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51.
52.
Dario Pasini Luigi Garlaschelli Elza Bontempi Laura E. Depero 《Fullerenes, Nanotubes and Carbon Nanostructures》2007,15(5):367-378
The synthesis of a series of polymers and cyclopolymers bearing crown ethers of differing structure and affinities towards primary ammonium ions is discussed. These polymers have been tested in their efficiency to form structurally homogeneous thin films when blended with an amphiphilic C60 compound containing a primary ammonium ion functional group. The X-ray reflectivity characterization of the films revealed that the polymer bearing the crown ether with the least affinity for primary ammonium ions, but having the highest degree of polymerization, is the most effective in forming structurally homogeneous thin films. 相似文献
53.
Jinhong Shin Wyatt A. Winkenwerder Kyriacos Agapiou Gyeong S. Hwang 《Thin solid films》2007,515(13):5298-5307
Chemical vapor deposition growth of amorphous ruthenium-phosphorus films on SiO2 containing ∼ 15% phosphorus is reported. cis-Ruthenium(II)dihydridotetrakis-(trimethylphosphine), cis-RuH2(PMe3)4 (Me = CH3) was used at growth temperatures ranging from 525 to 575 K. Both Ru and P are zero-valent. The films are metastable, becoming increasingly more polycrystalline upon annealing to 775 and 975 K. Surface studies illustrate that demethylation is quite efficient near 560 K. Precursor adsorption at 135 K or 210 K and heating reveal the precursor undergoes a complex decomposition process in which the hydride and trimethylphosphine ligands are lost at temperatures as low at 280 K. Phosphorus and its manner of incorporation appear responsible for the amorphous-like character. Molecular dynamics simulations are presented to suggest the local structure in the films and the causes for phosphorus stabilizing the amorphous phase. 相似文献
54.
Langmuir films (LFs) of biphenyl and anthracene derivatives on the surface of liquid mercury were studied by surface-specific X-ray and surface tension measurements. Phases of lying-down, side-lying and standing-up molecules were found, some of which exhibit long-range lateral order. The molecular symmetry and the position and nature of the side-, end-, and headgroups are shown to dominate the structural evolution of the LFs with surface coverage. 相似文献
55.
56.
源气体流量比对F-DLC薄膜结构的影响 总被引:3,自引:1,他引:2
以高纯石墨作靶,CHF3/Ar作源气体采用反应磁控溅射法制备出了氟化类金刚石(F-DLC)薄膜。拉曼光谱表明,CHF3相对流量的增加会引起薄膜的D峰与G峰强度之比I(D)/I(G)减小,晶粒增大,芳香环结构出例下降。红外吸收光谱分析证实了这些推论,指出这是由于薄膜中氟含量上升的结果。 相似文献
57.
主要介绍了光学薄膜在光通信的无源型器件中的原理及应用,并与光纤光栅和平面光波导型的无源器件作简单比较。 相似文献
58.
59.
M. Liu Q. Fang G. He L.Q. Zhu S.S. Pan L.D. Zhang 《Materials Science in Semiconductor Processing》2006,9(6):876
High-k HfOxNy thin films have been grown by radio frequency (rf) reactive sputtering of metal Hf target in N2/Ar/O2 ambient at different substrate temperatures. The chemical compositions of the films have been investigated as a function of substrate temperature by X-ray photoelectron spectroscopy (XPS). XPS measurements showed that nitrogen concentration increases with an increase in substrate temperature. Room-temperature spectroscopic ellipsometry (SE) with photon energy 0.75–6.5 eV was used to investigate the optical properties of the films. SE results demonstrated that refractive index n increases with an increase in substrate temperature. Based on TL parameters which were obtained from the best fit results used in a simulation of the measured spectra, meanwhile, we conclude that the energy band gap (Eg) decreases with an increase in substrate temperature. 相似文献
60.
M. Knaapila R. Stepanyan B.P. Lyons M. Torkkeli A.P. Monkman 《Advanced functional materials》2006,16(5):599-609
This account highlights recent progress towards understanding the complex hierarchical levels of solid‐state structure in a prototypical helical hairy‐rod polyfluorene, poly[9,9‐bis(2‐ethylhexyl)fluorene‐2,7‐diyl] (or PF2/6). This branched‐side‐chain containing polyfluorene undergoes a systematic intermolecular self‐assembly and liquid‐crystalline phase behavior in combination with uniaxial and biaxial alignment. The latter processes yield full three‐dimensional orientation of the crystallites and polymer chains. Also reviewed are the impact of the molecular structure and phase behavior on surface morphology, anisotropic film formation, and, ultimately, the overall impact of these physical attributes on optical constants. This particular polyfluorene also represents a model system for demonstrating the applicability of mean‐field theory in detailing the self‐organization of aligned hairy‐rod block‐copolymer systems. These results of PF2/6 are compared to those of other archetypical π‐conjugated hairy‐rod polymers. General guidelines of how molecular weight influences nanostructure, phase behavior, alignment, and surface morphology are given. 相似文献