Cu基体电镀Ni层表面渗Al组织及其形成机理

以纯Al粉为渗剂、NHCl4作为活化剂、鸡蛋清为粘结剂、Cu基体镀Ni层表面渗Al。研究经800℃保温12 h后的渗铝层的表面形貌、组织、厚度和截面元素分布,分析渗铝过程的机理。结果表明：渗铝处理后Cu-Ni界面结合良好。渗铝层组织为单一的富Al的Ni2Al3金属间化合物。渗铝层厚度为200μm,平均显微硬度HV达到1 100。Al的沉积和运输主要依靠AlCl2完成。     

Csf/Al复合材料热压缩变形力学行为的数值模拟

与长碳纤维增强铝基复合材料相比,短碳纤维增强铝基复合材料的最大优点是可以进行二次塑性加工。在复合材料塑性加工中,加工工艺参数对复合材料性能的影响很大。然而由于复合材料界面结构、成分的复杂性和微观性,实验研究无法给出定量的细节过程描述。文章借助数值模拟手段,全面细致地模拟了变形量、温度对复合材料塑性加工的影响,研究了塑性加工时复合材料的应力应变分布规律。实验结果表明,塑性加工时应变主要集中在纤维端部附近,全面进入屈服后纤维的受力随变形量的增加而缓慢增加,变形温度越高,纤维与界面的受力越小,变形越均匀,对保持纤维的长度和界面的性能越有利。     

A comparative study of surface integrity of Ti–6Al–4V alloy machined by EDM and AECG

The electrical discharge machining (EDM) process produces the recast layer with or without cracks on the surface that requires a remedial post-treatment in the manufacture of critical or highly stressed surfaces. One of the frequently used post-treatment processes is also the abrasive electrochemical grinding (AECG) and it has been widely used in the precision machining of difficult-to-cut materials due to an enhanced surface integrity and productivity. The aim of this study is to investigate improvability of surface integrity in terms of machining voltage, electrolyte flow rate and table feed rate parameters of AECG in EDMed Ti6Al4V alloy. Scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive spectrograph (EDS) and surface roughness measurement were performed to study the surface characteristics of the machined samples. Experimental results indicate that the AECG process effectively improves the surface roughness and eliminates the EDM damages completely by setting suitable grinding parameters.     

Electrochemical investigation of the iron-containing and no iron-containing AB5-type negative electrodes

The electrochemical behaviour of LaNi_3.55Mn_0.4Al_0.3Co_0.75−xFe_x (x = 0, 0.15, 0.55, 0.75) intermetallic compounds has been studied and presented [C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, Int. J. Hydrogen Energy 29 (2004) 307–311; C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, J. Alloys Compd. 360 (2003) 266–271; C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, J. Alloys Compd. 384 (2004) 249–253]. It has been deduced that the LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compound has interesting electrochemical properties. In this paper we present the electrochemical study of LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compound properties compared with the parent LaNi_3.55Mn_0.4Al_0.3Co_0.75 compound. Several techniques, such as, the chronopotentiometry, the constant potential discharge (CPD), the cyclic voltammetry (CV) and the linear polarization (LP) were applied to characterize these electrochemical properties. The electrochemical discharge capacity of the LaNi_3.55Mn_0.4Al_0.3Co_0.75 alloy increases to reach 294 mAh g⁻¹ after few cycles only (five cycles). However, the activation of the LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 alloy takes more than 20 cycles to be achieved and the obtained maximum discharge capacity is 194 mAh g⁻¹. The hydrogen diffusion coefficient D_H was determined by constant potential discharge and cyclic voltammetry techniques. The obtained values of the LaNi_3.55Mn_0.4Al_0.3Co_0.75 and LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compounds are 6.29 × 10⁻¹¹ and 7.62 × 10⁻¹¹, and 2 × 10⁻⁸ and 7.5 × 10⁻⁸ cm² s⁻¹ by CPD and CV techniques, respectively. The exchange current density values, determined by a linear polarization technique, are 44 and 27 mA g⁻¹, respectively, for LaNi_3.55Mn_0.4Al_0.3Co_0.75 and LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 alloys.     

The oxidation of nanocrystalline Ni3Al fabricated by mechanical alloying and spark plasma sintering

Nanocrystalline Ni₃Al was fabricated through mechanical alloying of elemental powders and spark plasma sintering. The nanocrystalline Ni₃Al has a nearly full density after being sintered at 1223 K for 10 min under a pressure of 65 MPa. Isothermal and cyclic oxidations of nanocrystalline Ni₃Al were tested at 1173–1373 K with intervals of 100 K. The results indicate that nanocrystalline Ni₃Al exhibits excellent isothermal and cyclical oxidation resistance. The oxide scales consist primarily of dense and continuous -Al₂O₃. The grain refinement is beneficial for improving the oxidation resistance of Ni₃Al by providing more nucleation centers for the Al₂O₃ formation, promoting the selective formation of Al₂O₃ and improving the adhesion of oxide scales to the matrix.     

喷射成形60Si40Al电子封装材料的钎焊性能研究

喷射成形Si-Al（wSi=50％～70％）合金因其低的热膨胀系数、高的热导率和低的密度而成为一类新型的电子封装材料。但研究中发现，Si-Al合金的钎焊性能很差。本文采用在Si-Al合金基体上化学浸锌预处理后再行电镀镍镀层的方法，有效地改善了Si-Al合金的钎焊性能。     

卷绕铅酸电池泡沫铅负极电化学行为的研究

以泡沫铅作为负极集流体制备了卷绕VRLA电池.采用计时电流法、循环伏安曲线、电化学阻抗谱和充放电实验研究了泡沫铅负极的电化学行为,结果表明泡沫铅负极的真实表面积比铅箔负极的大,因此泡沫铅负极具有较低的过电势,并且不论是在怎样的放电状态下,泡沫铅负极的电化学反应电阻较小;与铅箔负极相比,在10、5和2小时率放电状态下,泡沫铅负极的质量比容量分别增加25.9%,30.0%和48.2%.此外,SEM观察显示,泡沫铅负极表面活性物质为更加细小的晶体颗粒和具有更高的孔率.     

Al2O3/Cu复合材料制备中的Cu2O-Al体系化学反应

对Cu2O与Al进行热力学分析后将其粉末压制成块,测试了不同温度下反应的热分析曲线,并对反应后的试样进行X射线衍射分析.结果表明Cu2O-Al体系化学反应包括3个阶段,即第1阶段体系温度T＜910 K,有少量Al2O3和Cu生成;第2阶段体系温度为910 K≤T＜1103 K,Cu2O-Al体系未发生化学反应;第3阶段体系温度为1103 K≤T≤1373 K,Cu2O-Al体系发生化学反应,其产物为Cu、Al2O3及CuAlO2.     

近净成形制备SiCp/Al复合材料Ⅱ:SiC预成形坯自发熔渗Z101

以超细SiC粉(W7)为原料制备的SiC多孔骨架为先驱体,采用无压渗透工艺制备出致密、增强体分布均匀的SiC/Al复合材料.SiC-Al间存在厚度为0.3～0.5 μm的界面层,该界面层能很好地被铝液润湿,并阻止铝液与SiC的接触与反应.SiC坯体渗入铝合金后无形状和尺寸的变化,能够实现制品的近净成形.加入SiC后,铝合金的强度显著提高,弹性模量提高近1倍.细颗粒的SiC能更好地抑制铝基体的热膨胀.材料的热学性能可通过SiC的含量来调整,SiC体积分数介于37%至54%之间时,室温导热系数介于136 W/(m.K)至118 W/(m.K)之间,室温至100 ℃的平均线热膨胀系数介于9.98×10.6 K.1至7.69×10.6 K.1之间.