Antenna array techniques for nonuniform cell zooming and adaptive frequency planning

This paper proposes the antenna array system and the techniques for the nonuniform cell zooming and adaptive frequency planning which is suitable for the energy‐efficient LTE network and multitier 5G heterogeneous network. The antenna array system is designed for the beam width control and scan control in the azimuth plane. The beam tilt is controlled in the elevation plane to control the cell radius. The first feature of the antenna array system is to perform nonuniform sector size control in order to deal with the nonuniform traffic distribution. The second feature of the antenna array system is to control the beam scan in the azimuth plane for the adaptive frequency planning. The footprint control of the current work is evaluated considering the antenna array's radiation pattern and all the physical parameters. Adaptive frequency planning can mitigate cochannel interference (CCI), which may be caused due to the cell zooming techniques proposed in this work. The footprint simulations confirm that the antenna array system can control the sector size with the highest possible flexibility. The antenna array system due to these features can effectively mitigate the interference. The results also confirm that the current antenna array system outperforms the existing antenna array systems.     

Reticulate Dual‐Nanowire Aerogel for Multifunctional Applications: a High‐Performance Strain Sensor and a High Areal Capacity Rechargeable Anode

Nanowire aerogels (NWAs) are highly versatile and used in many applications. However, most synthesized NWAs are composed of single components that may produce unsatisfactory aggregated performance in mechanical strength, conductivity, and electrochemistry. To address this issue, a reticulate dual‐nanowire aerogel (rDNWA) composed of FeS₂ nanowires and carbon nanotubes (CNTs) via a simple solvothermal method is synthesized. The rDNWA possesses excellent compressibility (modulus of 1.32 MPa), good conductivity (0.65 S cm^?1), and high porosity (>98%). It can be applied as a high‐performance strain sensor with good sensitivity (Gauge Factor = 1.69) and enhanced stability. It can be densified to yield a high areal capacity of 10.0 mAh cm^?2 and a high mass loading of 14.4 mg cm^?2 after 100 cycles. As a freestanding anode for lithium ion battery (LIB), it exhibits a high specific mass capacity of 1031 mAh g^?1 after 100 cycles at a current density of 100 mA g^?1 and retains it to 729 mAh g^?1 at a current density of 500 mA g^?1 after 400 cycles. The outstanding overall performance of the hybrid aerogel is derived from the synergistic effect of intertwined CNTs and FeS₂ nanowires and can be extended to fabricate NWAs with novel multifunctional capabilities.     

Highly Efficient Photoelectrochemical Water Splitting: Surface Modification of Cobalt‐Phosphate‐Loaded Co3O4/Fe2O3 p–n Heterojunction Nanorod Arrays

Hematite (α‐Fe₂O₃) as a photoanode material for photoelectrochemical (PEC) water splitting suffers from the two problems of poor charge separation and slow water oxidation kinetics. The construction of p–n junction nanostructures by coupling of highly stable Co₃O₄ in aqueous alkaline environment to Fe₂O₃ nanorod arrays with delicate energy band positions may be a challenging strategy for efficient PEC water oxidation. It is demonstrated that the designed p‐Co₃O₄/n‐Fe₂O₃ junction exhibits superior photocurrent density, fast water oxidation kinetics, and remarkable charge injection and bulk separation efficiency (η_inj and η_sep), attributing to the high catalytic behavior of Co₃O₄ for the oxygen evolution reaction as well as the induced interfacial electric field that facilitates separation and transportation of charge carriers. In addition, a cocatalyst of cobalt phosphate (Co‐Pi) is introduced, which brings the PEC performance to a high level. The resultant Co‐Pi/Co₃O₄/Ti:Fe₂O₃ photoanode shows a photocurrent density of 2.7 mA cm^?2 at 1.23 V_RHE (V vs reversible hydrogen electrode), 125% higher than that of the Ti:Fe₂O₃ photoanode. The optimized η_inj and η_sep of 91.6 and 23.0% at 1.23 V_RHE are achieved on Co‐Pi/Co₃O₄/Ti:Fe₂O₃, respectively, corresponding to the 70 and 43% improvements compared with those of Ti:Fe₂O₃. Furthermore, Co‐Pi/Co₃O₄/Ti:Fe₂O₃ shows a low onset potential of 0.64 V_RHE and long‐time PEC stability.     

Ultrasonication‐Induced Self‐Assembled Fixed Nanogap Arrays of Monomeric Plasmonic Nanoparticles inside Nanopores

Monomeric gold (Au) and silver (Ag) nanoparticle (NP) arrays are self‐assembled uniformly into anodized aluminium oxide (AAO) nanopores with a high homogeneity of greater than 95%, using ultrasonication. The monomeric metal NP array exhibits asymmetric plasmonic absorption due to Fano‐like resonance as interpreted by finite‐difference time‐domain (FDTD) simulation for the numbers up to 127 AuNPs. To examine gap distance‐dependent collective‐plasmonic resonance, the different dimensions of S, M, and L arrays of the AuNP diameters/the gap distances of ≈36 nm/≈66 nm, ≈45 nm/≈56 nm, and ≈77 nm/≈12 nm, respectively, are prepared. Metal NP arrays with an invariable nanogap of ≈50 nm can provide consistent surface‐enhanced Raman scattering (SERS) intensities for Rhodamine 6G (Rh6G) with a relative standard deviation (RSD) of 3.8–5.4%. Monomeric arrays can provide an effective platform for 2D hot‐electron excitation, as evidenced by the SERS peak‐changes of 4‐nitrobenzenethiol (4‐NBT) adsorbed on AgNP arrays with a power density of ≈0.25 mW µm^‐2 at 514 and 633 nm. For practical purposes, the bacteria captured by 4‐mercaptophenylboronic acid are found to be easily destroyed under visible laser excitation at 514 nm with a power density of ≈14 mW µm^‐2 for 60 min using Ag due to efficient plasmonic‐electron transfer.     

Solution‐Processable,High‐Performance Flexible Electroluminescent Devices Based on High‐k Nanodielectrics

Flexible alternating‐current electroluminescent (ACEL) devices have attracted considerable attention for their ability to produce uniform light emission under bent conditions and have enormous potential for applications in back lighting panels, decorative lighting in automobiles, and panel displays. Nevertheless, flexible ACEL devices generally require a high operating bias, which precludes their implementation in low power devices. Herein, solution‐processed La‐doped barium titanate (BTO:La) nanocuboids (≈150 nm) are presented as high dielectric constant (high‐k) nanodielectrics, which can enhance the dielectric constant of an ACEL device from 2.6 to 21 (at 1 kHz), enabling the fabrication of high‐performance flexible ACEL devices with a lower operating voltage as well as higher brightness (≈57.54 cd m^?2 at 240 V, 1 kHz) than devices using undoped BTO nanodielectrics (≈14.3 cd m^?2 at 240 V, 1 kHz). Furthermore, a uniform brightness across the whole panel surface of the flexible ACEL devices and excellent device reliability are achieved via the use of uniform networks of crossaligned silver nanowires as highly conductive and flexible electrodes. The results offer experimental validation of high‐brightness flexible ACELs using solution‐processed BTO:La nanodielectrics, which constitutes an important milestone toward the implementation of high‐k nanodielectrics in flexible displays.     

Broadband photonic structures for quantum light sources

Quantum light sources serve as one of the key elements in quantum photonic technologies. Such sources made from semiconductor material, e.g., quantum dots (QDs), are particularly appealing because of their great potential of scalability enabled by the modern planar nanofabrication technologies. So far, non-classic light sources based on semiconductor QDs are currently outperforming their counterparts using nonlinear optical process, for instance, parametric down conversion and four-wave mixing. To fully exploring the potential of semiconductor QDs, it is highly desirable to integrate QDs with a variety of photonic nanostructures for better device performance due to the improved light-matter interaction. Among different designs, the photonic nanostructures exhibiting broad operation spectral range is particularly interesting to overcome the QD spectral inhomogeneity and exciton fine structure splitting for the generations of single-photon and entangled photon pair respectively. In this review, we focus on recent progress on high-performance semiconductor quantum light sources that is achieved by integrating single QDs with a variety of broadband photonic nanostructures i.e. waveguide, lens and low-Q cavity.     

Mechanically Programmable Dip Molding of High Aspect Ratio Soft Actuator Arrays

This work presents multiple methods of creating high aspect ratio fluidic soft actuators that can be formed individually or in large arrays via dip coating. Within this methodology, four strategies are provided to mechanically program the motion of these actuators, including the use of fiber inclusions, gravity, surface tension, and electric fields. The modular nature of this dip coating fabrication technique is inexpensive, easy to modify, and scalable. These techniques are used to demonstrate the fabrication of soft actuators with aspect ratios up to 200:1 and integrated arrays of up to 256 actuators. Furthermore, these methods have the potential to achieve higher aspect ratios and larger array sizes. Operating pressure, curvature, and curling strength tests reveal the design space in which fabrication parameters can be selected to tune the input and output parameters of soft bending actuators. An individual bending actuator made with these methods weighs between 0.15 and 0.5 g, can hold up to 2 N, and can be designed to work in groups to increase curling strength with distributed contact forces. Arrays of these actuators may be useful in atypical grasping and manipulation tasks, fluid manipulation, and locomotion.     

Electrospinning Multilayered Scaffolds Loaded with Melatonin and Fe3O4 Magnetic Nanoparticles for Peripheral Nerve Regeneration

Peripheral nerve injury is a common clinical problem bringing heavy burden to patients, due to its high incidence and unsatisfactory treatment. Nerve guidance conduit (NGC) is a promising scaffold for peripheral nerve repair, and bioactive agents are applied for great functional recovery. Melatonin (MLT) and Fe₃O₄ magnetic nanoparticles (Fe₃O₄‐MNPs) are proven to inhibit oxidative stress, inflammation, and induce nerve regeneration. Herein, a multilayered composite NGC loaded with MLT and Fe₃O₄‐MNPs is designed for sequential and sustainable drug release, creating an appropriate microenvironment for nerve regeneration. The composite scaffold shows sufficient mechanical strength and biocompatibility in vitro, and evidently promotes morphological, functional, and electrophysiological recovery of regenerated sciatic nerves in vivo. This work proves that the multilayered conduits show great prospect in the long‐term nerve defects treatment due to easy manufacture and desired efficacy.