全文获取类型
收费全文 | 11884篇 |
免费 | 682篇 |
国内免费 | 268篇 |
专业分类
电工技术 | 64篇 |
技术理论 | 1篇 |
综合类 | 233篇 |
化学工业 | 6076篇 |
金属工艺 | 2508篇 |
机械仪表 | 358篇 |
建筑科学 | 132篇 |
矿业工程 | 63篇 |
能源动力 | 931篇 |
轻工业 | 187篇 |
水利工程 | 9篇 |
石油天然气 | 30篇 |
武器工业 | 32篇 |
无线电 | 369篇 |
一般工业技术 | 1521篇 |
冶金工业 | 258篇 |
原子能技术 | 43篇 |
自动化技术 | 19篇 |
出版年
2024年 | 25篇 |
2023年 | 223篇 |
2022年 | 235篇 |
2021年 | 381篇 |
2020年 | 380篇 |
2019年 | 339篇 |
2018年 | 362篇 |
2017年 | 310篇 |
2016年 | 284篇 |
2015年 | 274篇 |
2014年 | 578篇 |
2013年 | 646篇 |
2012年 | 695篇 |
2011年 | 1043篇 |
2010年 | 900篇 |
2009年 | 745篇 |
2008年 | 759篇 |
2007年 | 793篇 |
2006年 | 801篇 |
2005年 | 601篇 |
2004年 | 555篇 |
2003年 | 367篇 |
2002年 | 249篇 |
2001年 | 194篇 |
2000年 | 182篇 |
1999年 | 199篇 |
1998年 | 183篇 |
1997年 | 123篇 |
1996年 | 93篇 |
1995年 | 61篇 |
1994年 | 56篇 |
1993年 | 43篇 |
1992年 | 36篇 |
1991年 | 34篇 |
1990年 | 26篇 |
1989年 | 22篇 |
1988年 | 15篇 |
1987年 | 4篇 |
1986年 | 9篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1980年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
《Ceramics International》2022,48(17):24888-24897
In the furnace cycle test, the growth of oxide film leads to the propagation and coalescence of multiple cracks near the interface, which should be responsible for the spallation of thermal barrier coatings (TBCs). A TBC model with real interface morphology is created, and the near-interface large pore is retained. The purpose of this work is to clarify the mechanism of TBC spallation caused by successive initiation, propagation, and linkage of cracks near the interface during thermal cycle. The dynamic growth of thermally grown oxide (TGO) is carried out by applying a stress-free strain. The crack nucleation and arbitrary path propagation in YSZ and TGO are simulated by the extended finite element method (XFEM). The debonding along the YSZ/TGO/BC interface is evaluated using a surface-based cohesive behavior. The large-scale pore in YSZ near the interface can initiate a new crack. The ceramic crack can propagate to the YSZ/TGO interface, which will accelerate the interfacial damage and debonding. For the TGO/BC interface, the normal compressive stress and small shear stress at the valley hinder the further crack propagation. The growth of YSZ crack and the formation of through-TGO crack are the main causes of TBC delamination. The accelerated BC oxidation increases the lateral growth strain of TGO, which will promote crack propagation and coalescence. The optimization design proposed in this work can provide another option for developing TBC with high durability. 相似文献
12.
《中国有色金属学会会刊》2021,31(12):3800-3813
The Fe−Ni−TiO2 nanocomposite coatings were electrodeposited by pulse frequency variation. The results showed that the nanocomposite with a very dense coating surface and a nanocrystalline structure was produced at higher frequencies. By increasing the pulse frequency from 10 to 500 Hz, the iron and TiO2 nanoparticles contentswere increased in expense of nickel content. XRD patterns showed that by increasing the frequency to 500 Hz, an enhancement ofBCC phase was observed and the grain size of deposits was reduced to 35 nm. The microhardness and the surface roughness were increased to 647 HV and 125 nm at 500 Hz due to the grain size reduction and higher incorporation of TiO2 nanoparticles into the Fe−Ni matrix (5.13 wt.%). Moreover, the friction coefficient and wear rate values were decreased by increasing the pulse frequency;while the saturation magnetization and coercivity values of the composite deposits were increased. 相似文献
13.
Thermal barrier coatings (TBCs) produced by electron beam physical vapor deposition (EB-PVD) or plasma spray (PS) usually suffer from molten calcium-magnesium-alumino-silicate (CMAS) attack. In this study, columnar structured YSZ coatings were fabricated by plasma spray physical vapor deposition (PS-PVD). The coatings were CMAS-infiltrated at 1250?°C for short terms (1, 5, 30?min). The wetting and spreading dynamics of CMAS melt on the coating surface was in-situ investigated using a heating microscope. The results indicate that the spreading evolution of CMAS melt can be described in terms of two stages with varied time intervals and spreading velocities. Besides, the PS-PVD columnar coating (~100?μm thick) was fully penetrated by CMAS melt within 1?min. After the CMAS attack for 30?min, the original feathered-YSZ grains (tetragonal phase) in both PS-PVD and EB-PVD coatings were replaced by globular shaped monoclinic ZrO2 grains in the interaction regions. 相似文献
14.
Iryna Smokovych Manja Krüger Michael Scheffler 《Journal of the European Ceramic Society》2019,39(13):3634-3642
Silica-based coating systems were developed using polymer derived ceramics (PDCs) technology. Ceramic composites on the base of a SiO2 and SiNO matrix and homogeneously distributed Mo5SiB2, SiB6, Si and B fillers were manufactured. The coating systems have low porosity and provide a high oxidation resistance up to 100 h at 800 °C and 1100 °C in air. The influence of temperature and atmosphere of pyrolysis on the polymer precursor, the volume fraction of filler materials on the chemical composition of compacts as well as their high-temperature oxidation protection was investigated. 相似文献
15.
16.
随着我国环境保护法规《大气污染防治法》的修订和《涂料征收消费税通知》的公布,探讨了其对船舶涂料企业的冲击及其应对措施。 相似文献
17.
腐蚀阴极尖端的新方法 总被引:1,自引:0,他引:1
给出一种腐蚀阴极尖端的新方法,使得对阴极常用金属材料(W,Mo,Ir,Ta等)制作的阴极尖端的腐蚀效果明显,针尖对称性和重复性都很好,成品率和质量都有所提高. 相似文献
18.
19.
ABSTRACT: Shellac and wax-based citrus coatings were applied to Fallglo, Robinson, Sunburst, Dancy and Murcott tangerines, Nova and Orlando tangelos, and Temple oranges. Flavor volatiles were measured before and after storage. Concentrations of ethyl acetate, ethyl butyrate, isopentanol and 2-methyl-3-buten-2-ol increased markedly for fruit with shellac-based coatings, and were highly correlated with ethanol content, but at different ratios for the different varieties. The concentration increases were relatively less for fruit coated with the wax-based coatings, and suggest that high-gloss shellac and resin-based coatings are not appropriate for tangerines. 相似文献
20.
Two commercial Pt modified aluminide coatings (RT22 and MDC150L) on the same single crystal Ni-based superalloy (CMSX-4) were studied by: scanning electron microscopy; transmission electron microscopy; energy dispersive X-ray spectrometry; and gravimetry. The RT22 coating is an inward grown coating (high activity), while MDC150L is produced by outward growth (low activity). Samples were oxidised in still laboratory air at 1050 °C for various times up to 2000 h. It was found that the outward grown coating produced a slower growing oxide that was more spallation resistant. Several possible reasons for this were identified including: coating purity; coating surface topography; and ductile to brittle transition temperature. The microstructural differences between the two coatings in the as-coated condition were investigated and the development of their microstructure during heat treatment was described. A model for coating growth during heat treatment was proposed. 相似文献