工程机械表面涂层早期缺陷与防治措施

针对采用液体涂料进行涂装的各类工程机械,调查表面涂层常出现的早期缺陷,分析其产生的原因并提出了防治建议措施。     

一种无溶剂环氧酚醛管道补口涂料的性能评定

在管道干线防腐层技术中,三层结构聚乙烯(3PE)防腐层和熔结环氧(FBE)是两种非常成熟并广为应用的技术。而在管道补口防腐层技术中,国内主要采用聚乙烯热收缩带为主,国外补口材料有多种类型,包括液体涂料,熔结环氧粉末和聚烯烃涂层等。管道补口防腐层关系到整条管线的防腐质量,也是导致管道失效的薄弱环节。介绍了国外关于管道补口防腐层的短期和长期性能的评定方法以及无溶剂环氧酚醛124在该评定方法下的产品性能。     

汽车面漆色差产生的原因及解决方法

根据笔者在实际工作中的经验,讨论了各种色差产生的原因及解决方法。     

热反射涂料对储罐腐蚀性能的作用规律研究

太阳热反射涂料用于储罐外壁涂装可以使其外表面保持相对低温,不仅可以达到减少储罐降温喷淋的频次,起到节水节电的作用,同时,降低温度也降低了相应的腐蚀速率,达到比传统防腐涂料更好的防腐效果。     

Performance enhancement of multicrystalline silicon solar cells and modules using double‐layered SiNx:H antireflection coatings

Silicon nitride coating deposited by the plasma‐enhanced chemical vapor deposition method is the most widely used antireflection coating for crystalline silicon solar cells. In this work, we employed double‐layered silicon nitride coating consisting of a top layer with a lower refractive index and a bottom layer (contacting the silicon wafer) with a higher refractive index for multicrystalline silicon solar cells. An optimization procedure was presented for maximizing the photovoltaic performance of the encapsulated solar cells or modules. The dependence of their photovoltaic properties on the thickness of silicon nitride coatings was carefully analyzed. Desirable thicknesses of the individual silicon nitride layers for the double‐layered coatings were calculated. In order to get statistical conclusions, we fabricated a large number of multicrystalline silicon solar cells using the standard production line for both the double‐layered and single‐layered antireflection coating types. On the cell level, the double‐layered silicon nitride antireflection coating resulted in an increase of 0.21%, absolute for the average conversion efficiency, and 1.8 mV and 0.11 mA/cm² for the average open‐circuit voltage and short‐circuit current density, respectively. On the module level, the cell to module power transfer factor was analyzed, and it was demonstrated that the double‐layered silicon nitride antireflection coating provided a consistent enhancement in the photovoltaic performance for multicrystalline silicon solar cell modules than the single‐layered silicon nitride coating. Copyright © 2015 John Wiley & Sons, Ltd.     

Fabrication of Titanium Bipolar Plates by Rubber Forming Process and Evaluation Characteristics of TiN coated Titanium Bipolar Plates

In this study, the rubber forming process is used to fabricate a micro‐channel titanium plate for a PEM fuel cell. The micro‐channel plate is fabricated using a 200 ton hydraulic press, and various parameters (punch speed, press pressure, rubber thickness, rubber hardness) are investigated in order to evaluate the formability. TiN films are deposited by reactive DC magnetron sputtering (DCMS) with an electromagnetic field system (EMFS). For the uncoated titanium and TiN‐coated titanium substrates, the hardness, surface roughness, and corrosion resistance are estimated by nano‐indentation and electrochemical methods, respectively. The improved corrosion resistance of the TiN films can be attributed to the densification of the film caused by enhancement of nitrification with increasing high reactive nitrogen radicals. The uncoated titanium and TiN‐coated titanium bipolar plates are combined with a unit cell for a performance test, and respective current densities of 0.396 and 0.888 A cm⁻² at 0.6 V are obtained.     

非均相沉淀法在无机包覆中的应用

结合近来非均相沉淀法在颗粒包覆中的应用进展情况,对利用该法进行颗粒包覆时的一些关键因素:覆层前驱物溶液浓度、体系pH值、基体颗粒的分散、包覆类型等作了较系统论述.     

热障涂层热导率的研究进展

简要回顾了热障涂层体系的发展,讨论了氧化锆陶瓷材料的传热规律,包括涂层微观结构、陶瓷成分等因素的影响.同时指出了改进陶瓷涂层热导率的方法和开发适用于更高温度下的陶瓷涂层材料的指导原则,并详细介绍了改善热障涂层热导率的研究现状.     

泡沫Ni-32Cr合金的结构及其性能研究

以聚氨酯泡沫树脂为基体,采用浆料涂覆、电沉积、热解和合金化等技术制备出网状结构的高孔率泡沫Ni-32Cr合金.对该泡沫合金的形貌结构、成分分布和使用性能进行了分析研究.实验结果表明:该泡沫合金骨架平整,成分均匀,相对密度为6.4%,骨架的室温显微硬度HV为168,压缩强度约5MPa,且800℃时氧化1h,其增重率小于2×10-3.     

多元合金化强化TiN复合镀层的研究进展

多元合金化是提高TiN镀层的有效途径之一,也是目前研究的热点.本研究综述了多元合金强化TiN复合镀层的最新进展,详述了Ti(CxN1-x),(Ti,Al)N,(Ti,Nb)N,Ti-Si-N,Ti-B-N,Ti-C3N4复合镀层的工艺、结构和性能,指出了今后TiN镀层的研究方向.