Elution of copper from vermiculite with environmentally benign reagents

For the purpose of remediation of soils polluted by heavy metals, the use of some strong synthetic chelating agents such as ethylenediaminetetraacetic acid (EDTA) has been proposed. However, EDTA would not be considered as the preferential choice for the remediation of soil polluted with heavy metals like copper because of its nonbiodegradability and permanent residence in the natural environment. In the present work, some novel environmentally benign chelating agents, glucosamine hydrochloride, chito-oligosaccharide and -asparaginic-N,N-diacetic acid (ASDA) were screened to find alternatives to EDTA by investigating the elution of copper from vermiculite with these reagents and comparing their effectiveness with EDTA. The effects of suspension contact time, reagent concentration and equilibrium pH of the solution on the removal of copper were examined. A stoichiometric amount of EDTA can quantitatively remove copper in both acidic and neutral conditions. Chito-oligosaccharide was a slightly less-effective reagent under acidic conditions compared to EDTA, and an amount well in excess of stoichiometry is required to achieve the maximum removal of copper from vermiculite. Glucosamine hydrochloride shows a relatively weak ability for the liberation of copper. The elution behavior of ASDA was equivalent to EDTA in acidic and neutral media. It was concluded that ASDA is the best substitute for EDTA because of its similar high complexing ability and superior biodegradability.     

高频微型脉冲管制冷机的实用化研究

脉冲管制冷机经过多年的发展，性能不断改善，目前已开始进入实用化阶段。高频微型脉冲管制冷机结构紧凑，应用方便，并且主要工作在需求量较大的液氮温区，因此将首先得到一定规模的应用。介绍了作者针对脉冲管制冷机在红外和超导方面的应用所作的实用化工作，讨论了尚待解决的问题。     

小功率行波管可靠性数字仿真的研究

基于对实际器件的测试数据,采用模糊数学和最可能故障法建立整个器件的可靠性模型.引入可靠性分布密度函数,将实际测试得到的离散数据拟合成随时间变化的连续函数,不仅可得到小功率行波管测试性能的评估,而且还可以对其可靠性进行预测;进一步研究,还可以给出预测的准确度概率.本文主要讨论小功率行波管可靠度评估模型的建立、数据处理与精度分析等,并对预测与准确度的概率给予简要的介绍.     

锅炉炉管爆破原因分析

对在爆裂的水冷壁管正常管段和鼓包处所取的试样分别进行化学分析、金相检验、硬度测定和高温拉伸试验。分析结果表明，在近烧嘴的炉管长期处于超温工作状态，引起该部位材质严重劣化，高温强度不断下降，当该部位的高温强度低于锅炉炉管对材质所要求的技术条件即会发生爆裂。对炉管的继续使用提出了应急的预防措施。     

A novel technique for fabrication of metallic structures on polyimide by selective electroless copper plating using ion implantation

The successful use of palladium ion implantation into polyimide to seed an electroless plated film of copper on the polyimide surface is reported. Polyimide (Hitachi PIX 3400) was implanted with palladium ions to doses of 1.5 × 10¹⁵ − 1.2 × 10¹⁷ ions cm⁻² using a MEVVA ion implanter. The implanted ions acted as sites for nucleation of copper film. A copper film was then deposited on implanted polyimide using a commercial electroless plating solution. The ion energy was kept low enough to facilitate a low critical ‘seed’ threshold dose that was measured to be 3.6× 10¹⁶ Pd ions cm⁻². Test patterns were made using polyimide to study the adaptability of this technique to form thick structures. Plated films were studied with optical microscopy, Rutherford Backscattering Spectrometry (RBS) and Profilometry. The adhesion of films was qualitatively assessed by a ‘scotch tape test’. The film growth (thickness) was observed to be linear with plating time. A higher implantation dose led to greater plating rates. The adhesion was found to improve with increasing dose.     

LP-401磷化液在冷拔钢管生产中的应用

简单介绍了磷化液成膜原理。通过对比试用，得出了较为合理的工艺参数。实践证明，LP-401磷化液能够满足冷拔无缝钢管生产要求。     

1422轧机滑块式万向接轴的故障及处理

以热轧板厂粗轧主传动滑块式万向接轴为例，分析了该接轴及接轴平衡机构的常见故障及其排除方法，提出了日常维护措施。     

螺旋管簧的可靠性优化设计

讨论了螺旋管簧的可靠性优化设计问题。在基本随机变量的概率特性已知的情况下，采用二阶矩法和可靠性优化设计方法对螺旋管簧进行了可靠性优化设计。通过计算机程序可以直接实现螺旋管簧的可靠性优化设计，迅速准确地得到螺旋管簧的可靠性优化设计信息。     

彩色显像管电子束亮度分布自动测量系统

电子束轮廓的描述是彩色显像管特性检测中的难点之一。采用光电转换与计算机信息处理技术，通过自动调整边界条件和三次样条拟合的方法建立了电子束轮廓自动测量系统。与传统测量方法相比，该系统精度高，测试速度快，极大地减轻了测试人员的工作强度，并增加了对排列率和并列率等的测试功能。     

涡流管类比逆流换热器方法的研究

结合Scheper，Lewins和Bejan的理论模型，对涡流管类比逆流换热器模型进行了深入地分析，得出了冷流分量对温度分离效应的函数关系式，为了解涡流管机理和实验中强化涡流管温度分离效应提供了理论依据。