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51.
稀土元素对钯室温电学性能的影响 总被引:2,自引:2,他引:2
研究了稀浓度(0.6at%以下)稀土元素(La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Er、Yb)对钯的室温电学性能的影响。所有稀土元素均提高钯的电阻率(p)、降低电阻温度系数(α),实验结果与理论分析证明(p·α)_((?)d-RE)d=(p·α)_(Pd)。Gd以前的稀土元素降低钯的对铜热电势(ε),其余重稀土元素增大钯的对铜热电势。按0.1at%RE归一化处理的实验数据表明,轻稀土元素对钯电阻率的影响稍大于重稀土,但Ce、Eu、Yb呈反常影响,化合价和尺寸因素是影响电学性能的主要因素。 相似文献
53.
54.
稀土元素Ce对纯铜导电性及力学性能的影响 总被引:12,自引:0,他引:12
在纯铜中加入稀土元素Ce,研究不同含量Ce及不同保温时间对纯铜的导电性、抗拉强度、硬度、耐磨性等的影响.研究发现在纯铜中加入Ce起到净化、去杂质的作用,改善纯铜的导电性;也可使晶粒细化,改善纯铜的抗拉强度及其它力学性能.且熔炼时加入稀土后的保温时间要适当.在试验的条件下保温时间以30 min为宜,稀土Ce的最佳加入量w为0.02%. 相似文献
55.
Q.H. Zhang R. Du J.H. Zhang Q.B. Zhang 《International Journal of Machine Tools and Manufacture》2006,46(12-13):1582-1588
This study focuses on using ultrasonic to improve the efficiency in electrical discharge machining (EDM) in gas medium. The new method is referred to as ultrasonic-assisted electrical discharge machining (UEDM). In the process of UEDM in gas, the tool electrode is a thin-walled pipe, the high-pressure gas medium is applied from inside, and the ultrasonic actuation is applied onto the workpiece. In our experiment, the workpiece material is AISI 1045 steel and the electrode material is copper. The experiment results indicate that (a) the Material Removal Rate (MRR) is increased with respect to the increase of the open voltage, the pulse duration, the amplitude of ultrasonic actuation, the discharge current, and the decrease of the wall thickness of electrode pipe; and (b) the surface roughness is increased with respect to the increase of the open voltage, the pulse duration, and the discharge current. Based on experimental results, a theoretical model to estimate the MRR and the surface roughness is developed. 相似文献
56.
57.
K. G. Shkadinskii N. I. Ozerkovskaya S. V. Kostin 《Combustion, Explosion, and Shock Waves》2004,40(3):285-294
The specific features of dynamics of the thermal explosion in systems porous reagent–active gas–solid product under conditions where the heattransfer and masstransfer regions are separated from the ambient medium are considered. In addition to the competition of heat release and heat removal, the process of initiation of exothermal chemical interaction in these systems under normal pressures depends significantly on conditions of filtration transport of the gaseous reagent. The induction and postinduction periods of the thermal explosion are studied. The theoretical analysis of thermalexplosion issues is supplemented by an experimental study of the process for the porous titanium–nitrogen–titanium nitride system. 相似文献
58.
Processing-structure-multi-functional property relationship in carbon nanotube/epoxy composites 总被引:1,自引:0,他引:1
Erik T. Thostenson 《Carbon》2006,44(14):3022-3029
The novel properties of carbon nanotubes have generated scientific and technical interest in the development of nanotube-reinforced polymer composites. In order to utilize nanotubes in multi-functional material systems it is crucial to develop processing techniques that are amenable to scale-up for high volume, high rate production. In this research we investigate a scalable calendering approach for achieving dispersion of CVD-grown multi-walled carbon nanotubes through intense shear mixing. Electron microscopy was utilized to study the micro and nanoscale structure evolution during the manufacturing process and optimize the processing conditions for producing highly-dispersed nanocomposites. After processing protocols were established, nanotube/epoxy composites were processed with varying reinforcement fractions and the fracture toughness and electrical/thermal transport properties were evaluated. The as-processed nanocomposites exhibited significantly enhanced fracture toughness at low nanotube concentrations. The high aspect ratios of the carbon nanotubes in the as-processed composites enabled the formation of a conductive percolating network at concentrations below 0.1% by weight. The thermal conductivity increased linearly with nanotube concentration to a maximum increase of 60% at 5 wt.% carbon nanotubes. 相似文献
59.
M. Bilal Banaras Khan H.A. Rahnamaye Aliabad M. Maqbool S. Jalai Asadabadi I. Ahmad 《Computer Physics Communications》2014
Thermoelectric properties of two antiperovskites SbNCa3 and BiNCa3 are calculated using first principles calculations. High values of Seebeck coefficients are observed for these materials. Electrical and thermal conductivities are also calculated. Increase in thermal conductivity and decrease in electrical conductivity are found with increasing temperature. The maximum values of thermal conductivity are 92×1014 W/m K s and 88×1014 W/m K s for SbNCa3 and BiNCa3 respectively at a temperature of 900 K. The peak values of 5×1020/Ω m s and 5.2×1020/Ω m s are achieved for n-type SbNCa3 and BiNCa3 respectively at a temperature of 300 K. Figure of merit is achieved for these materials at room temperature which shows that these materials can be useful for thermoelectric devices and alternative energy sources. 相似文献
60.
Electrochemical parameters of the nanoporous carbide-derived carbon|organic electrolyte have been studied by cyclic voltammetry and electrochemical impedance spectroscopy. The gas adsorption measurements have been used for evaluating the specific surface area, pore size distribution and porosity as the essential parameters influencing the double layer performance of carbon. The region of ideal polarizability, values of series and parallel resistance, capacitance and other important electrical double layer parameters were established. It was shown that specific capacitance of typical nanoporous carbon derived from titanium carbide is in the range of 70-90 F cm−3 or 100-130 F g−1 and it depends on the synthesis conditions. The influence of the electrolyte solvent to the capacitance was insignificant, although acetonitrile was advantageous with respect of smaller viscosity. 相似文献