熟料烧结过程中氧化铁反应行为的热力学分析

通过对Fe2O3与碳酸钠、氧化钙以及硅酸钙反应的热力学分析,明确Fe2O3在铝土矿炉料烧结过程中的热力学反应规律。热力学计算、分析结果表明:Fe2O3在正常烧结温度范围内能与Na2CO3或CaO发生反应,但更易与CaO反应形成2CaO.Fe2O3或CaO.Fe2O3,Fe2O3和Na2O.Fe2O3能使2CaO.SiO2和3CaO.2SiO2转变为CaO.SiO2,CaO.SiO2进一步与Na2O.Al2O3或Na2O.Fe2O3反应生成不溶的三元化合物而造成烧结法生产氧化铝过程中Na2O和Al2O3的损失。4CaO.Al2O3.Fe2O3不能由铁酸钙和铝酸钠相互反应产生,而可能是CaO、Al2O3和Fe2O3三者直接反应的产物,且在烧结条件下Na2O.Fe2O3可分解4CaO.Al2O3.Fe2O3。     

利用金属络合物的电火花加工研究

在电火花加工的工作液中添加络合剂，使之与被蚀除的金属颗粒产生络合化学反应，生成可溶于工作液中的络合物。利用这种原理，可提高电火花加工性能，在小孔、深槽等加工应用中起到促进排屑的作用。     

REACTIVE DIFFUSION BETWEEN Si AND NbC AT 1300℃

ＲＥＡＣＴＩＶＥＤＩＦＦＵＳＩＯＮＢＥＴＷＥＥＮＳｉＡＮＤＮｂＣＡＴ１３００℃Ｃ．Ｒ．Ｋａｏ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｃａｌＥｎｇｉｎｅｅｒｉｎｇＮａｔｉｏｎａｌＣｅｎｔｒａｌＵｎｉｖｅｒｓｉｔｙＣｈｕｎｇＬｉ，Ｔａｉｗａｎ）Ｊ．Ｗｏｏｄｆ...     

Defect structure and chemical diffusion in nickel sulfide β-Ni3S2

The chemical composition, defect structure, and diffusion in nickel sulfide -Ni₃S₂ have been investigated in H₂S-H₂ mixtures containing between 1 and 65% H₂S between 560 and 700°C. Gravimetric, density, and X-ray studies were carried out. In the thermodynamically stable compound the ratio of Ni/S varied between 1.3 and 1.75. The X-ray examination showed a step change in the lattice parameter at the Ni/S ratio 1.4. A linear dependence of the density values (between 5.5 and 6.2 g/cm³) on the composition was observed. On the basis of the chemical composition and density measurements the number of nickel and sulfur atoms in 1 cm³ were determined. It has been shown that the Ni₃S₂ phase is defected in both anion and cation sublattices and that its chemical formula may be described as follows: Ni_3±yS_2x, where y 2x. It has been found that in the mixture containing 10% H₂S the process of defect formation is determined by their diffusion in the sulfide. The temperature dependence of the diffusion coefficient is described by the equation D = 13.15 exp(-30,000/RT) cm²/sec. No dependence of D on the sulfur partial pressure was observed, but this may be due to the relatively large uncertainties in the measurement of the diffusion coefficients.     

A computational fluid dynamic analysis of gas and particle flow in flame spraying

The flame spraying process, which is a common industrial thermal spraying application, has been analyzed by means of three-dimensional computational fluid dynamics (CFD) simulations. The process used at the Volvo Aero Corporation for the coating of fan and compressor housings has been modeled. The process uses the Metco 6P torch (Metco, Westbury, NY), which ejects a mixture of acetylene and oxygen at high speed through a ring of 16 orifices to form the flame. A stream of argon gas flowing through an orifice in the center of the ring carries a powder of nickel-covered bentonite through the flame to the spray substrate. The torch is cooled by a flow of air through an outer ring of 9 orifices. The simulation emulated reality closely by including the individual inlets for fuel, cooling air, and injected particles. The gas combustion was simulated as a turbulent, multicomponent chemically reacting flow. The standard, two-equation k-ε turbulence model was used. The chemical reaction rates appeared as source terms in the species transport equations. They were computed from the contributions of the Arrhenius rate expressions and the Magnussen and Hjertager eddy dissipation model. The first simulations included several intermediate chemical substances whose predicted concentration agreed favorably with measurements. Later, more simplified simulations incorporated only the global chemical reaction involving the initial and the final products, with corrections to the thermal properties being made to account for the missing intermediaries. The gas velocity and temperature fields predicted by the later simulations compared satisfactorily to those predicted by the earlier, more elaborate, ones. Therefore, the final simulations, which incorporated injected particles, were conducted employing the simplified model with only the global reaction. An in-house finite difference code was developed to calculate particle properties. Allowance was made for elliptical shapes, phase changes, and internal heat transfer with regard to the composite material. The particle velocities and temperatures predicted by the final simulations compared fairly well with experimental results obtained with the optical DPV2000 system.     

PATTERN RECOGNITION APLLIED TO STABILITY OF FILLED Ti_2Ni PHASES

Pattern recognition method is used for the investigation of stability,region of filled Ti_2Niphases in multi-dimensional bond-parameter space.The filling of C,N and O atoms intoT_6 octahedra consisting of atoms of earhy-transition elements makes the expansion of thestability region of Ti_2Ni phase,and the relative stability of AI_2Cu and MoSi_2 type com-pounds decreases after the introduction of non-metallic elements such as C,N and O.     

奥氏体化温度及冷却方式对20Mn2SiVB钢组织及性能的影响

通过各种试验手段,研究了20Mn2SiVB钢不同奥氏体化温度及不同冷却方式处理后其显微组织及其强度和塑性的变化,确定了最佳的热处理工艺。结果表明:900℃奥氏体化后风冷时钢的强塑性最好;在强塑性最佳时的微观组织是铁素体+粒状贝氏体。     

Temperature Dependence of the Magnetocrystalline Anisotropy in Nd_2Co_(14)B Compound

Easy and hard magnetization curves of Nd_2Co_(14)B compound have been measured withextracting-sample-magnetometer(μ_0H_(max)=6T)at 10～300 K.Magnetic anisotropy constants K_1 and K_2have been determined by fitting the hard magnetization curves,in which only K_1 ,K_2 and misalignment anglehave been taken as fitting parameters.The values of K_1 and K_2 at 4.2 K were derived by extrapolation.Anisotropy coefficients,x_2~° and x_4~°were derived from the anisotropy constants.The anisotropy constant K_2increases rapidly with increasing temperature when TT_(sr).The temperature depen-dence of the magnetic anisotropy coefficient x_2~° was fitted with the formula.The anisotropy coefficients x_2~°can be well described by the tenth-power law from 4.2 K to T_(sr)and by the sixth-power law from T_(sr_ to 300 K.     

Preparation and characterization of TiO2 photoelectrode codoped with aluminum and boron and its application in dye-sensitized solar cell

Nanocrystalline titania films codoped with aluminum and boron were prepared by cathodic vacuum arc deposition. In the process, titanium alloy target was used under an O2/Ar atmosphere, and sensitization of films were carried out by natural dye-sensitized complex in anhydrous ethanol. The structure, surface morphology and UV-vis spectra of titania films codoped were measured by X-ray diffraction analysis, scanning electron microscopy and ultraviolet-visible spectrometer. Theas-deposited films are found to be amorphous. The films annealed were examinedto be of anatase structure with orientation along the (101) planes, the averagecrystal size is in the range between 41 and 45 nm. SEM results show that thereare some pores in the codoped titania films, the optical properties of the dye-sensitized films were also measured which reveals that the spectral responses of films shift to the visible region. Under simulated sunlight illumination, the overall energy conversion efficiency of dye-sensitized nanocrystalline solar cell is 0.9%.