Solid extraction of caffeine and theophylline from green tea by molecular imprinted polymers

This paper involves a feasibility study on using molecular imprinted polymers as the sorbent materials in solid phase extraction for caffeine and theophylline from green tea. Two kinds of MIPs, with caffeine-theophylline mixture and pentoxifylline-theophylline mixture as the templates respectively, MAA as the monomer, EDMA as the crosslinker and ATBN as the initiator, were applied to this purpose. Mixture solution of caffeine and theophylline (1 Μg/ ml in acetonitrile) was applied to the solid extraction cartridges following a load, wash and elute procedure with acetonitrile, methanol, methanol-acetic acid (90/10, v/v) as the solvents, respectively. This solid phase extraction protocol was applied for extraction of caffeine and theophylline from green tea. Comparison between the results obtained with the MIPs cartridges and a traditional C₁₈ reversed-phase cartridge was made. It showed that the MIP-based sorbent on the solid phase extraction was comparable with that of C₁₈ material. HPLC analysis using a C₁₈ column (5 Μm, 250× 4.6 mm from Rstech corporation), methanol: water (60 :40, v/v) as the mobile phase at a flow rate of 0.6 ml/min was applied for the quantitative determination.     

用超临界CO2流体从香兰草豆荚中萃取香兰素的研究

研究了用超临界CO2 流体技术从香兰豆荚中萃取香兰素的工艺条件 ,探索了萃取压力、温度、时间对萃取率的影响 ,结果表明 ,超临界CO2 萃取香兰素的工艺切实可行 ,最佳萃取条件是萃取压力为 35 0bar、温度为 4 5℃、时间为 14 0min ,在此萃取条件下每克香兰豆荚的香兰素萃取量为 2 0 .0 5mg ,萃取率为 98.5 %。     

Comparison of the generation of oil by the extraction and the hydropyrolysis of biomass

This paper discusses the maximisation of the yields of useful bio-oils generated from seeds and nut-shells both by extraction and by hydropyrolysis. The formation and the composition of the bio-oils are also discussed.Powdered (<0.25 mm diameter) Rapeseed, Linseed and Safflower seed and Hazel nut and Walnut shells, that is, fresh precursors of liptinite, have been characterised by their elemental analyses, infra-red and NMR spectra. Bio-oils obtained both by extraction and by slow hydropyrolysis to 520 °C at moderate pressure in the presence of ammonium dioxydithiomolybdate have been compared by the same analyses and by gas chromatography. Consistent with previous work [Hardy JA. A greener future with biodiesel. Green Chem 2001 G56-G57], extraction of the seeds with organic solvents, including Diesel oil, gave yields of up to 40% together with an uninteresting residue. However, subsequent saponification of the residues gave further yields of oil. Hydropyrolysis removed oxygen from the seeds as water and as oxides of carbon to generate bio-oil in yields of up to 75%. Whereas little oil could be extracted from the nut-shells, hydropyrolysis gave oil yields of ∼40%. Some char was also formed, suggesting that optimisation of the hydropyrolysis might give even larger yields of oil.     

Concentration of tocopherols from soybean sludge by supercritical carbon dioxide

A supercritical fluid extraction method has been applied to test the feasibility of tocopherol concentration from soybean sludge with carbon dioxide at temperatures and pressures ranging from 35 to 70°C and 200 to 400 bar, respectively. The supercritical solubility of the esterified soybean sludge was over 4–6 times greater than that of the original soybean sludge. By a simple batch-type one-stage method the tocopherols in the esterified soybean sludge could be concentrated up to 40 wt%. The overall results of the present study show that soybean sludge initially containing about 13–14 wt% tocopherols may require a countercurrent multistage column to be highly and effectively concentrated.     

基于稀疏表示的多特征融合害虫图像识别

为提高害虫图像识别的准确率,针对不同害虫具有不同的颜色、形状、纹理的特点,提出一种将颜色、形状、纹理特征与稀疏表示相融合的害虫识别方法.该方法利用已标注的训练样本构造不同特征下的训练样本矩阵,通过求解样本的最优稀疏系数以实现害虫图像识别.由于相同样本通过不同特征训练字典求解的稀疏系数不同,进而识别结果也不同.因此,文中进一步通过设计不同特征下的识别分类器实现多特征的融合.在实验室环境与农田环境下的实验结果表明,相较于其他方法,该方法的害虫识别率获得较大的提高.     

基于事件的移动智能终端侦查方法概述

侦查取证过程中,智能终端早已成为关键证据和难点。通过比对功能机和智能机的特点,针对智能终端侦查取证,提出了一套新型的基于事件分析的策略和方法,并通过工具展示基于事件分析的优势。     

网站数据相关内容提取功能的设计与研究

本文根据内容提取的相关知识,以及它们在用户浏览信息时的应用,提出了内容匹配的高效算法,重点研究提取信息时如何提高匹配精度。通过这种算法,系统预测用户可能感兴趣的文章,并按感兴趣的程度向用户提供内容导航,得到一个个性化的相关信息显示页面。     

Barley Protein Isolate: Thermal, Functional, Rheological, and Surface Properties

Barley protein isolate (BPI) was extracted in 0.015 N NaOH in a 10:1 ratio solvent:flour and was precipitated by adjusting the pH to 4.5 and freeze-dried. The thermal properties of BPI were determined using modulated differential scanning calorimetry (MDSC). BPI with 4% moisture content exhibited a glass transition (T _g) with 140 °C onset, 153 °C middle, and 165 °C end temperatures and a ΔC _p of 0.454 J/g per °C. The high moisture content sample (50%) showed a T _g at 89, 91, or 94 °C and 0.067 ΔC _p. Acetylation had no apparent effect on the foaming and emulsifying properties of protein from barley flour but exhibited the least-stable foam among BPI samples. Foaming capacities of both barley protein isolates were ∼12% less than that of acid-precipitated soy protein isolate reported in the literature. Acetylated BPI showed the highest surface hydrophobicity compared to the other samples. The surface-tension test confirmed that unmodified and modified BPI possessed surface activity. BPI phosphorous oxycloride-crosslinked was the most effective in lowering the surface tension of aqueous NaCl, while the crosslinked BPI was the least effective. The G′ value of BPI suspension was greater than G″ at all frequencies from 0.1 to 100 rad/s. The strain value at which linear behavior ceased and nonlinear behavior began ranged from 3 to 10%. Names are necessary to report factually on available data; however, the United States Department of Agriculture (USDA) neither guarantees nor warrants the standard of the product, and the use of the name by the USDA implies no approval of the product to the exclusion of others that may also be suitable.     

数据集市技术浅析

数据集市是当前数据仓库建设的重要环节,本文通过对目前某电信的数据现状进行分析,给出了两种数据集市的建设方案,并分别对两种方案特点进行了描述。解决了电信所遇到的数据问题。