A simple mathematical analysis on the effect of sand in Cr(VI) reduction using zero valent iron

A simple mathematical model was proposed to analyze the enhancement of Cr(VI) reduction when sand materials are added to the zero valent iron (ZVI). Natural decay of Cr(VI) in a control experiment was analyzed by using a zero-order decay reaction. Adsorption kinetics of Cr(VI) to sand was modeled as a first-order reversible process, and the reduction rate by ZVI was treated as a first-order reaction. Natural decay of Cr(VI) was also included in other experiments, i.e., the adsorption to sand, the reduction by ZVI, and both adsorption and reduction when sand and ZVI are present together. The model parameters were estimated by fitting the solution of each model to the corresponding experimental data. To observe the effect of sand addition to ZVI, both adsorption and reduction rate models were considered simultaneously including the natural decay. The solution of the combined model was fitted to the experimental data to determine the first-order adsorption and reduction rate constants when sand as well as ZVI is present. The first-order reduction rate constant in the presence of sand was about 35 times higher than that with ZVI only.     

25Cr3Mo3NiNb二次硬化钢中的碳化物

利用TEM和萃取相分析方法，研究了25Cr3Mo3NiNb二次硬化钢淬火回火组织中的碳化物。结果表明，随淬火奥氏体化温度的升高，M6C型碳化物逐渐溶解。于1050℃奥氏体化时M6C型碳化物全部溶解，淬火态试样中只有少量的Nb(C，N)颗粒和自回火M3C型碳化物。随回火温度的升高，先后析出ε、M3C、M2C和M7C3等类型的碳化物。Nb(C，N)颗粒可以阻止淬火奥氏体晶粒的异常长大，而高温回火析出的M2C碳化物有二次硬化作用，从而提高回火稳定性和高温强韧性。     

热处理对Ti-25V-15Cr-2Al-2Mo-0.2C合金组织稳定性的影响

研究了热处理对Ti-25V-15Cr-2A1-2Mo-0.2C阻燃β钛合金组织稳定性的影响。结果表明，高温固溶并直接时效处理导致合金β基体上析出较多的α相沉淀，尤其在随后的热暴露组织中形成了恶化合金塑性的连续晶界α膜。然而，若在时效前再进行一次低温固溶处理则可明显减少α相的析出数量，合金的热稳定性因此而得到显著改善。     

高速钢W6Mo5Cr4V2的脱磷试验

在３０ｋｇ感应炉上用ＣａＯ－Ｎａ２ＣＯ３－ＣａＦ２－ＦｅｘＯ（ＭｏＯ３）渣、ＭｏＣｌ６粉剂和Ａｌ－Ｃａ合金作脱磷剂对高速钢Ｗ６Ｍｏ５Ｃｒ４Ｖ２进行脱磷试验。结果表明，ＣａＯ－Ｎａ２ＣＯ３－ＣａＦ２－ＦｅｘＯ渣的脱磷效果最好，一般脱磷率可达２６％￣５６％。     

Zr-2/Cr反应扩散研究

研究了Zr-2/Cr扩散偶在1023－1123K范围内的反应扩散，用扫描电镜观察反应宽度，用能谱仪（EDS）测定了反应层Zr,Fe和Cr沿扩散方向的浓度分布，研究了反应层的生长动力学，结果表明，反应层生长基本符合抛物经规律，生长过程受扩散控制，用Boltzman-Matano-Heumann模型计算了Cr在反应层Zr（Fe,Cr）2中的互扩散系数D，得到了互扩散系数D与温度的Arrhenius方程，由计算的扩散数据与Cr在Zr中形成稀固溶体时Cr的扩散数据比较可知，Cr在金属间化合物Zr（Fe,Cr）2中的扩散比在稀因溶体中的扩散快5个数量级。     

Probing the early stages of polymerization of ethylene on a model chromium/silica catalyst by Fourier transform infrared spectroscopy

The nature of the interaction of monomer, and the early stages of growth of oligomers of ethylene on a rather more uniform surface of Cr/SiO₂ catalyst than hitherto studied has been investigated by differenceFTIR spectroscopy using C₂D₄ and C₂H₄ as reactants both with and without subsequent treatment of the catalyst with CO andTHF. The active catalyst was prepared by reaction of vapour phase CrO₂Cl₂ with the vicinal hydroxyls of the silica surface. Three distinct kinds of methylene groups were detected. Arguments are given for assigning the peaks at 2935 and 2860 cm^–1 to CH₂ groups directly bound to the active site and those at 2920 and 2850 to CH₂s in the growing chain well removed from the Cr. The peaks at 2160 and 2165 cm^–1 are attributed to CD₂ groups hydrogen bonded to surface hydroxyls.     

Cr12钢的预处理工艺研究

本文研究了Ｃｒ１２钢经４种不同的预处理工艺处理后钢中碳化物的大小，数量，分布及钢的硬度，强度和韧性，试验结果表明，经调质处理，高温固溶淬火＋高温退火处理后，Ｃｒ１２钢中碳化物的大小，分布及其组织，性能均优于常规球化退火预处理的。通过扫描电镜对冲击断口的分析，初步探讨了新的预处理工艺提高韧性的原因。     

常减压蒸馏装置阻垢剂进料管腐蚀与防护

通过对常减压蒸馏装置阻垢剂进料管的材质、性能、工作条件及腐蚀形貌、腐蚀产物的全面分析,找出了使进料管发生大面积腐蚀的腐蚀介质为环烷酸.并提出了减缓阻垢剂进料管环烷酸腐蚀的措施,主要包括选用更耐蚀的316或316 L材质以及改进三通结构等.     

深部调剖驱油交联剂的研究

为提高非均质性严重的地层原油采出率 ,合成了用于聚合物驱油的 4种交联剂 ,并对聚合物种类、用量和其与交联剂组成的体系进行了评价。 4 0℃下铝交联剂凝胶粘度低 ,酚醛树脂交联剂低温下不成胶 ,而有机铬交联剂 (J2 )和有机复合胺 (J3)交联效果好。当选用HPAM/有机铬交联剂 /有机酸交联体系时 ,其中HPAM相对分子质量为 2 1× 10 7,可通过改变体系pH值调节成胶速度 ,pH值 6 5时 ,14 0 0mg/LHPAM和 4 0 0mg/LJ2组成的体系在 4 0℃、30d可形成粘度为12 0mPa·s以上的凝胶 ,且热稳定性好 ,成胶时间能满足现场施工需要。 14 0 0mg/LHPAM和10 0 0mg/LJ3交联剂组成的体系 ,成胶时间长 ,有利于油田深部调剖驱油     

ZG3Cr13钢经长期时效后组织及硬度的研究

研究了ZG3Cr13钢在550℃～600℃的工作温度区间经2500h长期时效后的硬度及组织的变化。结果表明，在时效1000h内，硬度有明显的下降，之后趋于稳定；组织变化与正常处理后的组织均匀化程度有关，原始组织越均匀组织稳定性和热强性越高。