聚合物在离子选择电极上的应用

本文概述了聚合物膜离子选择电极的发展,制备、应用等方面的研究情况;将聚合物膜离子选择电极分为固态膜类和液态膜类,分别对其优缺点和发展前景加以分析;并讨论了聚合物在敏感膜中的作用,以及聚合物结构对敏感膜性能的可能影响。     

Particularities of condensation of atoms with increased kinetic energy

Novel universal method for measurement of the condensation coefficient α is developed. Using this method, noticeable difference between measured (α≈0.8) and expected (α≈1) values of the condensation coefficient for sputtered Cr atoms was revealed for the first time. The effect is assumed to be a result of considerable elevation of the surface temperature during atomic condensation induced by the energy delivered to the condensation surface by sputtered atoms and from the plasma.     

Fabrication of Er3+/Pr3+ Co-doped soda-lime glass thin films using RF magnetron sputtering method and optical property characterization

Er^3+/Pr³⁺ co-doped soda-lime glass thin films have been fabricated using RF magnetron sputtering method and their structural and optical properties have been studied. Deposition rate, crystallinity, and composition of glass thin films were investigated by scanning electron microscopy, transmission electron microscopy, and electron probe micro area analysis. Refractive index, birefringence and binding characteristics have been investigated using a prism coupler and X-ray photoelectron spectroscopy. Er³⁺/Pr³⁺ co-doped soda lime glass thin films were prepared by changing substrate temperature (room temp. ∼550^∘C), RF power (90 W–130 W), and Ar/O₂ gas flow ratio at processing pressure of 4 mTorr. Glass thin films could be obtained at the optimized processing condition at 350^∘C, RF power of 130 W, and gas flow of Ar:O₂ = 40:0 with maximum deposition rate of 1.6 μm/h. Refractive index and birefringence increased from 1.5614 to 1.5838 and from 0.000154 to 0.000552, respectively, as the content of Pr³⁺ increased. Binding energy of Pr3d also increased as the content of Pr³⁺ increased.     

Electron beam evaporated carbon nanotube dispersed SnO2 thin film gas sensor

Carbon nanotube (CNT) is a useful material for gas-sensing applications because of its high surface to volume ratio structure. In this work, multi-wall CNTs are incorporated into tin oxide thin film by means of powder mixing and electron beam evaporation and the enhancement of gas-sensing properties is presented. The CNTs were combined with SnO₂powder with varying concentration in the range of 0.25–5% by weight and electron beam evaporated onto glass substrates. From AFM and TEM characterization, CNT inclusion in SnO₂thin film results in the production of circular cone protrusions of CNT clusters or single tube coated with SnO₂layer. Experimental results indicate that the sensitivity to ethanol of SnO₂thin film increases by the factors of 3 to 7, and the response time and recovery time were reduced by the factors of 2 or more with CNT inclusion. However, if the CNT concentration is too high, the sensitivity is decreased. Moreover, the CNT doped film can operate with good sensitivity and stability at a relatively low temperature of 250–300^∘C. The improved gas-sensing properties should be attributed to the increasing of surface adsorption area of metal oxide produced by CNT protrusion.     

Characterization of Hydroxyapatite Film on Titanium Substrate by Sputtering Technique

Radiofrequeut magnetron sputtering technique was used to produce calcium phosphate coated on the titurdum substrates, and the sputtered coating films were crystallized in an autoclave at 110℃ using a low temperature hydrothermal technique. The crystallization of as-sputtered coating film on the titanium substrates were amorphous calcium phosphate film. However, after the hydrothermal technique, calcium phosphate crystals grew and these were cohumnar crystal. The Ca/P ratio of sputtered coating films in 1.6 to 2.0.     

表征PAN纤维和炭纤维微细结构的HRTEM样品制备方法

为用高分辨透射电子显微术(HRTEM)表征聚丙烯腈(PAN)纤维和炭纤维的微细结构，从纤维性能出发，探讨研碎、离子束减薄和超薄生物切片三种制备方法及其工艺步骤，结合实验结果，对比了三种制备方法的原理、优缺点，提出了制备方法的适用范围和选择原则，并推断适于表征预氧化纤维微细结构的样品制备方法。与生物样品的制备方法类似，把超薄生物切片法引入到纤维材料HRTEM样品制备领域，为系统研究炭纤维微细结构的演变提供了线索。     

离子束辅助沉积铌提高铀的抗腐蚀性能研究

利用离子注入技术在铀表面进行了离子束辅助沉积铌和离子注入铌形成表面改性层，并对改性层的厚度、注入元素的分布进行俄歇电子能谱（AES）分析和表面相及结构的X射线衍射谱（XRD）分析，用电化学极化法测试抗腐蚀性能。结果表明：离子束辅助沉积表面改性层比离子注入表面改性层明显增厚，铀的耐蚀性得到进一步改善。最后讨论了注铌改性层耐蚀性提高的原因。     

退火对直流磁控溅射铬膜附着性的影响

为了利用铬膜改善锆的抗腐蚀性，研究了退火对Zr-2基体上制备的直流磁控溅射铬膜附着性的影响，使用扫描电镜（SEM）观察了界面形貌及锆，铬的界面的分布，用X－射线衍射仪（XRD）分析了膜层的组成，用划痕法测定了铬膜的附着，结果表明，锆／铬界面结合良好，边界可见；与现有文献比较，获得的铬膜附着性好――均超过20N；溅射后退火使Zr-Cr界面更像扩散界面，但X－射线衍射结果未发现有界面反应产物；退火提高铬膜与Zr-2基体的附着性约50％，扩散际着附着性增加的主要因素。     

UV-vis and photoluminescent spectra of TiO<Subscript>2</Subscript> films

TiO₂ fims have been deposited on glass substrates using DC reactive magnetron sputtering at different oxygen partial pressures from 0. 10 Pa.to 0.65 Pa. The transmittance (UV-vis) and photoluminescence (PL) spectra of the films were recorded. The results of the UV-vis spectra show that the deposition rate of the films decreased at oxygen partial pressure P(O₂)≥0.15 Pa, the band gap increased from 3.48 eV to 3.68eV for direct transition and from 3.27 eV to 3.34 eV for indirect transition with increasing the oxygen partial pressure. The PL spectra show convincingly that the transition for films was indirect, and there were some oxygen defect energy levels at the band gap of the films. With increasing the O₂ partial pressure, the defect energy levels decreased. For the films sputtered at 0.35 and 0.65 Pa there were two defect energy levels at 2.63 eV and 2.41 eV, corresponding to 0.72 eV and 0.94 eV below the conduction band for a band gap of 3.35 eV, respectively. For the films sputtered at 0.10 Pa and 0.15 Pa, there was an energy band formed between 3.12 eV and 2.06 eV, corresponding to 0.23 eV and 1.29 eV below the conduction band. ZHAO Qing-nan : Born in 1963 Funded by Natural Science Foundation of Hubei Province, China.