Characteristic Investigation of Nano-Crystal Hydrogen Storage Alloys

A Ml (NiCoMnA1)5 hydrogen storage alloys was prepared by double-roller rapid quenching.Its microstructure, electrochemically and kinetic characteristic were studied.A uniform crystal phase with CaCu5 structure could be detected by XRD analyses, whose average grain size is 30 ～ 50 nm and the ratio of c/a of nano-crystal hydrogen storage alloy is larger.The hydrogen absorption/desertion p - C isotherms of alloy show that its fiat-performance is perfect and the magnetic stagnant effect is very little.An simulate cell is used for electrochemical measurement.Electrode is 10C, the capacity decreasing rate via the 450 cycles at 7C is less than 20%.     

The oxidation of two ternary Ni-Cu-10 at.% Al alloys in 1 atm of pure O2 at 800-900 °C

The oxidation of the ternary alloys Ni-45Cu-10Al and Ni-30Cu-10Al has been studied at 800-900 °C under 1 atm O₂. The presence of 10 at.% Al reduces significantly the oxidation rate of the corresponding Cu-Ni alloys during the initial oxidation stages, even before the establishment of a complete Al₂O₃ layer. The weight of individual sample of the two ternary Ni-Cu-10Al alloys at 800 °C increases more rapidly than at 900 °C during the initial oxidation stage. As oxidation proceeds, the weight gain at 800 °C slows down to a degree that the total weight gain after 24 h oxidation at 800 °C is less than that at 900 °C. Due to a faster formation of the Al₂O₃ layer, which suppresses earlier the further oxidation of Cu and Ni, the external region of the scales grown on Ni-45Cu-10Al contain much less Cu and Ni oxides than those grown on Ni-30Cu-10Al. The transition from the internal oxidation to the selective external oxidation of the most reactive component Al in Ni-Cu-Al alloys is favored by higher values of the Al content, of temperature and of the Cu/Ni ratio.     

Cast bulk ZrTiAlCuNi amorphous alloys

Cylindrical bulk amorphous samples with diameters up to 10 mm have been prepared by casting ZrTiAlCuNi alloys in a copper mould. In order to rank glass-forming ability as a function of alloy composition, alloys were also cast into wedge-shaped moulds; to a first approximation, the thickness of the amorphous region obtained can be taken as an indication of glass-forming ability. The compositions which lead to the production of bulk glasses all have reduced glass transition temperatures in excess of 0.65 and the extremely high glass-forming ability of these compositions is discussed. We suggest that both the Al and Ti contents are determining factors for the production of bulk amorphous samples and these are believed to reduce the driving force for, and hence the rate of, crystallisation. These amorphous alloys have been found to display high thermal stability and can be annealed for several minutes in the supercooled liquid region. They are ductile at room temperature and have a high value of yield stress.     

中高频小功率电子元器件用非晶材料的开发与应用

随着电力和电子技术的飞速发展，相应的元器件向高频化，小型化，高效率和节能的方向发展，从而对元器件用材料也提出了更高要求。为此，本文概述了冶金部钢铁研究总院近年来所研究的用于开关电源，脉冲变压器，传感器，电流互感器和电感器等方面的非晶软磁合金的性能及其应用概况。     

Chemical vapor deposition of aluminum for ulsi applications

Aluminum has been used widely as a conducting material in the fabrication of integrated circuits, and chemical vapor deposition process for Al has been actively investigated for the application in ultra large scale integration. In this review, various precursors, mainly alkyl aluminum and alane compounds, and reaction mechanisms of these precursors in Al CVI) are described. Epitaxial growth and selectivity of the deposition are also discussed. In addition to thermal reactions, plasma and photochemical reactions are also briefly described.     

Comparison of supports for the direct synthesis of hydrogen peroxide from H2 and O2 using Au–Pd catalysts

The direct synthesis of hydrogen peroxide from H₂ and O₂ using a range of supported Au–Pd alloy catalysts is compared for different supports using conditions previously identified as being optimal for hydrogen peroxide synthesis, i.e. low temperature (2 °C) using a water–methanol solvent mixture and short reaction time. Five supports are compared and contrasted, namely Al₂O₃, -Fe₂O₃, TiO₂, SiO₂ and carbon. For all catalysts the addition of Pd to the Au only catalyst increases the rate of hydrogen peroxide synthesis as well as the concentration of hydrogen peroxide formed. Of the materials evaluated, the carbon-supported Au–Pd alloy catalysts give the highest reactivity. The results show that the support can have an important influence on the synthesis of hydrogen peroxide from the direct reaction. The effect of the methanol–water solvent is studied in detail for the 2.5 wt% Au–2.5 wt% Pd/TiO₂ catalyst and the ratio of methanol to water is found to have a major effect on the rate of hydrogen peroxide synthesis. The optimum mixture for this solvent system is 80 vol.% methanol with 20 vol.% water. However, the use of water alone is still effective albeit at a decreased rate. The effect of catalyst mass was therefore also investigated for the water and water–methanol solvents and the observed effect on the hydrogen peroxide productivity using water as a solvent is not considered to be due to mass transfer limitations. These results are of importance with respect to the industrial application of these Au–Pd catalysts.     

Strengths and ductility of Mo–TiC alloys after secondary recrystallization

A series of Mo–TiC alloys were heated in vacuum at 2473 K for 36 ks. First grain growth behavior was observed using a scanning electron microscope. Then effects of TiC addition on the strengths and ductility at low temperature were discussed from the viewpoints of chemical composition and grain structure.

Materials with TiC additions of not larger than 0.1% demonstrated a single-crystalline grain structure. Both yield and maximum strengths increased by TiC addition and consequently ductility was improved.     

富Ag的Ag—Cu合金再结晶

用度测量、示差扫描量热（ＤＳＣ）、金相显微镜、透射电镜等技术研究了富Ａｇ的Ａｇ－Ｃｕ合金的再结晶。对合金再结晶温室随Ｃｕ含量的变化规律以及在相同变形量下，Ｃｕ含量对合金再结晶过程中冷加工储存能的释放的影响进行探索，并讨论了结果。     

节能型铝合金连续熔化－去气炉

介绍一种用于铝合金的连续熔化－去气的节能装置。着重讨论了此装置的结构和操作要点以及影响铝合金质量的因素。文中对比了此装置与传统阶段式熔化系统操作上的异同点。分析了连续熔化炉的经济效益。研究表明毛坯耗电量下降８５％，并可减少合金元素加入量以及坩埚和加热元件的消耗。铸件质量合格。     

介绍一种生产冲挤用铝合金坯料的新工艺

哈兹列特铝板带连铸连轧工艺已被成功地用于铝和铝合金冲击挤压用坯料的生产。在对哈氏四个有关用户扫描的基础上，列举了其产品及其用途，并介绍了相关工艺及其优点。