长脉冲激光沉积原位生成YBaCuO超导膜

用长脉冲激光(脉冲宽度150μs,波长1.06μm)辐照高温烧结的YBa_2Cu_3O_(7-x)靶,在6Pa的氧气压强下,巳在(100)YSZ单晶衬底上原位生成YBa_2Cu_(?)O_(7-x)超导膜。衬底置于750℃的加热器上,衬底与靶之间的距离5cm,用该法制得的薄膜光亮坚实,正常态呈金属性,零电阻温度为84.7K。用XRD和SEM对薄膜进行了分析研究。     

氧气放电辅助激光淀积原位制备高T_c超导薄膜

采用低压氧气放电辅助的激光淀积方法,原位外延生长出零电阻温度91K,临界电流密度10~5A/cm~2的Y-Ba-Cu-O高温超导薄膜。扫描电镜和X光衍射分析结果表明,薄膜中超导相晶粒的生长具有c轴垂直于表面的择优取向。     

微波遥感典型地物介电常数实地测量

在微波遥感定量化研究中,要求对遥感目标的介电特性有较准确的了解.为此采用自由空间法在野外实地测量典型目标的介电常数.给出了基本原理,定标方法及在X波段对黑土,草地,和冰所测的介电常数。分析比较了测量结果。     

Emancipating Target‐Functionalized Carbon Dots from Autophagy Vesicles for a Novel Visualized Tumor Therapy

Killing the tumor cells by a visualized targeting system is a promising strategy with which to achieve high efficiency, low side effects, and a high survival rate for tumor therapy. Here, an autophagy regulation strategy is reported by emancipating target‐functionalized carbon dots from autophagy vesicles for the efficient visualized tumor therapy. The folic acid modified N‐doped carbon dots (FN‐CDs) are selectively endocytosed (specific cellular uptake rate >93.40%) and stably existed in autophagic vacuoles in tumor cells. Next, the autophagic vacuoles are “opened” by the autophagy inhibitors. Released FN‐CDs activate both the intrinsic and extrinsic apoptotic signaling pathway and kill tumor cells efficiently. This method achieves therapeutic effects with high performance in 26 types of tumor cell lines. Animal experiments show that the 30 d survival rate of this therapeutic strategy is much higher than that with traditional drug treatment. Real‐time imaging/monitoring and its effects on the intelligent tumor therapy are also demonstrated based on the stable, strong, green emission from FN‐CDs.     

散热密集孔爆板分层改善探讨

随着电子产品应用技术的不断更新以及功能的完善,板件的散热性能要求越来越高,因此大量的散热密集孔设计应用于印制线路板,由此带来散热密集孔分层的问题。本文通过对密集散热孔裂纹区域的分析、研究,对VIP散热密集孔设计、钻孔参数、烘烤参数进行了试验验证,并提出了散热密集VIP孔爆板分层改善的方向。     

基于FIB-SEM双束系统的纳尺度真空间隙电学特性原位实验装置

纳米尺度真空电气击穿与绝缘特性研究是高电压与绝缘技术领域的前沿课题.一方面,随着微纳尺度加工技术的不断发展,电气部件和电子器件的特征物理尺寸已经逐步降低到微米、纳米甚至是分子原子尺度,并且在军事和民用领域得到越来越广泛的应用;另一方面,传统的放电击穿理论和绝缘性能评价方法无法用来解释和预估微纳尺度的放电特性和绝缘水平.因此,本文基于聚焦离子束和扫描电子显微镜(FIB-SEM)双束系统,借助纳米压电位移技术和微弱电流测量技术,建立了纳尺度真空间隙电学特性的原位研究系统.该系统不仅能够进行微纳尺度(曲率半径为15 nm~10μm)金属电极的原位加工,材料组成成分的定量分析,而且可以实现纳尺度真空间隙(>20 nm)的放电特性研究,为纳尺度击穿规律和绝缘特性的实验研究提供了有力的支撑.     

TiC/n型4H-SiC欧姆接触的低温退火研究

利用电子回旋共振(ECR)氢等离子体处理n型4H-SiC(0.5～1.5×1019cm-3)表面,采用溅射法制备碳化钛(TiC)电极,并在低温(<800℃)条件下退火。直线传输线模型(TLM)测试结果表明,TiC电极无需退火即可与SiC形成欧姆接触,采用ECR氢等离子体处理能明显降低比接触电阻,并在600℃退火时获得了最小的比接触电阻2.45×10-6Ω.cm2;当退火温度超过600℃时,欧姆接触性能开始退化,但是比接触电阻仍然低于未经氢等离子体处理的样品,说明ECR氢等离子体处理对防止高温欧姆接触性能劣化仍有明显的效果。利用X射线衍射(XRD)分析了不同退火温度下TiC/SiC界面的物相组成,揭示了电学特性与微观结构的关系。     

线性分布的In组分对紫色InGaN/GaN单量子阱发光特性的影响

采用数值模拟的方法研究了具有相同的平均In组分,但In组分的分布不同的3个紫色InGaN/GaN单量子阱样品的光谱特性.通过分析样品的电致发光谱、能带结构、波函数交叠以及载流子浓度分布等,发现沿生长方向阱内In组分线性增加的单量子阱样品的发光效率最高,而In组分线性减小的样品发光效率最低.这是因为In组分的线性增加能够减弱极化场对价带的影响,使阱内价带变得更加平缓.这不仅降低了空穴的注入势垒高度、增大了阱中的空穴浓度,还增强了阱内电子-空穴波函数的交叠积分,提高了辐射复合几率,从而使In组分线性增加的量子阱的发光效率显著提高.     

Maskless Preparation of Spatially-Resolved Plasmonic Nanoparticles on Polydimethylsiloxane via In Situ Fluoride-Assisted Synthesis

Here, a fluoride-assisted route for the controlled in-situ synthesis of metal nanoparticles (NPs) (i.e., AgNPs, AuNPs) on polydimethylsiloxane (PDMS) is reported. The size and coverage of the NPs on the PDMS surface are modulated with time and over space during the synthetic process, leveraging the improved yield (10×) and faster kinetics (100×) of NP formation in the presence of F⁻ ions, compared to fluoride-free approaches. This enables the maskless preparation of both linear and step gradients and patterns of NPs in 1D and 2D on the PDMS surface. As an application in flexible plasmonics/photonics, continuous and step-wise spatial modulations of the plasmonic features of PDMS slabs with 1D and 2D AgNP gradients on the surface are demonstrated. An excellent spatially resolved tuning of key optical parameters, namely, optical density from zero to 5 and extinction ratio up to 100 dB, is achieved with AgNP gradients prepared in AgF solution for 12 minutes; the performance are comparable to those of commercial dielectric/interference filters. When used as a rejection filter in optical fluorescence microscopy, the AgNP-PDMS slabs are able to reject the excitation laser at 405 nm and retain the green fluorescence of microbeads (100 µm) used as test cases.     

Intermetallic compounds formed at the interface between liquid indium and copper substrates

The interfacial reactions between liquid In and Cu substrates at temperatures ranging from 175°C to 400°C are investigated for the applications in bonding recycled sputtering targets to their backing plates. Experimental results show that a scallop-shaped Cu₁₆In₉ intermetallic compound is found at the Cu/In interface after solder reactions at temperatures above 300°C. A double-layer structure of intermetallic compounds containing scallop-shaped Cu₁₁In₉ and continuous CuIn is observed after the Cu/In interfacial reaction at temperatures below 300°C. The growth of all these intermetallic compounds follows the parabolic law, which implies that the growth is diffusion-controlled. The activation energies for the growth of Cu₁₆In₉, Cu₁₁In₉, and CuIn intermetallic compounds calculated from the Arrhenius plot of growth reaction constants are 59.5, 16.9, and 23.5 kJ/mole, respectively.