Probing the Effects of Nanoscale Architecture on the Mechanical Properties of Hexagonal Silica/Polymer Composite Thin Films

We examine the effects of controlling nanoscale architecture on the tensile properties of honeycomb‐structured silica/polymer composite films. The hexagonal films are produced using evaporation‐induced self‐assembly and uniaxially strained using a home‐built tensile testing apparatus. Significant differences in the yield strain, failure strain, and tensile moduli between the axes parallel and perpendicular to the film‐deposition direction are observed for the thinnest films examined and are attributed to anisotropy in the film nanostructure that is further characterized with transmission electron microscopy and atomic force microscopy. For properly oriented composites, these films have tensile moduli comparable to the Young's modulus of bulk silica but exhibit failure strains that are about an order of magnitude larger than those seen in typical bulk‐silica systems. The yielding and failure processes are explored using X‐ray diffraction and optical microscopy and are characterized by irreversible changes in the nanoscale architecture. We show that tuning the nanoscale architecture can provide control over the tensile properties of composites, allowing for materials with combinations of stiffness and elasticity unachievable in the analogous bulk systems.     

Highly Stable Au Nanoparticles with Tunable Spacing and Their Potential Application in Surface Plasmon Resonance Biosensors

Colloidal Au‐amplified surface plasmon resonance (SPR), like traditional SPR, is typically used to detect binding events on a thin noble metal film. The two major concerns in developing colloidal Au‐amplified SPR lie in 1) the instability, manifested as a change in morphology following immersion in organic solvents and aqueous solutions, and 2) the uncontrollable interparticle distance, determining probe spacing and inducing steric hindrance between neighboring probe molecules. This may introduce uncertainties into such detecting techniques, degrade the sensitivity, and become the barricade hampering colloidal Au‐based transducers from applications in sensing. In this paper, colloidal Au‐amplified SPR transducers are produced by using ultrathin Au/Al₂O₃ nanocomposite films via a radio frequency magnetron co‐sputtering method. Deposited Au/Al₂O₃ nanocomposite films exhibit superior stability, and average interparticle distances between Au nanoparticles with similar average sizes can be tuned by changing surface coverage. These characteristics are ascribed to the spacer function and rim confinement of dielectric Al₂O₃ and highlight their advantages for application in optimal nanoparticle‐amplified SPR, especially when the probe size is smaller than the target molecule size. This importance is demonstrated here for the binding of protein (streptavidin) targets to the probe (biotin) surface. In this case, the dielectric matrix Al₂O₃ is a main contributor, behaving as a spacer, tuning the concentration of Au nanoparticles, and manipulating the average interparticle distance, and thus guaranteeing an appropriate number of biotin molecules and expected near‐field coupling to obtain optimal sensing performance.     

自适应波束形成采样矩阵求逆算法的改进

采样矩阵求逆(SMI)算法是自适应算法中的一个分类。由于该算法需要知道接收信号的波达方向角度,因此属于非盲算法。在现有采样矩阵求逆算法的基础上进行了2项改进,提出了对协方差矩阵进行信号子空间分解再加权的方法,有效改善了输出期望信号的主瓣增益和输出信干噪比;同时针对传统SMI算法无法应用于相干信号源的情况做了进一步改进,通过对相干信号进行解相关,解决了这一问题。     

Facile Synthesis of Manganese‐Loaded Mesoporous Silica Materials by Direct Reaction Between KMnO4 and an In‐Situ Surfactant Template

A series of manganese oxide‐loaded SBA‐15 (MnSBA‐xh, x = 1, 2, 3, 4, 5, 6; h: hour(s)) mesoporous materials are synthesized via a facile, in‐situ reduction method with a surfactant template. The composite materials are characterized using Fourier‐transform infrared spectroscopy, X‐ray diffraction, N₂ sorption isotherms, X‐ray photoelectron spectroscopy (XPS), transmission electron microscopy, energy‐dispersive spectroscopy, and CO oxidation catalysis. The results show that a high content of manganese (an atomic ratio of Mn/Si from 0.12 up to approximately 1) could be loaded into the channels of SBA‐15 when treated with an aqueous solution of potassium permanganate, while retaining the ordered mesostructure and large surface area of SBA‐15. Increasing the manganese oxide content results in a gradual decrease in the specific surface area, pore size, and pore volume. XPS spectra are employed to confirm the redox reaction between KMnO₄ and the surfactant. CO‐conversion tests on the calcined MnSBA‐2h sample (MnSBA‐2h‐cal) shows that it has a repeatable, and relatively high, catalytic activity.     

一种应用于电子封装的热匹配工艺设计

作为组件封装材料,铝合金与芯片和电路基板之间存在热膨胀不匹配问题.采用热匹配工艺设计,选择合适的热匹配材料,为铝合金盒体与LTCC基板热膨胀匹配提供了一种理想解决方案.根据匹配设计理念,利用Abaqus有限元软件对热匹配材料及铝盒体的结构进行了仿真和优化,并与加工出试验样品的测试结果进行了对比,验证了模拟结果,为铝合金...     

高频低阻抗长寿命铝电解电容器的研制

阐述了高频低阻抗长寿命铝电解电容器的特点,通过研制工作电解液、制订材料配套方案及工艺改进,研制出的高频低阻抗长寿命铝电解电容器产品性能与日本Nichicon公司PW系列产品相当,完全可以替代进口产品.     

基于行列式随机循环的压缩感知测量矩阵研究

压缩感知理论,从信号的自身特性出发,通过变换作用域和线性投影实现对信号的采样和压缩。测量矩阵是该理论中获得最优测量,实现精确重构的关键。本文在介绍常用测量矩阵的基础上,重点研究了结构化测量矩阵。鉴于测量矩阵设计的最重要的原则是降低矩阵元素间的相干性,本文借鉴循环矩阵和广义轮换矩阵的优点,提出了采用均匀随机数对结构化测量矩阵进行随机循环的构造方法。仿真实验表明新矩阵在信号重建上具有更好的性能。     

光传输系统中基于Bose第一类方法对QC-LDPC码的一种新颖构造方法

基于平衡不完全区组设计(BIBD)、循环矩阵分解和循环置换矩阵,提出了一种适用于光传输系统的新颖准循环低密度奇偶校验码(QC-LDPC)构造方法。利用Bose的第一类方法构造的低密度校验矩阵对其进行循环列分解得到相应的模板矩阵,再利用合适的循环置换矩阵对其进行扩展。采用该方法构造的QC-LDPC码具有良好的结构,且可根据实际需要来灵活地选择码长和码率。仿真结果表明:在误码率为10-6时其码率均为93.7%的情况下,该方法构造的novel-QC-LDPC(10992,10305)码比ITU-T G.975中RS(255,239)码的净编码增益(NCG)改善了约1.8d B。因此该构造方法所构造的QC-LDPC码具有更好的纠错性能,更适合高速长距离的光传输系统。     

Magnetic properties of nickel filament polymer-matrix composites

The magnetic properties of polyethersulfone-matrix composites with 3-19 vol.% polycrystalline nickel filaments (0.4 (im diam) were investigated. These filaments were found to exhibit hysteresis energy loss 10800 J/m³ of nickel and coercive force 16.9 kA/m, compared to corresponding values of 4930 J/m³ and 4.7 kA/m for 2 μ.m diam polycrystalline nickel fibers, 1020 J/m³ and 0.5 kA/m for 20 μm diam polycrystalline nickel fibers, and 1280 J/m³ and 2.3 kA/m for solid polycrystalline nickel.     

液晶运动图像投影仪

由产生图像的液晶显示元件，投影图像的光学机构和显示屏即构成液晶运动图像投影仪。液晶材料可将图像信息暂时储存，称为储存效应。连续图像投影方法是，在液晶材料中产生图像并暂时储存起来，将投影光源对准液晶材料，然后作为液晶透射或散射光函数的图像投影到投影屏上，可连续地产生投影图像。