稀土元素Er掺杂AlN的压电性能

采用第一性原理密度泛函理论法研究了纤锌矿结构AlN中掺杂不同含量Er后的晶体结构和压电性能。计算结果表明,随着掺杂Er原子数比x由0增加到25%,ErxAl1-xN晶体的晶胞参数、晶胞体积和键长显著增大,压电性能得到提升。当x=25%时,ErxAl1-xN体系的压电常数d33为8.67 pC/N,比纯AlN提高了795%,为未来AlN压电薄膜材料研究领域提供了更多可选材料。     

Spectroscopic investigations on Er3+/Yb3+-doped oxyfluoride glass ceramics containing YOF nanocrystals

Spectroscopic properties of Er3+/Yb3+-doped transparent oxyfluoride borosilicate glass ceramics containing YOF nanocrystals were systematically investigated. X-ray diffraction (XRD) confirmed the formation of YOF nanocrystals in the glassy matrix. Based on the Judd-Ofelt theory, the intensity parameters Ωi (i=2, 4, 6), spontaneous emission probability, radiative lifetime, radiative quantum efficiency and the effective emission bandwidth were investigated. The upconversion luminescence intensity of Er3+ ions in the glass ceramics increased significantly with the increasing crystallization temperature. The transition mechanisms of the green and red upconversion luminescence were ascribed to a two-photon process, and the blue upconversion luminescence was a three-photon absorption process.     

Enhancement of 1.54 μm emission in Er：LiNbO_3 crystal by codoping with Zn~（2＋） ions

The enhanced intensity and lengthened lifetime of 1.54 μm emission were observed for Er:LiNbO3 crystal codoped with Zn2+ ions.The ZnO codoping led to the reduction of the green upconversion emission in Er:LiNbO3 crystals.The decay trace of the 4S3/2→4I15/2 was ob-viously nonexponential for Er:LiNbO3 codoped with 0 and 3 mol.% ZnO,but became exponential for one codoped with 6 mol.% ZnO.The OH-absorption spectra showed after codoping with Zn2+ ions,the OH-absorption peaking position shifted from ~3495 to 3484 cm-1,and the absorption cross section decreased.These spectroscopic characteristics suggested that the improvement of 1.54 μm emission was attributed to the reduction of Er3+ cluster sites.     

基于Mach-Zehnder滤波的可调谐光纤激光器

() ()基金项目: 。摘要:为了实现高稳定性的可调谐激光输出,提出并设计了一种基于Mach-Zehnder(M-Z)滤波结构,结合Fabry-Perot(F-P)滤波器的可调谐掺铒光纤激光器,并对激光器的原理及实现方案进行理论分析和实验验证。所设计激光器系统的泵浦源工作波长为976 nm;长度5 m的掺铒光纤作为增益介质;采用全光纤M-Z结构进行滤波,并结合F-P滤波器实现单波长激光可调谐输出。实验中,通过调节F-P滤波器,在泵浦功率为60 mW时,实现了1547～1568 nm范围内单波长激光的稳定可调谐输出,波长调谐间隔小于1.7 nm,每个输出波长的边模抑制比均大于55 dB,线宽均小于0.1 nm。     

退火处理对含铒Al-6Mg-1Mn铝合金组织和性能的影响

研究了不同稳定化退火工艺下,热挤压含铒高镁铝合金板材的力学性能和耐蚀性能,通过优化稳定化退火工艺获得了热挤压含铒高镁铝合金板材稳定化工艺窗口。结果表明,热挤压含铒高镁铝合金板材在260～270 ℃退火,随稳定化退火时间的延长,耐蚀性能达到不敏感区;经人工加速敏化处理后合金的耐蚀性能仍然能够保持在介敏区,腐蚀性能改善;结合敏化后的腐蚀深度观察分析,结果显示在优化的260 ℃×16～24 h退火工艺下,合金具有良好的耐蚀性能和力学性能;通过透射电镜(TEM)对优化工艺合金微观组织进行分析,观察到晶界处无明显断续析出的β相,说明合金具有良好的耐腐蚀性能。     

Effect of in-flight particle behavior on the morphology of flame sprayed Er2O3 splats

The morphology and microstructure of splats impact the comprehensive capability of a new coating methodology called chelate flame spraying (CFS). This study addresses the quantitative characterization of the spread morphologies of flame sprayed Er₂O₃ splats directly deposited under different spray conditions on aluminum alloy substrates with a mirror finish. The influence of the in-flight particle temperature and velocity, carrier gas type, and carrier gas ratio on the solidification mechanism of molten droplets was investigated. Image analysis methods were employed to identify single splats from the morphology observed with field-emission scanning electron microscopy (FE-SEM). In addition, Er₂O₃ films were synthesized on an Al–Mg alloy (A5052) substrate using N₂ or O₂ as the carrier gas. When O₂ was used as the carrier gas, 109-μm-thick films were deposited on the A5052 substrate. The cross-sectional porosity of the films was 3.8%. In contrast, films with 101-μm thickness were synthesized on the A5052 substrate when N₂ was used as the carrier gas. The cross-sectional porosity of these films was 13.8%. The results showed that the carrier gas type (N₂) and carrier gas ratio had a significant effect on the flattening behavior of the molten droplets. A spraying method combined with multidimensional modes is proposed to control the morphology of the splats.     

Er3+掺杂TiO2空心球的制备及其光催化性能研究

以钛酸四丁酯、氧化铒、硝酸等为原料, 采用碳球模板法制备了TiO₂: Er³⁺空心球材料, 利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)等测试方法, 对样品的结构和形貌进行了表征。并利用紫外-可见(UV-Vis)分光光度计考察了TiO₂: Er³⁺空心球材料在催化染料罗丹明B、亚甲基蓝、茜素红、甲基橙的脱色降解过程中的应用性能。系统研究了Er³⁺掺杂浓度、不同离子型染料和染料水溶液的pH等因素对催化降解效率的影响。实验结果表明: 经600℃煅烧3 h制备的TiO₂: Er³⁺为锐钛矿晶型, 空心球结构, 尺寸均匀, 粒径约为120 nm, 比表面积约为60.5 m²/g; Er³⁺掺杂量为0.5mol%的样品对甲基橙染料的催化降解效率最高; 对四种不同离子型染料, 茜素红的催化降解效果显著, 在紫外光照射下, 催化效率较未掺杂Er³⁺的TiO₂提高了约30%。     

Preparation and ASE Spectrum of a Single-Mode Erbium Doped Tellurite Glass Fiber with D-type Cladding Geometry

Based on the host of tellurite glasses, the glass formation, preform manufacture, and fiber fabrication are described. The characterization of amplified spontaneous emission (ASE) from this newly fabricated single-mode Er3+-doped tellurite fibers is also presented. When pumped at 980 nm, a very broad erbium ASE around 1.53 μm was observed. The variations of ASE with fiber length and pumping power are measured and discussed. The output of 2 mW from Er3+-doped tellurite fiber ASE source was obtained under the pump power of 660 mW.     

Emission Properties of Yb3+/Er3+ Doped TeO2-WO3-ZnO Glasses for Broadband Optical Amplifiers

The YbS /Er3 doped TeO2-WO3-ZnO glasses were prepared. The absorption spectra, emission spectra and fluorescence lifetime of Era at 1.5μm, excited by 970 nm were measured. The influence of Er2Oa, Yb2Oa and Ohcontents on emission properties of Era at 1.5 μm was investigated. The optimum doping concentrations for Era and Yba is around 3.34× 1020 ions/cma and 6.63×1020 ions/cma, respectively. The peak emission cross section is 0.83～0.87 pm2. With the increasing concentration of Yba , the FWHM of Era emission at 1.5 μm in the glass increases from 77 nm to 83 nm. The results show that Yba /Era doped meO2-Woa-ZnO glasses are promising candidate for Era -doped broadband optical amplifier.