Formation and thermal stability of amorphous Ni-Mo-P alloys

The experimental researches on the chemical deposition of Ni-Mo-P amorphous alloys were carried out by adding Na2 MoO4 into acidic solutions. The optimum technology conditions were obtained by orthogonal design experiments. The structures and the relationship between compositions and their thermal stability were studied by energy spectrum (EC), scanning electron micrograph and X-ray diffraction spectrum. Compared with Ni-P amorphous alloys, the Ni-Mo-P amorphous alloys have high crystallization temperature and thermal stability, and the hardness reaches its peak when the annealing temperature is 500 ℃. With the increase of the heat treatment temperature, the surface morphology of the alloys changes.     

低碳低合金铸钢力学性能的研究

利用Olympus光学显微镜、扫描电镜(SEM)及能谱分析(EDAX)探讨了等温淬火工艺对低碳低合金CrMnSi铸钢力学性能的影响,并通过XRD定量分析了相的组成.结果表明,合适的等温淬火工艺,可获得一定数量的贝氏体和残余奥氏体(约6%)的复合组织,冲击断口形貌由解理刻面变为韧窝状,铸造成形无缺口试样(10 mm×10 mm×55 mm)的冲击韧度由ακ≤30 J/cm2增加至ακ≥170 J/cm2,硬度HRC≥40,具有较高硬度和冲击韧度的配合.     

Influence of electroplating conditions on magnetic properties of Fe-36wt.% Ni alloy film

A Fe-Ni soft magnetic film was prepared in sulphate solution by electroplating. The influences of the molar ratio of n [Fe2+ ]/ n [Ni2+ ], current density, bath temperature, pH and L-ascorbic acid concentration on magnetic properties of Fe-Ni alloy film were investigated. The results show that the saturated flux density(BS) of the film increases initially and decreases after it reaches the specific value with the increase of n [Fe2+ ]/ n [Ni2+ ] molar ratio, current density, bath temperature and pH. However, the relationship between L-ascorbic acid concentration and B S keeps linear. It is observed that the coercive force( Hc) is enhanced with the increase of n [Fe2+ ]/ n [Ni2+ ] molar ratio, current density and pH. By comparison, when the bath temperature increases, Hc always decreases. With the increase of L-ascorbic acid concentration, the coercive force increases initially and then decreases.     

Effect of grain size on high-temperature oxidation behavior of Cu-80Ni alloy

1　INTRODUCTIONTheoxidationofunalloyedcopperandnickelhasalreadybeenstudiedindetail.Whilethehigh tem peratureoxidationofCu Nialloys ,alsostudiedanumberoftimestodate[13] ,isanexampleofarela tivelysimpleclassofscalingofbinaryalloysbyasin gleoxidant,becausethemetalsformacontinuousse riesofsolidsolutions ,whiletheiroxides ,CuO ,Cu2 OandNiO ,exhibitsmallmutualsolubilitiesandshowsignificantdifferencesinthethermodynamicstabilityandparabolicgrowthrates .Thus ,copper richalloysformexternalscales…     

含共晶碳化物Fe－Cr－Mn合金在高温含硫气氛中的腐蚀研究

对含碳量为０．５０－２．６３％的Ｆｃ－Ｃｒ－Ｍｎ合金在８００℃下含硫混合气氛中进行腐蚀试验．用Ｘ射线物相分析法分析了腐蚀产物种类及其相对含量，现实测定了元素在腐蚀产物中的分布及试样亚表层共晶碳化物的腐蚀行为。结果表明：试验合金比高Ｎｉ耐热钢具有高的抗腐蚀性；合金的腐蚀行为受硫化及氧化腐蚀双重制约，因而使合金的腐蚀增重呈现峰值，随气氛氧化性增强，峰值向低碳方向移动；共晶碳化物具有比金属基体略好的抗腐蚀性。     

High temperature corrosion mechanisms and effect of alloying elements for materials used in waste incineration environment

Corrosion products on two typical materials, SA213-T12 steel and alloy 625 exposed to the actual combustion gas, were analyzed in addition to laboratory tests for penetration of corrosive matter. It has been clarified that corrosion products of oxides containing a little chlorides and sulphides show lamellar structures and that at the alloy-scale interface, chlorination, sulphidation, and oxidation occur under a low P_O2-high P_Cl2 condition. The formation of scale structures and the effect of corrosion-resistant alloying elements can be explained according to the stability tendencies of metals, chlorides, and oxides in the M-Cl-O equilibrium diagrams. The severity of corrosion environments at the interface is influenced by the penetration extent of corrosive matters through deposits and scales, and the protective effects of oxide films derived from alloying elements play an important role in preventing the corrosion. On the other hand, it has been shown that thermal fluctuation characterized in this kind of environment makes the lamellar scale structures and sometimes breaks and peels off the scale, and thus accelerates the corrosion. On the basis of the above mentioned knowledge, a new corrosion model is presented.     

An improved practice to manufacture Al–Ti–B master alloys by reacting halide salts with molten aluminium

The well-established “halide salt” route was employed in the present work to produce Al–Ti–B grain refiner alloys with consistent, good properties. The holding step in the production cycle was revised, however, to avoid oxidation of the molten alloy which is believed to be responsible for the relatively low Ti recoveries and thus for the inadequate and inconsistent grain refining efficiency. Stirring during holding was found to degrade the grain refining properties when molten potassium aluminium fluride salt was left on the molten alloy to avoid excessive oxidation. Likewise, holding temperatures higher than 800 °C and holding times longer than 30 min both had an undesirable effect on the grain refining performance. The experimental Al–5Ti–1B grain refiner alloy produced according to the present method provided consistent and better overall grain refining performance.     

TENSILE FRACURE IN AN Al-Li ALLOY 8090

ＴＥＮＳＩＬＥＦＲＡＣＵＲＥＩＮＡＮＡｌ－ＬｉＡＬＬＯＹ８０９０￥Ｊｉａｎｇ，Ｄａｍｉｎｇ；Ｗａｎｇ，Ｙｉｎｏｎｇ；Ｈｏｎｇ，Ｂａｎｄｅ；Ｌｅｉ，Ｔｉｎｇｑｕａｎ（ＨａｒｂｉｎＩｎｓｔｉｔｕｔｅｏｆＴｅｃｈｎｏｌｏｇｙ，Ｈａｒｂｉｎ１５００８０）Ｓｕ...     

电场固溶对2091A1-Li合金显微结构的影响

用电子探针及透射电镜研究了２０９１ＡｌＬｉ合金的电场固溶对显微结构的影响。结果发现，电场固溶通过促进含铜相溶解提高铜元素的固溶程度，加剧Ｌｉ原子在晶界上的非平衡偏聚，导致析出相δ′分布不均匀，体积分数减少，晶界上出现粗大的δ平衡相，Ｔ１及Ｓ′相均匀弥散分布，合金的力学性能（Ｔ６）达到了应变时效处理（Ｔ８）的水平。     

Development of design principles for a creep-limited alloy for turbine blades

Recent advancements in turbine-blade materials engineering are reviewed in light of general superalloy research and the author’s work on a new powder metallurgy IN-792 creep-limited alloy for application in blades of gas-turbine engines. The developed set of principles presented in this paper incorporates all the factors that must be taken into consideration in selecting and designing an alloy for turbine blades.