Corrosion properties of plasma nitrided AISI 410 martensitic stainless steel in 3.5% NaCl and 1% HCl aqueous solutions

Samples of an AISI 410 martensitic stainless steel were plasma nitrided at a temperature of 420 °C, 460 °C or 500 °C for 20 h. The composition, microstructure and hardness of the nitrided samples were characterised using a variety of analytical techniques. In particular, the corrosion properties of the untreated and plasma nitrided samples were evaluated using anodic polarisation tests in 3.5% NaCl solution and immersion tests in 1% HCl acidic water solution. The results showed that plasma nitriding produced a relatively thick nitrided case consisting of a compound layer and a nitrogen diffusion layer on the 410 stainless steel surface. Plasma nitriding not only increased the surface hardness but also improved the corrosion resistance of the martensitic stainless steel. In the immersion test, nitrided samples showed lower weight loss and lower corrosion rate than untreated one. In the electrochemical corrosion tests, the nitrided samples showed higher corrosion potentials, higher pitting potentials and greatly reduced current densities. The improved corrosion resistance was believed to be related to the iron nitride compound layer formed on the martensitic stainless steel surface during plasma nitriding, which protected the underlying metal from corrosive attack under the testing conditions.     

Laboratory assessment of wear on nitrided surfaces of dies for hot extrusion of aluminium

A newly designed “block-on-cylinder” wear resistance testing rig, which allows testing at higher contact pressures than conventional testing methods, was used to elucidate the effect of an iron nitride compound layer (white layer) on the wear resistance of nitrided dies used for hot extrusion of aluminium (Al). The tested dies (AISI H13) with various nitrided microstructures were provided by different manufacturers of equipment for plasma and gas nitriding. The wear surfaces were analysed by SEM, BEC, micrography and roughness measurements. It was found that the iron nitride compound layer is chemically more stable against hot Al in comparison to die material. Deterioration of the compound layer begins with cracking, and as a consequence, its spalling from the nitrided surface. A high thickness of the compound layer combined with a low nitriding depth leads to its earlier spalling and vice versa. Due to the increased roughness at the removal sites, accelerated chemical attack by hot Al takes place. Comparative and simultaneous testing of two nitrided samples was carried out.     

Microstructural and chemical surface and rim zone changes of ferrite-perlite 42CrMo4 steel after electrochemical machining

Electrochemical machining is based on the anodic dissolution of most metals and generates high quality polished surfaces. However, ferrite-perlite 42CrMo4 steel reveals local optical changes at the surface after electrochemical finishing, such as a widely variable surface finish from shiny (reflective) to rough (dark) surfaces even after one processing step. The optical different surface areas of ferrite-perlite 42CrMo4 steel (AISI 4140) are studied by different electron microscopy techniques, x-ray diffraction and x-ray photoelectron spectroscopy to gain information about the local chemistry of the reaction layers and residual stresses of the rim zone. The results show that the rim zone for the different surface areas are about 50 nm–100 nm thick and contain oxygen. Selected area diffraction reveals the formation of iron(II/III) oxide (Fe₃O₄) and x-ray photoelectron spectroscopy confirms the formation of a mixed iron oxide (Fe_3-xO₄) with a variation of the oxidation state for both near-surface rim zones. Furthermore, the reflective surfaces reveal a homogeneous dissolution of ferrite and cementite lamellae whereas the rough surfaces show a preferred dissolution of cementite and an inhomogeneous dissolution of ferrite within the rim zone. X-ray diffraction measurements do not show any introduced residual stresses in the rim zone.     

Fatigue crack propagation behavior in AISI 304 steel welded joints for cold‐stretched liquefied natural gas (LNG) storage tank at cryogenic temperatures

AISI304 steel welded joints are used in cold‐stretched liquefied natural gas (LNG) storage tanks used for storing and transporting of liquefied gases. Compared with a conventional liquefied natural gas storage tank, a cold‐stretched liquefied natural gas storage tank has many advantages such as reduced thickness, light weight, low cost and low energy consumption. However, liquefied natural gas storage tanks can be subjected to alternative loads at cryogenic temperatures; thus, it is important to investigate the fatigue crack propagation behavior in AISI 304 steel welded joints at cryogenic temperatures. Specimens were machined from a cold‐stretched liquefied natural gas storage tank with a welding structure. The crack length was determined using compliance method and confirmed by examination with traveling microscope. Fatigue crack propagation rates were evaluated at various stress ratios and temperatures. The fatigue crack growth rate of all specimens a little appears the effect of stress ratio, but it has a great influence at a cryogenic temperature. The fatigue crack growth rate of longitudinal welded joint is the fastest at room and cryogenic temperature. Fracture mechanism in the specimen is examined using a scanning electron microscope.     

A sustainability comparison between drilling and milling for hole-enlargement in machining of hardened steels

Abstract

Hole-making is one of the most important processes of metal shaping domain. Although, drilling is a commonly used approach to cut holes in metallic parts, the process cannot be completed with the cutting action of one drill bit if the work material is hard and diameter of the hole is large. Usually, a drill having diameter equal to the required diameter of the hole is utilized to enlarge a predrilled hole of a smaller diameter. In this work, we have investigated sustainability of using another method of enlarging a pre-drilled hole, namely side and end milling and compared it with the drilling-based approach. The work material used in the study is a high carbon steel, which is heat-treated to two distinct levels of surface hardness. Besides process type and work material hardness, the other two parameters tested in the investigation are cutting speed and depth of hole. A total of 16 experiments were performed to generate data regarding the sustainability measures, namely hole surface roughness, specific cutting energy and tool wear. Process choice (drilling or milling) for hole-enlargement was found to possess a significant effect on all the measured responses. Analyses carried out on the experimental data revealed that although the drilling-based option led to an immensely better surface finish, the milling-based option performed better with respect to the other measures of economic and environmental sustainability.     

Niobium boride coating on AISI M2 steel by boro-niobizing treatment

In this study, niobium boride coating was applied on pre-boronized AISI M2 steel by the thermo-reactive deposition technique in a powder mixture consisting of ferro-niobium, ammonium chloride and alumina at 950 °C for 1-4 h. The coated samples were characterized by X-ray diffraction, scanning electron microscope and micro-hardness tests. Niobium boride layer formed on the pre-boronized AISI M2 steel was smooth, compact and homogeneous. X-ray studies showed that the phases formed on the steel surfaces are NbB, Nb₃B₂, FeB and Fe₂B. The depth of the niobium boride layer ranged from 0.97 μm to 3.25 μm, depending on treatment time. The higher the treatment time the thicker the niobium boride layer observed. The hardness of the niobium boride layer was 2738 ± 353 HV_0.01.     

Acoustic emissions during fracture toughness tests of steels exhibiting varying ductility

This investigation is primarily aimed at examining steels with varying ductility using characteristics of acoustic emission (AE). Four steels (AISI 1060, AISI 1080, SA333 grade 6 and AISI 304LN) were selected and their structure property relations were characterized using standard metallographic examinations, hardness and tensile properties. Fracture toughness of these steels was determined as per the guidelines of ASTM standard E1820 with simultaneous recording of AE signals. The results of these investigations have been used to demonstrate that: (a) nature of the variation of AE cumulative counts with time is different for linear and non-linear load–displacement plots, (b) synergistic analysis of the rate of change of cumulative energy, cumulative counts and intensity of AE signals provide the point of crack initiation in a material, and (c) fracture toughness of a material estimated using AE parameters is lower compared to that obtained by ASTM standard procedure.     

AISI8630钢泥浆泵排出缸失效分析及工艺改进

针对AISI8630钢锻件在实际生产中出现的锻造失效问题进行了研究。采用"EAF→LF→VD→铸锭"工艺冶炼AISI8630钢锭,钢锭锻造成泥浆泵锻件,经热处理加工后探伤发现密集性缺陷。通过化学成分、低倍分析和金相显微分析,对产生的缺陷进行分析研究。结果表明:宏观检测受检面有许多裂纹,将裂纹打开,发现断口存在明显的白点缺陷;近裂纹附近有灰色硫化物夹杂,存在明显的组织偏析现象,远离裂纹处的金相组织无明显差异。通过加强冶炼过程控制,对钢锭进行锻前消氢、消应力退火及锻后250℃以下缓冷处理等工艺优化,避免了白点缺陷的形成,并经现场验证得到合格产品。     

基于权重粒子群算法的工件铣削温度研究

为研究铣削加工中工件的温度分布规律,推导其热传导数学模型,提出应用权重粒子群算法(Weighted particle swarm optimization, WPSO)开展时变热流密度辨识的方法,并结合试验数据对AISI1045钢在特定工况下的温度分布情况进行分析。结果表明,铣削过程中的界面热流密度呈3个阶段的非线性变化;切削初期存在缓慢温升的平台期,渡过平台期后,工件与刀具相接触部分的温度急剧上升,最高温度可达到860 ℃左右;从试验结果与解析结果的对比来看,两者误差的最大值约为11.06%,结果基本吻合。研究表明所提出的方法可以较为准确研究铣削加工过程中工件的温度分布情况。     

Hardness properties and high-temperature wear behavior of nitrided AISI D2 tool steel, prior and after PAPVD coating

Wear experiments in the range of 25–600 °C have been conducted on samples of D2 tool steel in different conditions involving unnitrided, nitrided and nitrided and coated with Balinit^® A (TiN) and Balinit^® Futura (TiAlN) deposited industrially at Balzers (Amherst, NY, USA), by means of PAPVD. The results indicate that coating the nitrided D2 tool steel substrate with these two films gives rise to an improvement of 97% (TiN) and 99% (TiAlN) in the wear behavior at the test temperature of 300 °C, in comparison with the uncoated substrate. However, at a temperature of 600 °C, besides oxidation of the coatings, the mechanical strength of the substrate decreases giving rise to fracture and delamination of the films. At this temperature the uncoated substrate exhibited the highest resistance to sliding wear, presumably due to the formation of a well bonded surface glazed layer which gives rise to a significant reduction in the friction coefficient. The indentation experiments that were conducted with the nitrided steel substrate and the coated systems indicates that the nitriding process applied to the D2 steel prior to PAPVD coating provides a satisfactory load support which contributes to the improvement of the coated systems capability to withstand indentation loads at room temperature. In this regard, the coated system with a TiAlN coating displayed a better behavior than that shown by the system with a TiN coating. An experimental procedure is proposed in order to predict the hardness profile of the nitrided tool steel, along the cross section of the material, just from hardness measurements taken on the surface of the sample, employing different indentation loads.