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排序方式: 共有480条查询结果,搜索用时 15 毫秒
51.
百色油田油井结蜡及清防蜡处理 总被引:2,自引:0,他引:2
本文了滇黔桂百色油田的严重结蜡情况,清防蜡剂的筛选,使用筛选出的防蜡剂JS2进行油清防蜡处理的工艺方法和效果。自1990年10月起,在百色油田各区块62口油井采用不停产加入油套环空,加入后关井或在油套管间循环2-4小时,挤入油层等方法进行的清防蜡作业,除井温过低的一个井外,全部获得成功。 相似文献
52.
Lanthanum nitrate has been investigated as corrosion inhibitor of X70 pipeline steel in 3.0 (wt.%) NaCl solution using electrochemical techniques such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in conjunction with scanning electron microscopy (SEM) and energy dispersive X‐ray detector (EDX) techniques. The results showed that La(NO3)3 belonged to the film‐formed mixed inhibitors, which can form a compact network over the whole surface of X70 pipeline steel. The inhibition effect of La(NO3)3 on X70 steel reinforced with the increase of the concentration itself. The EDX analysis showed that lanthanum ions were found to participate in the network film formed on the sample surface. 相似文献
53.
The electrochemical behavior of low carbon steel (API 5L grade B) in 1 mol/L HCI solution with different concentrations of N,Nr-bis(4-formylphenol)-trimethylenediamine Schiff base was studied by electrochemical techniques and density functional theory analysis. The inhibition efficiency was found to increase with increasing inhibitor concentration and decreased with increasing temperature. The high inhibition efficiency was attributed to the blocking of active sites by adsorption of inhibitor molecules on the steel surface. Thermodynamic parameters for the adsorption and activation processes were determined. Galvanostatic polarization data indicated that Schiff base act as a mixed-type inhibitor and the adsorption isotherm obeyed the Langmuir adsorption isotherm. Results obtained from quantum chemical studies show excellent correlations between the quantum chemical parameters and the experimental inhibition efficiencies using density functional theory at the B3LYP/6-31G(d,p) and B3LYP/3-21G basis set levels and ab initio calculations using HF/6-31G(d,p) and HF/3-21G methods. 相似文献
54.
Partial nitrification was successfully achieved with addition of 5mM KClO(3) in the aerobic granules system. Batch tests demonstrated that KClO(3) selectively inhibited nitrite-oxidizing bacteria (NOB) but not ammonia-oxidizing bacteria (AOB). During stable partial nitrification, the influent pH was kept at 7.8-8.2, while the DO and temperature were not controlled in the SBR. When the NH(4)-N and COD levels were kept at 100mg/l and 400mg/l in the influent, the NH(4)-N and COD removal efficiencies reached 98.93% and 78.65%, respectively. The NO(2)-N accounted for 92.95% of the NO(χ)-N (NO(2)-N+NO(3)-N) in the effluent. Furthermore, about 90% of the chlorate was reduced to nontoxic chloride, thus it would not cause environmental problem. SEM showed that the main composition of the aerobic granules was bacilli and coccus bacteria. FISH analysis revealed that AOB became the dominant nitrifying bacteria, whereas NOB were detected only in low abundance. Chlorate could be used to control the development and maintenance of aerobic granules sludge for partial nitrification. 相似文献
55.
56.
本文通过元素分析,IR谱及MS谱等方法研究了TBP—正十二烷体系中酸性强络合辐解产物的性质和结构。用同位素示踪方法对长链酸性磷酸酯的生成机理进行了探讨并找到了能抑制长链酸性磷酸酯的有效的抑制剂。 相似文献
58.
Huei Tarng Liou 《臭氧:科学与工程》2009,31(1):53-59
We report on an on-site 500 RT cooling tower ozone treatment process, in which chemicals other than ozone itself were completely eliminated. Ozone in an amount leading to less than 0.1 ppm of dissolved ozone was continuously introduced via side-stream injection into the circulating water returning from the chiller. The ozonated water was initially made to flow from the distributor to the filler in order to eliminate the growth of algae, and then to the chiller to reduce the corrosion and the fouling in the water. Positive ions such as Ca+2 and Mg+2 in the circulating water were precipitated by chelating them with carboxylic acids formed by the oxidation of organic compounds. We observed that using an ozone dosage of 0.1 ppm resulted in a colony-forming unit (CFU) less than 2 × 103 /mL. With that well-controlled CFU, corrosion controlling and scale reducing were achieved as well. 相似文献
59.
Zn(H2PO4)2-N[CH2CH2OPO(OH)2]3对碳钢的协同效应与缓蚀机理研究 总被引:2,自引:0,他引:2
采用失重法、表面观察法、极化曲线法、氩离子刻蚀法和XPS分析法研究Zn(H2PO4)2-N「CH2CH2OPO(OH)2」3在海水中对碳钢的协同效应与缓蚀机理。结果发现:50%Zn(H2PO4)2+50^N「(CH2CH2OPO(OH)2」3(XM-303在海水中对碳钢具有明显的协同缓蚀效应。50%Zn(H2PO4)2+50%N「CH2CH2OPO(OH)2」3(XM-303)主要为阴极抑制型缓蚀 相似文献
60.
利用γ射线共照射技术在聚醚砜(Polyethersulfone,PES)粉体上按枝了丙烯酸。研究了丙烯酸单体体积分数、接枝溶液pH值、吸收剂量、阻聚剂(Cu^2+)浓度等对接枝率的影响规律。通过与称重法相结合,得到了利用红外光谱对接枝率进行定量分析的工作曲线。研究结果表明,当吸收剂量为25kGy、单体体积分数为30%、阻聚剂用量为0.004mol/L时,可以获得最高的接枝率。接枝溶液中盐酸的添加有利于提高接枝率。提高接枝率有助于改善PES的亲水性。 相似文献