热处理非晶态Ni-P合金镀层的晶化过程

运用电沉积的方法在45钢基体上制备Ni-P合金镀层,使用差示扫描量热法(DSC)和热重法(TG)分析非晶态NiP合金镀层在20℃/min加热速率下的热效应和质量变化。在300℃和400℃分别对镀层进行0,15,30,45,60,75min的热处理,采用扫描电镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、显微硬度计对镀层进行表征。结果表明:Ni-P合金镀层在加热过程中的放热峰出现在284.8℃处,镀层的质量和元素组成稳定;晶化过程经历了非晶态、亚稳态NiP和Ni5P2、稳定态Ni3P的转变;经过热处理后,镀层的显微硬度显著提高,最大值达1036.56HV,约为镀态的2倍;热处理态镀层的耐NaCl溶液腐蚀性能比镀态有所下降,但两者都比45钢基体好。     

半固态触变挤压对ZA27合金组织和力学性能的影响

通过与常规铸造方法的比较,研究半固态触变挤压对ZA27合金变质、热处理组织和力学性能的影响。结果表明:半固态挤压态合金的密度较铸态合金提高了3%,合金经Sc变质或者半固态挤压都获得了细小而均匀的近似球状组织,而Sc变质结合半固态挤压的球状组织具有最高的圆整度;经T6热处理的半固态挤压合金由细小的初生α相和共析(α+η)组织组成,说明半固态挤压可促进ε相溶解、减少三元共晶(β+η+ε)组织的含量。力学性能测试表明,ZA27合金经半固态挤压+Sc变质+T6热处理后其抗拉强度,伸长率和布氏硬度分别达到586.01MPa,17.57%及171HB。     

高熵合金氮化物薄膜的研究进展

基于多元高熵合金思想制备的高熵合金氮化物薄膜由于多种元素相互混合,易于产生高熵效应、晶格畸变效应和缓慢扩散效应,使得该新型薄膜体系形成简单的非晶结构和纳米晶结构。依赖于成分和制备工艺,多元高熵合金氮化物薄膜表现出简单的固溶体结构和优异的性能,因而在许多领域极具应用潜力。综述了高熵合金氮化物薄膜的发展概况、组织特点、性能特征、制备方法和应用前景,并对高熵合金氮化物薄膜的发展方向进行了展望。     

Electrochemical corrosion behavior of 2A02 Al alloy under an accelerated simulation marine atmospheric environment

The corrosion behavior of 2A02 Al alloy under simulated marine atmospheric environment has been studied using mass-gain, scanning electron microscope/energy dispersive spectroscopy (SEM/EDS), laser scanning confocal microscopy, X-ray diffraction spectroscopy and localized electrochemical methods. The results demonstrate that the relationship between the corrosion induced mass-gain and the corrosion time is in accordance with the power rule. The mass-gain increases gradually during the corrosion time, while the corrosion rate decreases. With ongoing of the corrosion, corrosion products film changed from a porous to a compact structure. The various spectroscopic data show that the corrosion products films composed mainly of Al(OH)₃, Al₂O₃ and AlCl₃. The electrochemical corrosion behavior of the 2A02 Al alloy was studied by electrochemical impedance spectroscopy (EIS).     

Rolling texture and its effect on tensile property of a near-α titanium alloy Ti60 plate

Rolling texture and its effect on tensile properties of Ti60 alloy plates were investigated in the present study. The plates wereβ-rolled at 1070℃ and(α+β)-rolled at 980℃, using uni-directionally rolling(UDR) and cross-directionally rolling(CDR) processes, respectively.β-rolled plates exhibited weak textures, which were attributed to the dispersive orientations of secondary α during the β→α phase transformation. Strong deformation textures formed in(α+β)-rolled plates as a result of slipping mechanisms: the strong T-type texture in UDR plate was related to {10 1 0}[11 2 0] slipping, while the B-type texture in CDR plate was relevant with {0001}[11 2 0] slip. Strong T-type textures led to anisotropic tensile properties. B-type textures would decrease such an anisotropy. The(α+β)-CDR process was found to be a candidate process for reducing anisotropy of Ti60 alloy plates.     

烧结与冷镦过程中铝硅共晶合金显微结构与密度的演变

采用烧结及后续的镦粗工艺制备了铝硅共晶合金块体材料,研究了烧结温度对烧结体显微结构、抗压强度及相对密度的影响。结果表明：烧结温度显著影响烧结体的显微结构和抗压强度,以临近铝硅共晶合金液相线的温度烧结时,发生了局部熔化,产生的熔融液体破坏了颗粒表面的氧化膜,颗粒之间相互黏结,形成了烧结骨架。以优化的555℃烧结,Si颗粒呈球状,抗压强度达到最佳,但相对密度未发生变化。在后续的冷镦过程中,烧结骨架及粉末颗粒均产生变形,孔隙减小,颗粒呈扁平状,相对密度达到了98%。     

储氢与合金材料

介绍了储氢合金材料和开发应用动态。     

Room temperature oxidation of lead-indium alloy films

The kinetics of growth of thin (14 to 40Å) oxide layers on lead-indium alloys was investigated ellipsometrically, using: 3000Å thick films at 23°C; and oxygen exposures at 760 torr for times ranging from five minutes to five days. Assuming that the oxide layer is comprised of a two-phase mixture of PbO and In₂O₃ having a negligible extinction coefficient made it possible to estimate the oxide composition from the ellipsometrically-obtained oxide refractive index. Under these oxidizing conditions, the volume fraction of PbO in the oxide mixture decreases from a value of unity for pure lead to zero for alloys containing more than 30 at. percent In, in agreement with the Auger Electron Spectroscopy results of Chou and coworkers. The oxidation rate equals a exp (X₁/X), where α and X₁ will be seen to vary complexly with alloy composition. A theoretical explanation of these results is also presented.