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11.
Sol–gel films are actively investigated during the last decade as possible candidates for environmentally friendly pre-treatments. However, the important drawback in this case is the lack of active corrosion protection and self-healing ability. 相似文献
12.
A new method of studying the corrosion inhibition mechanism of rare earth metal(REM) on LC4 Al alloy with the spilt cell technique was studied. The principle and experimental method of the spilt cell technique were analyzed. By measuring the change of net-electric current between the two electrodes caused by the change of the amount of oxygen in the solution and the addition of CeCl3, the influence of corrosive performance of CeCl3 on LC4 super-power aluminum alloy in the 0.1 mol·L−1 NaCl solution was investigated. Meanwhile, the conditional changes of pH values, CeCl3 solution, additire and time of performance were also studied. Finally, the features of electrode surface were revealed by using SEM and X-ray energy-dispersive spectrometry (EDS). By combining these with other electric chemical techniques, such as potential-time curve, polarization curve et al. 相似文献
13.
Takayuki Honma Yuichiro Kuroki Tomoichiro Okamoto Masasuke Takata Yukihiro Kanechika Masanobu Azuma Hitofumi Taniguchi 《Ceramics International》2008,34(4):943-946
Aluminum nitride ceramics were prepared by sintering with 0–4.8 mass% of Ca3Al2O6 (C3A) as a sintering additive. The transmittance in the range of 260–550 nm increased with increasing amount of C3A. The cathodoluminescence intensity attributed to oxygen-induced defects decreased with increasing amount of C3A. From the results, the increase of the transmittance in the range of 260–550 nm was considered to be related to the decrease of the oxygen-induced defect density. 相似文献
14.
M. Guerioune Y. Amiour W. Bounour O. Guellati A. Benaldjia A. Amara N. E. Chakri M. Ali-Rachedi D. Vrel 《International Journal of Self-Propagating High-Temperature Synthesis》2008,17(1):41-48
Aiming at preparation of shape memory alloys (SMAs), we explored the SHS of Cu1 − x
Zn1 − y
Al1 − z
alloys (0.29 < x < 0.30, 0.74 < y < 0.75, and 0.83 < z < 0.96). The most pronounced shape memory effect was exhibited by the alloys of the following compositions (wt %): (1) Cu(70.6)Zn(25.4)Al(4.0),
(2) Cu(70.1)Zn(25.9)Al(4.0), and (3) Cu(69.9)Zn(26.1)Al(4.0). The effect of process parameters on the synthesis of CuZnAl
alloys was studied by XRD, optical microscopy, and scanning electron microscopy (SEM). The grain size of CuZnAl was found
to depend on the relative amount of the primary CuZn and AlZn phases. Changes in the transformation temperature and heat of
transformation are discussed in terms of ignition intensity and compaction. Mechanism of the process depends on the level
of the temperature attained relative to the melting point of components. At the melting point of AlZn, the process is controlled
by the solid-state diffusion of AlZn into a product layer. The ignition temperature for this system depends on the temperature
of the austenite-martensite transformation in CuZnAl alloys. The composition and structure of the products was found to markedly
depend on process parameters. The SHS technique has been successfully used to prepare a variety of SMAs.
相似文献
15.
镍氢电池负极用低成本储氢合金的研究 总被引:1,自引:0,他引:1
研究了ABS型储氢合金在低Co含量条件下,随B组元替代元素Co,Al,Si等含量的变化对合金电化学性能的影响规律,同时研究了A组元中不同La/Ce比对合金电化学性能的影响情况。结果表明,随合金中Co含量的降低,合金的活化性能和放电容量得以改善,但合金的循环寿命下降也比较明显;在试验范围内,随Al元素的加入,合金的循环寿命得以改善,但材料的放电容量和活化性能均有所下降;随合金La/Ce比的降低,合金的放电容量略有下降,但其循环寿命和放电电压平台有较大提高。 相似文献
16.
17.
A. MONSALVE M. PÁEZ M. TOLEDANO A. ARTIGAS Y. SEPÚLVEDA y N. VALENCIA 《Fatigue & Fracture of Engineering Materials & Structures》2007,30(8):748-758
The S-N-P (stress, number of cycles, failure probability) curves for 2024 T3 and 7075 T7351 aluminium alloys were obtained. Previously, surface treatments of degreasing and different types of anodizing were applied to samples, evaluating the influence of these treatments on the fatigue life of the alloys. The determination of the S-N-P curves was done using Maennig's method. Rotary fatigue was used because this technique produces greater stress on the sample surfaces, the zone in which it is important to evaluate fatigue resistance. Both the transition range and the finite life range were evaluated, calculating the 1, 50 and 99% fracture probability. SEM was performed in order to characterize the fracture micromechanism. The conclusions were that Maennig's method is useful to evaluate fatigue life of these materials in a fast and efficient manner. Moreover, surface treatments produce a decrease in the fatigue life of both alloys, associating this effect with the surface damage produced on each sample during the treatment. 相似文献
18.
A general numerical model is described for the dissolution kinetics of spherical particles in binary systems for any combination of first order reactions at the particle-matrix interface and long distance diffusion within the matrix. The model is applicable to both finite and infinite media and handles both complete and partial particle dissolution. It is shown that interfacial reactions can have a strong effect on the dissolution kinetics, the solute concentration at the particle-matrix interface and the solute concentration profile in the matrix. 相似文献
19.
Investigations have been carried out on an erosion-corrosion apparatus to investigate the behaviour of corrosion-resistant highalloy iron-base materials containing hard phases. These materials had been optimized for increased wear resistance under complex stress conditions. As expected, in dry erosion tests, very low mass losses were established; there was little difference between the materials. Also, in corrosive environments (NaCl, H2SO4), the materials showed good stability; however, the duplex structures were superior to the martensitic ones. The combination of erosion and corrosion produced large differences and, in some cases, markedly reduced resistance to damage. These results confirmed observations that it is impossible to deduce the environmentally influenced mechanical behaviour of an alloy from its behaviour in separate corrosion and erosion experiments. The basic mechanisms underlying these processes have been investigated only tentatively. 相似文献
20.
通过铝箔项目的工程实例,详细介绍了铝箔项目给排水专业设计的主要构成,并总结了几点设计体会,可供有关专业设计人员借鉴、参考。 相似文献