环保高性能防腐涂料驱动未来市场

介绍了防腐涂料的新品种和防腐体系的选择,指出了我国防腐涂料的发展趋势。     

汽车防护条塑料件的涂装工艺及设计

介绍了汽车防护条的预处理工艺、涂装工艺及设计原则,列举了防护条涂装工艺的应用实例。     

纳米结构陶瓷涂层的外圆磨削力以及磨削表面精度的实验研究

使用功率计监测磨削加工的能量消耗，探讨了纳米结构陶瓷涂层的外圆磨削过程；对纳米陶瓷涂层和传统陶瓷涂层在磨削力和磨削表面精度方面进行了比较．磨削实验使用了外圆磨床和陶瓷结合剂金刚石砂轮．通过测量主轴功率获得切向磨削力，讨论了加工参数，如切深、进给率以及砂轮粒度对切向磨削力的影响．还对磨削后的涂层表面用粗糙度仪和扫描电镜进行了评估，揭示了表面粗糙度与加工参数的关系．     

Direct current bias applied to hot flame diamond deposition produces smooth low friction coatings

As-deposited diamond coatings generally have a high surface roughness which results in a high friction coefficient and extensive wear of the counter material in sliding contact. Therefore several methods for smoothening diamond coatings have been proposed, such as laser polishing, molten metal etching, thermochemical polishing and mechanical polishing. All these methods have some disadvantage e.g. long processing time or high processing temperature. Furthermore, they are all post-deposition treatments i.e. the manufacture of these coatings requires at least two processing steps, deposition and smoothening. With the present method which combines d.c. bias with hot flame diamond deposition, a smooth diamond surface is produced during the actual growth of the film. No post-deposition treatment is necessary. The surface roughness is not dependent on the coating thickness which means that thick coatings with smooth surface can be produced. In fact, the method has a smoothening effect, i.e. rough surfaces can be made smooth. The method is comparable to conventional hot flame deposition of diamond as to growth rate and cost of producing the coatings. The coatings have a nano-crystalline structure and a surface roughness of Ra = 25 nm, and result in a friction coefficient of 0.1 or less in dry sliding and about 0.05 in water-lubricated sliding against cemented carbide. Their wear resistance is virtually the same as that of conventional diamond films.     

紫外光固化聚合物涂层的原位光稳定化研究

选用实验室制备的四种新型反应型受阻胺类光稳定剂(r-HALS):4-甲基丙烯酰氧基-2,2,6,6-四甲基哌啶醇酯(MTMP)、4-丙烯酰氧基-2,2,6,6-四甲基哌啶醇酯(ATMP)、4-甲基丙烯酰氧基-1,2,2,6,6-五甲基哌啶醇酯(MPMP)和4-丙烯酰氧基-1,2,2,6,6-五甲基哌啶醇酯(APMP),实现了紫外光固化聚合物涂层(膜)的原位(in situ)光稳定化。通过室内人工光老化实验和在光氧化过程中黄度指数(Yellowness Index,YI)的监测,再与典型的商用HALS(Tinuvin770和Tinuvin292)进行平行实验对比,考察了r-HALS对紫外光固化聚合物涂层的光防护效果,探索一条紫外光固化聚合物涂层原位(in situ)光稳定化的新途径。     

Copper‐Free Clickable Coatings

The copper‐catalyzed azide–alkyne 1,3‐dipolar cycloaddition (CuAAC) is extensively used for the functionalization of well‐defined polymeric materials. However, the necessity for copper, which is inherently toxic, limits the potential applications of these materials in the area of biology and biomedicine. Therefore, the first entirely copper‐free procedure for the synthesis of clickable coatings for the immobilization of functional molecules is reported. In the first step, azide‐functional coatings are prepared by thermal crosslinking of side‐chain azide‐functional polymers and dialkyne linkers. In a second step, three copper‐free click reactions (i.e., the Staudinger ligation, the dibenzocyclooctyne‐based strain‐promoted azide–alkyne [3+2] cycloaddition, and the methyl‐oxanorbornadiene‐based tandem cycloaddition?retro‐Diels?Alder (crDA) reaction) are used to functionalize the azide‐containing surfaces with fluorescent probes, allowing qualitative comparison with the traditional CuAAC.     

激光-感应复合熔覆Ni基WC复合层的工艺研究

为了提高熔覆效率与消除熔覆层的裂纹,采用激光-感应复合熔覆的方法在A3表面获得了无气孔与裂纹的Ni基WC复合层。研究了不同的加工参量对复合层质量的影响,结果表明,随着激光比能的增加,粉末面密度增加;在相同的激光比能条件下,随着粉末面密度增加,熔覆层的高度增加,稀释率减小;在相同的粉末面密度条件下,随着激光比能的增加,熔覆层的宽度略有增加。此外,相对于单纯的激光熔覆技术,激光-感应复合熔覆的效率约可以提高5倍。在激光-感应复合熔覆过程中,熔覆层与基材间的温度梯度大大降低,这是Ni基WC复合层无裂纹的关键原因。     

Ambient flash sintering of reduced graphene oxide/zirconia composites:Role of reduced graphene oxide

Fabrication of graphene/ceramic composites commonly requires a high-temperature sintering step with long times as well as a vacuum or inert atmosphere,which not only results in property degradation but also significant equipment complexity and manufacturing costs.In this work,the ambient flash sintering behavior of reduced graphene oxide/3 mol% yttria-stabilized ZrO₂(rGO/3 YSZ) composites utilizing rGO as both a composite component and a conductive additive is reported.When the sintering condition is carefully optimized,a dense and conductive composite can be achieved at room temperature and in the air within 20 s.The role of the rGO in the FS of the rGO/3 YSZ composites is elucidated,especially with the assistance of a separate investigation on the thermal runaway behavior of the rGO.The work suggests a promising fabrication route for rGO/ceramic composites where the vacuum and furnace are not needed,which is of interest in terms of simplifying the fabrication equipment for energy and cost savings.