Mg-Li-Al合金近液相线制浆及部分重熔

采用近液相线铸造方法制备了Mg—5％Li—3％A1合金的半固态浆料。通过对该合金近液相线铸造与常规铸造组织进行比较，以及在不同静置时间、不同冷却速率下对其铸造组织的影响，较详细地分析了近液相线铸造组织的变化过程。试验结果表明，在Mg—Li合金熔炼中，添加2％Ca可实现阻燃，但效果不如对一般镁合金；与常规铸造相比，近液相线铸造可获得均匀、细小枝晶的组织结构；适当静置或提高冷却速率有利于组织的细化和均匀化；在适当的部分重熔工艺条件下，坯料组织可获得较理想的触变组织。     

GH871 合金的蠕变断裂机制

对采用AIM+ESR和VIM+ESR工艺冶炼的GH871合金在650 ℃的蠕变性能及特征的研究表明,与用AIM+ESR工艺冶炼的GH871合金相比,用VIM+ESR工艺冶炼的GH871合金在蠕变断裂过程中裂纹萌生的形式(包括裂纹形状及形成时间)和裂纹扩展至裂纹连接所需的时间均表现出明显韧化的特征.     

Surface Position-Resolved Thermophysical Properties for Metallic Alloys

Thermophysical properties are collective measures of a material to transport dynamical quantities of physical nature on its surface or through the bulk. As such, the exact nature of couplings between particles in a many-body assembly of building block atoms or molecules sensitively determines their values. The couplings between nearest neighbors are the product of the local elemental composition and the material phase. In this study, thermal cycling of a four-element Wood’s alloy specimen brings out cadmium-rich patches to the top surface of the specimen. An assembly of such patches leads to depth-dependent deviations of elemental composition from that of the bulk. Surface-layer atoms are driven to form a high temperature laser-produced plasma (LPP), and time-resolved spectroscopy of their emissions show the variability of elemental composition over surface positions as well as over depth from the surface. These thermal history-driven composition anomalies contribute to significant variability in the measured values of spectral emissivity and thermal diffusivity.     

镁合金表面喷铝防腐蚀层的微观组织分析

在AZ91D镁合金表面热喷铝，用以提高其表面的耐腐蚀性能。采用SEM，EPMA等方法对AZ91D表面喷铝扩散层的组织进行了仔细的观察与分析，发现在防腐蚀层上有大量的Mg17Al12相存在，且呈决状及非连续片状分布。经显微硬度测定，喷铝层硬度较镁合金基体高；腐蚀后这种相凸出于基体，比镁合金基体有较好的耐腐蚀性能。     

Corrosion Behavior of a Sputtered K38G Nanocrystalline Coating with a Solid NaCl Deposit in Wet Oxygen at 600 to 700°C

A nanocrystalline coating of K38G alloy was obtained by means of magnetron sputtering. The corrosion behavior of cast K38G alloy and its sputtered nanocrystalline coating with a solid NaCl deposit in dry air or wet oxygen at 600 and 700°C have been studied and compared. The results indicated that the mass gain of the coating is higher than that of the cast alloy at 600 and 700°C. Therefore, nanocrystallization reduced the corrosion resistance at these temperatures. Furthermore, the mass gains of the coating and the cast alloy with a NaCl deposit in wet oxygen were less than that with a NaCl deposit in dry air. The relevant corrosion mechanisms are discussed.     

非化学计量LaNi5型储氢合金的性能

采用富La混合稀土与Ni、Co、Mg等元素组合，获得了一种非化学计量LaNi5型储氢合金、用金相、XRD和SEM-EDX等方法分析了该合金的组织结构，研究了合金的气相储氢特性以及电化学性能，结果表明：在1.6MPa氢压和温度29℃下，该合金的储氢量达到1.58%（质量分数），该合金的放电容量为380mAh/g。经300次循环后容量保持率为55%，该合金的基体是CaCu5型结构的LaNi5相，但有第二相（LaMg)Ni3析出，这种第二相的形成是导致该合金大容量的关键。     

Recovery retardation in equal channel angular pressed Al–Zr alloy during friction stir welding

The effect of Zr on reduction of hardness and microstructure in an FS weld of equal channel angular-pressed Al alloy was investigated. Zr addition to Al suppressed dynamic recovery in the thermomechanically affected zone and enabled retention of the high hardness of the ECA-pressed material throughout the weld.     

Rapid determination of the fracture toughness of metallic materials using circumferentially notched bars

Three types of material whose fracture toughness tests were previously performed by using circumferentially notched bars, namely (1) a dual-phase steel with three different morphologies; (2) an Al-Zn-Mg-Cu-wrought alloy; and (3) Al-Si-cast alloys with three different Si contents, were investigated in terms of accuracy and reliability of the testing method. Also, the advantages of using circumferentially notched bars for fracture toughness determination of metallic materials were discussed. With the help of stress concentration factors, which are associated with the bluntness of the notch, correction factors for the fracture toughness calculations are derived. The corrected fracture toughness values are found to be close to the uncorrected ones, implying that the testing procedure is reliable.     

原始组织及加热方式对Al-5.8wt%Cu合金熔化行为的影响

利用DSC分析手段，研究了具有3种不同凝固组织的Al-5.8wt%合金在7种不同加热方式下的熔化开始温度和熔化热，发现凝固组织中存在的非平衡共晶在加热过程中大部分扩散溶解，溶入基体，剩余部分参与共晶熔化，其熔化开始温度与组织状态无关，随加热速度的增大略有升高，溶解部分的体积分散与组织状态和加热方式有关，随加热时间和非平衡相表面积的增大而增大。     

混合稀土对AZ91镁合金在NaCl溶液中的腐蚀行为影响

通过静态失重法、极化曲线和交流阻抗测试研究了混合稀土 (Re)对AZ91镁合金腐蚀行为的影响。结果表明 :Re的加入使AZ91微观组织得到改善 ,减缓了AZ91镁合金在NaCl溶液中的腐蚀