500 ℃、剂油质量比6和停留时间1.99 s条件下,DOC-Ⅰ催化剂上原料油的转化率达75.01%,较参比催化剂提高1.79个百分点,相应的液化气产率降低0.28个百分点,汽油产率增加2.9个百分点,烯烃含量下降5.21个百分点,异构烷烃和芳烃含量明显增加,产品分布有效改善。表明研制的DOC-Ⅰ催化剂具有较好的催化裂化性能和降烯烃能力。     

Ⅰ型轨道板预制施工工艺与造价分析

结合石太客运专线Ⅰ型轨道板预制的成功经验,对轨道板预制的模型安装及要求、钢筋加工、混凝土施工及养护、预应力施工、轨道板存放等关键技术以及轨道板的造价组成进行了深入详细的剖析,为今后的客运专线Ⅰ型轨道板的推广应用提供有益的参考。     

乙醇－水在疏水硅沸石表面上的吸附分离

研究不同温度下乙醇在不含Ｓｉ－ＯＨ基团的疏水硅佛石（Ｓｉｌｉｃａｌｉｔｅ－Ⅰ）表面上的吸附等温线及脱附等温线。计算出硅沸石上乙醇的吸附热及脱附活化能分别为４９．４ｋＪ及１４．９ｋＪ／ｍｏｌ。疏水硅沸石吸附剂或硅沸石填充硅橡胶分离膜能有效地从稀乙醇－水的混合液中，或从发酵产生的啤酒中分离、浓缩乙醇。     

塔中Ⅰ号坡折带上奥陶统礁滩型储层发育特征及其主控因素

塔中Ⅰ号坡折带上奥陶统发育大型台缘礁滩复合体,具有小礁大滩的结构特征,多旋回礁滩体纵向多期加积叠置、横向复合连片。静态和动态资料表明礁滩复合体基质孔隙度低,属低孔特低渗储层,以孔洞-裂缝型、洞穴型、孔洞型储层为主,次生的溶蚀孔洞和构造裂缝是礁滩复合体最有效的储、渗空间。研究表明,有利沉积相带是礁滩型储层发育的基础,优质储层主要沿台缘礁滩相展布,岩溶作用和构造作用是古老碳酸盐岩储集性能改善的关键,所形成的大型缝洞系统是油气高产稳产的主要原因。     

大渡河枕头坝一级水电站鱼道设计研究

枕头坝一级水电站位于大渡河干流上,为减缓工程对鱼类的不利影响,提出了修建鱼道来改善大坝上下游鱼类种群交流.枕头坝一级水电站鱼道工程设计总长1 241.74 m,是目前国内已建和在建规模最大的鱼道工程.在鱼类游泳能力测试和水力学模型试验的基础上,对鱼道的过鱼对象、鱼道建筑物设计进行了研究.最终确定,枕头坝一级水电站采用单侧竖缝式鱼道,鱼道内过鱼孔流速建议为1.10～1.25 m/s;进口流速应大于0.15～1.3 m/s;鱼道设置3个进口,并增设诱鱼系统;还在鱼道进口和出口分别设置1个观察室,以便指导调整鱼道运行方式.     

核电站暖通系统仪表的抗震试验程序和方法

本文介绍了暖通系统的仪表抗震试验的试验目的、试验程序和实施方案及合格判定要求，分别从抗震仪表分类、试验步骤、试验方法和功能评价等方面进行阐述，为核电站仪表或设备的抗震试验提供一定的试验思路和借鉴指导。抗震鉴定试验表明，被试仪表具有足够的强度抵抗设计地震载荷，试验中及试验后被试仪表结构完整并且运行功能完好，满足暖通系统对此类仪表的抗震Ⅰ类的抗震要求。     

钛合金Ⅰ型裂纹应力强度因子测试的实验研究

采用疲劳裂纹预制机对含I型缺口的TC4合金试件预制裂纹，通过数字图像相关方法观测试件在三点弯曲加载条件下裂纹的扩展过程及裂尖区域的位移场，将位移场数据带入裂尖位移场方程，计算裂尖位置和应力强度因子。结果表明，采用该方法可以准确测定钛合金的I型裂纹应力强度因子、裂尖位置及裂纹扩展长度。该方法解决了以往研究中因不能准确测定裂纹尖端位置，而无法准确测定钛合金I型裂纹应力强度因子的难题     

Mode-Ⅰ fracture and durability of FRP-concrete bonded interfaces

In this study, a work-of-fracture method using a three-point bend beam (3PBB) specimen, which is commonly used to determine the fracture energy of concrete, was adapted to evaluate the mode-Ⅰ fracture and durability of fiber-reinforced polymer (FRP) composite-concrete bonded interfaces. Interface fracture properties were evaluated with established data reduction procedures. The proposed test method is primarily for use in evaluating the effects of freeze-thaw (F-T) and wet-dry (W-D) cycles that are the accelerated aging protocols on the mode-Ⅰ fracture of carbon FRP-concrete bonded interfaces. The results of the mode-Ⅰ fracture tests of F-T and W-D cycle-conditioned specimens show that both the critical load and fracture energy decrease as the number of cycles increases, and their degradation pattern has a nearly linear relationship with the number of cycles. However, compared with the effect of the F-T cycles, the critical load and fracture energy degrade at a slower rate with W-D cycles, which suggests that F-T cyclic conditioning causes more deterioration of carbon fiber-reinforced polymer (CFRP)-concrete bonded interface. After 50 and 100 conditioning cycles, scaling of concrete was observed in all the specimens subjected to F-T cycles, but not in those subjected to W-D cycles. The examination of interface fracture surfaces along the bonded interfaces with varying numbers of F-T and W-D conditioning cycles shows that (1) cohesive failure of CFRP composites is not observed in all fractured surfaces; (2) for the control specimens that have not been exposed to any conditioning cycles, the majority of interface failure is a result of cohesive fracture of concrete (peeling of concrete from the concrete substrate), which means that the cracks mostly propagate within the concrete; and (3) as the number of F-T or W-D conditioning cycles increases, adhesive failure along the interface begins to emerge and gradually increases. It is thus concluded that the fracture properties (i.e., the critical load and fracture energy) of the bonded interface are controlled primarily by the concrete cohesive fracture before conditioning and by the adhesive interface fracture after many cycles of F-T or W-D conditioning. As demonstrated in this study, a test method using 3PBB specimens combined with a fictitious crack model and experimental conditioning protocols for durability can be used as an effective qualification method to test new hybrid material interface bonds and to evaluate durability-related effects on the interfaces.