硫脲树脂对Cu~(2+)吸附性能研究

考察了不同吸附时间、pH值和吸附温度下,聚对苯甲酰基硫脲树脂和聚酯基硫脲树脂对Cu2+的吸附性能影响;并对吸附动力学和热力学进行了研究。     

Preparation of ultra-fine copper powder and its lead-free conductive thick film

In this paper, non-agglomerated monodispersed ultra-fine copper metallic powders have been synthesized with chemical reduction method. Fine lead-free glass powders were also prepared by solid synthesis process. Thick film paste prepared by above-mentioned copper metallic powders and lead-free glass powders was applied as conductive paste of MLCC. Mixture of glass and zinc oxide give the thick film a high adhesion strength which is attributed to the rough interface from interfacial reaction between glass and chip, and a good densification. Diffusion of metal between copper thick film and nickel thick film is clear. Ni-Cu solid solution appears under high temperature firing.     

开发稀土铝合金镀层油管的设想

叙述了热浸镀铝钢的镀层组织、耐蚀性能及研究进展，介绍了稀土对铝合金耐蚀性的影响作用，在此基础上提出了开发稀土铝合金镀层油管的设想。     

高频微型脉冲管制冷机的实用化研究

脉冲管制冷机经过多年的发展，性能不断改善，目前已开始进入实用化阶段。高频微型脉冲管制冷机结构紧凑，应用方便，并且主要工作在需求量较大的液氮温区，因此将首先得到一定规模的应用。介绍了作者针对脉冲管制冷机在红外和超导方面的应用所作的实用化工作，讨论了尚待解决的问题。     

Copper(II) removal from aqueous solutions by fly ash

The removal of Cu(II) by adsorption on fly ash has been found to be concentration, pH and temperature dependent. The kinetics of adsorption indicates the process to be diffusion controlled. The Langmuir constants have been calculated at different temperatures, and the adsorption has been found to be endothermic (ΔH = 15.652 kcal mol^?1). The maximum removal is observed at pH 8.0, and variation in adsorption with pH has been explained on the basis of surface ionisation and complexation.     

东方红浆砌石重力坝扬压力安全评价

东方红水库大坝是一座运行近40a的浆砌石重力坝，坝体裂缝、坝体渗漏及坝体碳化严重，扬压力有逐年增高的趋势。本文利用坝基扬压力测压管水位观测资料建立了测压管水位的统计模型，并结合现场渗漏实测流量资料建立了渗流反分析模型，详细分析了坝基的渗流性态和扬压力状态，并对其渗流性态做出安全评价。     

A kinetic model for the acid-oxygen pressure leaching of Ni–Cu matte

A semi-empirical mathematical model for the acid-oxygen pressure leaching of Ni–Cu matte is presented, based on data from batch leaching experiments. The primary controlling factor in the leaching process is found to be galvanic inhibition of the more highly oxidized copper and nickel sulfide species by less oxidized species, particularly Ni alloy and Ni₃S₂. The leaching rate of many species is greatly reduced by the presence of one or both of these phases, and others will not commence leaching until neither is present. The mathematical model is based on first-order chemical reaction controlled rate expressions, as the reactions occurring are electrochemical in nature. Mass transfer effects are included only empirically. Some possibly diffusion-related phenomena are noted, although the model is not extended to incorporate these effects on a fundamental level. The model is verified and extended by the inclusion of several different factors that were tested experimentally. The effects of variations in O₂ flow rate and partial pressure, initial particle size, reaction pulp density and initial acid concentration were all studied, and included in the model. Variations in O₂ flow rate and partial pressure are found to affect the reaction rates via the dissolved oxygen concentration in the solution phase.     

小功率行波管可靠性数字仿真的研究

基于对实际器件的测试数据,采用模糊数学和最可能故障法建立整个器件的可靠性模型.引入可靠性分布密度函数,将实际测试得到的离散数据拟合成随时间变化的连续函数,不仅可得到小功率行波管测试性能的评估,而且还可以对其可靠性进行预测;进一步研究,还可以给出预测的准确度概率.本文主要讨论小功率行波管可靠度评估模型的建立、数据处理与精度分析等,并对预测与准确度的概率给予简要的介绍.     

锅炉炉管爆破原因分析

对在爆裂的水冷壁管正常管段和鼓包处所取的试样分别进行化学分析、金相检验、硬度测定和高温拉伸试验。分析结果表明，在近烧嘴的炉管长期处于超温工作状态，引起该部位材质严重劣化，高温强度不断下降，当该部位的高温强度低于锅炉炉管对材质所要求的技术条件即会发生爆裂。对炉管的继续使用提出了应急的预防措施。     

FLOW OF NEWTONIAN FLUIDS THROUGH SINUSOID ALLY CONSTRICTED TUBES. NUMERICAL AND EXPERIMENTAL RESULTS

Numerical and experimental predictions of pressure drops in the flow of Newtonian fluids through sinusoidally constricted tubes (SCT) are carried out. The numerical evaluations analyzed in this work are obtained from the following methods: Geometric Iteration (GJM), Geometric Iteration with First and Second Upwinds (GIM1, GIM2), Successive Over Relaxation by Line (SORBLM), Global Galerkin Spectral Method (GGSM), Collocation (CM) and Dufort-Frankel (DFM). The GIM1, GIM2 and SORBLM are applied to SCT and explained in this work. The other methods have been previously reported in the literature with the same purpose. Experiments are accomplished for constrictions of approximately 40,60 and 80% of the average tube diameter and results compare well with numerical predictions of the steady flow. It is concluded that special attention should be given to evaluations of the friction factor ƒ for Reynolds numbers Re between the onsets of flow separation and turbulence due to flow instability. Finally, the SCT as a model for porous media (PM) is discussed.