预退火时间对Pd40Cu30Ni10P20玻璃转变及晶化的影响

采用示差扫描量热(DSC)分析方法,测定了大块非晶合金Pd40Cu30Ni10P20经523 K((Tg-100 K)＜7＜Tg)不同时间(0～64 h)预退火后的玻璃转变温度7g、玻璃转变峰温度TM、起始晶化温度Tx、晶化峰的峰温Tp、晶化焓以及在玻璃转变过程中的比热容增量,并根据Kissinger公式计算了晶化的表观活化能.同时,测量了不同时间预退火后样品的显微硬度.结果表明:在玻璃转变温度以下的预退火处理使Pd40Cu30Ni10P20大块非晶合金的微观原子组态发生变化,从而影响了其随后的玻璃转变行为,但对晶化的影响不大.其显微硬度随预退火时间的延长而逐步增加后趋于稳定.并利用结构弛豫理论分析了预退火对玻璃转变、晶化和显微硬度的影响.     

NUMERICAL SIMULATION OF CONTROLLING IN TITANIUM ALLOY SHEETS WELDING RESIDUAL STRESS BY TRAILING PEENING

It is a promising and new technology to apply welding with trailing peening to control welding stress and distortion of titanium alloy. Numerical simulation of conventional welding and welding with trailing peening of the titanium alloy sheet is carried out, using nonlinear finite element theory and the engineering analysis software MARC. The result shows that welding with trailing peening technology reduces longitudinal residual stress in welding joint effectively, and it is more effective to reduce residual stress to peen the weld than to peen the weld toe. It is a effective result that other technolooy and method used in welding can never achieved.     

Effect of chemical component on shape memory effect of Fe-Mn-Si-Ni-C-RE shape memory alloy

Effect of chemical component on shape memory effect (SME) of Fe-Mn-Si-Ni-C-RE shape memory alloys was studied by bent measurement, thermal cycle training, SEM etc. Results of study indicate that the alloys with high Mn content (25%) appeare better SME, especially in lower strain. SME improves evidently when Si is higher content, especially it's range from 3% up to 4%. But brittleness of Fe-Mn-Si-Ni-C-RE alloy increases by increasing the Si content. SME of the alloy is weakening gradually as carbon content increases under small strain (3%). But in the condition of large strain (above 6%), SME of the alloy whose carbon content ranges from 0.1 % to 0.12% shows small decreasing range, especially of alloy with the addition of compound RE.     

强化均匀化对7B04铝合金铸态组织与性能的影响

研究了强化均匀化 (大幅度延长均匀化时间 ,略高于传统均匀化温度 )对 7B0 4铝合金铸态组织和性能的影响。结果表明 :在 4 6 8℃× 4 8h的均匀化制度下 ,材料的铸态组织得到明显的改善 ,非平衡凝固形成的多相组织基本上转变成均匀化组织 ,材料的伸长率较传统均匀化提高 14 % ,为后续压力加工和热处理奠定了基础。     

液相渗Si提高TiAl基合金的高温抗氧化性

使用液相Al—Si合金对TiAl基合金进行表面渗Si处理，可明显增强TiAl基合金的高温抗氧化性．经1273K，100h的恒温氧化后，不同的表面涂层使合金在40—100h之间的氧化速率降低了2个数量级，恒温氧化100h后的最终氧化皮脱落量也减少3个数量级．液相渗Si使TiAl基合金表面高温抗氧化性能得到大幅度改善，其根本原因是Si与TiAl中的元素Ti结合，降低了Ti的活度，相对增强了涂层中元素Al的活度，而且涂层中Al的绝对含量也得到明显提高，这些均抑制了高温氧化过程中TiO2的生成，涂层最外层形成了致密的Al2O3氧化膜．     

The effect of corrosion inhibiting pigments on environmentally assisted cracking of high strength aluminum alloy

The effects of some corrosion inhibiting pigments on environmentally assisted cracking of 7075-T76 aluminum alloy were examined in 3.5% NaCl (pH=6.2) solution. In order to study the inhibition mechanism of these pigments in environmentally assisted cracking of aluminum alloy, electrochemical polarization tests were carried out in 3.5% NaCl (pH=6.2 and 3) and 0.1 M HCl solutions respectively with the presence and absence of these pigments. The results showed that the effects of the pigments on environmentally assisted cracking of aluminum alloy were exhibited mainly at crack initiation and the early stage of crack propagation. A nontoxic compound, composed of phosphate, molybdate, citrate, and thiazole/imidazole derivatives, was a promising pigment to inhibit environmentally assisted cracking of the alloy.     

Zr65Al7.5Ni10Cu17.5块状非晶晶化过程的电镜研究

用透射电镜对Zr65Al7.5Ni10 Cu17.5块状非晶合金的晶化过程进行了研究。发现晶化过程的不同阶段相的组成是不同的。710K时 ,主要是tI CuZr2 相和tP Al2 Zr3 相 ,两者有固定的取向关系 :[0 10 ]tI∥ [0 10 ]tP,(10- 3) tI∥(2 0 2 ) tP。在 76 0K时 ,除了前面的两个相外 ,又出现了hP2 Al2 NiZr6相和hP3 α Zr相 ,两者也有固定取向关系 :[113]hP2 ∥ [0 0 1]hP3 ,(14- 1) hP2 ∥ (2 1- 0 ) hP3 。根据它们的晶格常数的相似性可以把晶化相归纳为两类 :tI ,oC ,hP3 和tP ,hP1,hP2 。这些相都是Zr基的 ,但前者富Cu和Ni,后者富Al。用电镜得到的结果来标定X射线衍射谱 ,结果吻合很好。     

多向锻造7075铝合金的结构和性能

在440℃经多向锻造加工成7075铝合金锻件。研究了锻件的显微组织和力学性能随退火温度和T73回火的变化，TEM和SEM用于分析锻件的晶粒和第二相形态。多向和大变形锻造产生平均晶粒尺寸1．8μm的完全再结晶组织。390℃-450℃退火使晶粒长大到3μm，但位错和第二相分布没有明显改变，这时锻件展现出较低强度和较高延性。T73回火使锻件屈服强度和拉伸强度分别提高280％和210％，而延性同退火样相比并无明显下降，断裂韧性达到51MPam^1/2，可以认为这是沉淀强化的贡献。     

氢对Ti-2Al-2.5Zr钛合金疲劳性能的影响

研究了4种含量的氢对Ti-2Al-2.5Zr钛合金疲劳性能的影响。结果表明，自然含氢量的材料具有最好的疲劳性能。而当疲劳载荷大于材料的屈服强度时，氢含量对疲劳寿命基本没有影响；低于屈服强度后，疲劳寿命随着氢含量的升高而和。认为固溶的原子氢导致驻留滑移带软化，裂纹萌生提前，造成在较大△σ时充氢试样的疲劳寿命降低；而材料中氢化物对驻留滑移带（PSB）的阻碍作用导致氢化物与基体分离 而成为裂纹源，是小△σ下疲劳寿命降低扩要原因。     

变形Fe-Nb-C合金的室温至180℃内耗

测量了700℃，30min水冷后变形Fe－Nb-C合金室温至180℃的内耗，发现除Snoek峰外，合金在此温度区还有阻尼峰。测量了合金经过980℃，2h中间处理样品的内耗，并给出变形及室温原位时效的汽车钢ST14与GBPH340的内耗结果。认为Fe-Nb-C合金的变形“B”峰。是被饱和Cotterll气团碳原子团簇钉扎的位错段拖曳碳的稀Cottrell气团运动引起的，是合金在变形时碳原子稀Cottrell气团择优分布在位错上的结果。