Homogeneous Plastic Flow of Fully Amorphous and Partially Crystallized Zr_(41.2)Ti_(13.8)Cu_(12.5)Ni_(10)Be_(22.5) Bulk Metallic Glass

The homogeneous plastic flow of fully amorphous and partially crystallized Zr(41.2)Ti(13.8)Cu(12.5)Ni(10)Be(22.5) bulk metallic glass (Vitl) has been investigated by compression tests at high temperatures in supercooled liquid region. Experimental results show that at sufficiently low strain rates, the supercooled liquid of the fully amorphous alloy reveals Newtonian flow with a linear relationship between the flow stress and strain rate. As the strain rate is increased, a transition from linear Newtonian to nonlinear flow is detected, which can be explained by the transition state theory. Over the entire strain rate interval investigated, however, only nonlinear flow is present in the partially crystallized alloy, and the flow stress for each strain rate is much higher. It is found that the strain rate-stress relationship for the partially crystaltized alloy at the given temperature of 646 K also obeys the sinh law derived from the transition state theory, similar to that of the initial homogeneous amo     

液态挤压在铝合金减震筒上的应用：液态挤压比压值对制件性能影响的分析

指出了压力铸造及热挤压工艺生产铝合金减震筒的缺点，阐述了液态挤压的特征，介绍了液态挤压在减震筒上的应用，分析了比压值对制件性能的影响。     

Direct atomic scale analysis of the distribution of Cu valence states in Cu/γ-Al2O3 catalysts

In this paper, the microstructure of a 1 wt.% Cu/γ-Al₂O₃ catalyst that was reduced in a 4% hydrogen/argon atmosphere at temperatures of 523, 773 and 1073 K, is studied by Z-contrast imaging and electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM). Results show that the copper species are well dispersed when the catalyst is reduced below 523 K. At 773 K, separated Cu(I) and Cu(0) species are found existing as ring-like and bulk-like particles. This appears to indicate that the copper has not been reduced to its metallic form due to the interaction between the copper oxide and the support. Large spherical particles having core-shell structures with Cu(I) in the shells and Cu(0) in the cores are generated when the catalyst is reduced at 1073 K. The formation of partially oxidized copper species upon reduction at 1073 K is attributed to the metallic copper interaction with the alumina support. This study also demonstrates that high-spatial resolution Z-contrast imaging and EELS performed simultaneously can provide unique information on the morphology and chemistry of metal species in supported metal catalysts.     

试制STM-R80钻探用无缝钢管

采用42MnMo7、41MnV5钢锻坯,经热轧穿孔、冷拔加工,试制出STM-R80地质钻探管。该地质管经检验和使用,质量符合要求。介绍了钢的化学成分、试制的主要工艺过程及其参数。     

Cu/ZrO2催化剂的研究进展及其应用

综述了催化剂Cu／ZrO2的制备方法及其在CO／H2、CO2／H2合成甲醇、NOx的分解、醇胺脱氢合成氨基酸、CO的氧化及CO＋NO反应等方面的应用。     

Effects of Working Fluid,Tubeside Enhancement and Bundle Depth on the Optimized Fin Geometry of a Horizontal Condenser Tube

A theoretical study has been made to optimize the fin geometry of a horizontal finned tube which is to be usedfor condensers that handle the vapor load of a liquid phase change cooling module.Systematic numerical calcu-lations of the vapor to coolant heat transfer have been performed for parametric values of fin height,fin spacing,vertical bundle depth and tubeside heat transfer coefficient.Three dielectric fluids (R-113,FC-72,and FC-87)at atmospheric pressure were selected as the working fluids.For a single tube with optimized fin geometry,theaverage heat flux increased in the order of FC-87,R-113 and FC-72.Both the optimum fin height and optimumfin spacing increased with increasing vertical bundle depth.     

Diffusion Behaviour of Fe-Cu Interface of Copper Brazed Double-wall Steel Tubes

By means of electron probe(EPMA),scanning electron microscope(SEM),and optical microscope(QM),the diffusion behaviour on the Fe-Cu interface of copper brazed double-wall steel tubes andthe microstructure of the diffusion layer have been investigated.There are three kinds of metallurgicalbonds between copper plating layer and steel substrate: (1)the Cu diffusing into steel substratealong grain boundary of ferrite;(2)the Cu diffusion into grain bulk of ferrite: (3)the Fe diffusing intoCu layer.The copper brazed double-wall steel tubes are formed by the combination of the diffusionsmentioned above and this is the reason for excellent mechanical and technological properties of thecopper brazed double-wall steel tubes.     

旋风管不同排尘结构内流场及颗粒浓度场分析

采用智能型五孔球探针测试技术及等动采样方法，对两种新型旋风管排尘结构内的流场及颗粒浓度场进行测量。通过大量实验，发现在双锥内部存在的二次流及涡流使得颗粒分布呈现横向返混状态，这不利于颗粒的分离，对单锥与双锥两种不同排尘结构内的流场及颗粒浓度场分布特点进行了对比研究，为进一步优化旋风管排尘结构，提高分离性能奠定了实验基础。     

Diffusion and influence of Cu on properties of CdTe thin films and CdTe/CdS cells

The effective diffusion coefficients of Cu for thermal and photodiffusion in the CdTe films have been estimated from resistivity versus duration of thermal or photoannealing curves. In the temperature range 60–200°C the effective coefficient of thermal diffusion (D_t) and photodiffusion (D_ph) are described as D_t=7.3×10⁻⁷exp(−0.33/kT) and D_ph=4.7×10⁻⁸exp(−0.20/kT).It is found that the diffusion doping of CdTe thin films by Cu at 400°C results in a sharp decrease of resistivity up to 7 orders of magnitude of p-type material, depending on thickness of Cu film. The comparative study of performance of CdTe(Cu)/CdS and CdTe/CdS cells has been studied. It is shown that the diffusion doping of CdTe film by Cu increases efficiency of CdTe(Cu)/CdS cells from 0.9% to 6.8%. The degradation of photovoltaic parameters of CdTe(Cu)/CdS cell, during testing under forward and reverse bias at room temperature, proceeds at a larger rate than those of CdTe/CdS cell without Cu. The degradation of performance of CdTe(Cu)/CdS cells is tentatively assigned to electrodiffusion of Cu in CdTe, resulting in redistribution of concentration of Cu-related centers in CdTe film and heterojunction region.