气体进入挤出聚合物熔体时的喷嘴结构

分析了气体经各种喷嘴进入聚合物熔体时的气熔界面形态,得到了微孔塑料连续挤出成型中喷嘴的合理结构和安装位置.     

Melt spinning flow behaviour of high-density polyethylene blended with low-density polyethylene

ABSTRACT

The melt spinning flow behaviour of a high-density polyethylene (HDPE) blended with a low-density polyethylene (LDPE) was studied using a melt spinning technique in temperature ranging from 160 to 200°C and die extrusion velocity varying from 9 to 36?mm?s^?1. The results showed that the melt apparent extension viscosity of the blends was higher than those of the LDPE and HDPE; the melt apparent extension viscosity decreased with increasing temperature; while the melt apparent extension viscosity increased with increasing extension strain rate when the extension strain rate was lower than 0.2?s^?1, and then decreased; the melt apparent extension viscosity reached up to a maximum value when extension strain rate was about 0.2?s^?1; the relationship between the melt apparent extension viscosity and the LDPE weight fraction did not follow the mixing rule.     

Planar Entry Converging Flow During Extrusion of Polymer Melts

In this article, a planar entry converging flow during die extrusion of polymeric melts was analyzed and a differential equation of entry converging boundary streamline equation with rheological parameters and channel geometry is established. By applying limit theory, the entry converging boundary streamline equation in the case with different non-Newtonian index (n) was discussed, and the corresponding expressions of entry natural convergent half angle and convergent region length were derived. The entrant flow pattern might be described with the half angle of entry natural convergence (α₀) and the convergent region length (L _e ) of the melts, and α₀ and L _e were mainly a function of the entry elastic storage deformation energy (e) and n. The values of α₀ and L _e were calculated by means of these simplified expressions. It was found that the estimations of α₀ decrease nonlinearly white L _e increases linearly with an addition of e. Finally, a preliminary verification of the natural converging half angle equation was made. The results showed that the estimations of 2α₀ based on the experiments of a low-density-polyethylene (LDPE) and a high-density-polyethylene (HDPE) were close to the data reported in reference.     

玻璃净化剂组分对Cu50Ni50合金熔体过冷度稳定性的影响

在高真空下,研究了净化剂Ｂ２Ｏ３,８９％ＳｉＯ２＋１２．５％Ｂ２Ｏ３＋２．２％Ａｌ２Ｏ３＋０．６％ＣａＯ＋５．７％Ｎａ２Ｏ（简写为Ｎａ－Ｃａ－Ａｌ－Ｂ－Ｓｉ）和５０％Ｎａ－Ｃａ－Ａｌ－Ｂ－Ｓｉ＋５０％ｎａ２Ｂ８Ｏ４对Ｃｕ５０Ｎｉ５０ｘ合金溶体在循环过热过程中的过冷度及其稳定Ｃａ－Ａｌ－Ｂ－Ｓｉ玻璃的净化过程为物理－化学复合净化,但由于该净化剂粘度大,在循环过热的冷却过程中因发生合金溶体与净化剂分离     

Identification of structural entities in NdF3-LiF melts with cryoscopic method

Nd-F species in NdF3-LiF melts were studied using cryoscopic method.Liquidus temperatures of melts of various compositions were determined by differential thermal analysis(DTA).Based on the different model calculations,NdF4- was identified as the most likely Nd-F entity in the melts in which the mole fraction of NdF3 was lower than 20%,considering only one single Nd species in the melt,and which was formed in accordance with Temkin model or Flood model.Then,activities of different components in the melts were researched.The results show that activity of LiF decreases,and that of NdF3 increases with increasing the mole fraction of NdF3.The value of activity coefficient of NdF3 is higher than 1,and that of LiF is lower than 1.     

Application of annexation principle of thermodynamic property of In-Pb-Sb and In-Bi-Pb melts

Based on the principle of annexation and phase diagrams, the structural units of In-Pb-Sb and In-Bi-Pb melts were determined, and their calculating models of mass action concentrations were formulated. Calculated results agree well with practical values, which in turn show that the models deduced can reflect the structural realities of corresponding melts and the principle of annexation is applicable not only to some binary metallic melts, but also to ternary metallic melts.     

Molecular dynamics of structural properties of molten CaO-SiO2 with varying composition

1　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｓｔｕｄｙｏｆｍｏｌｔｅｎｓｔｒｕｃｔｕｒｅｏｆＣａＯ ＳｉＯ2 ,ｗｈｉｃｈａｃｔａｓｔｈｅｂａｓｉｃｆａｃｔｏｒｉｎｆｌｕｅｎｃｉｎｇｔｈｅｐｈｙｓｉｃａｌａｎｄｃｈｅｍｉｃａｌｐｒｏｐｅｒｔｉｅｓｏｆｔｈｅｓｉｌｉｃａｔ     

铟在氯化物熔盐中的氧化还原行为

采用循环伏安、计时电位等电化学分析测试手段对450℃下LiCl?KCl共融盐中In(Ⅲ)在惰性钼电极上的电化学行为进行系统研究.结果表明:In(Ⅲ)在熔盐中的还原是一个两步过程,电极反应In(Ⅲ)/In(I)和In(I)/In分别发生在?0.4 V和?0.8 V(vs Ag/AgCl).结合还原过程电子转移数的理论计算...     

The effect of inclusions of aluminum oxide on the processes of hydrogen dissolution and evolution in aluminum and copper melts

From the analysis of publications, it is concluded that the assumption about the effect of nitrogen bubbles on the film inclusions of aluminum oxide formed during the contact of aluminum melts with air as the ready centers of hydrogen evolution in the form of bubbles from the solution-melt previously put forward by the authors is valid. Based on this notion, the results of many production and laboratory investigations on the relation between the contamination of aluminum melts by oxide inclusions and porosity of cast billets caused by the evolution of hydrogen bubbles is logically explained. This notion is valid for brasses and bronzes, which include aluminum as an alloying component or in the form of impurity. The direct experiments for water containing dissolved air or carbon dioxide vividly demonstrated the effect of the mentioned mechanism. The uselessness of the term “bifilm” to describe double oxide films and the inadmissibility of its use in metallurgical publications in Russian are noted.     

Thermoplastic extrusion—the mechanism of the formation of extrudate structure and properties

Systems processed by thermoplastic extrusion can be regarded as heterophase polymer melts of incompatible water-plasticized biopolymers. In the process of thermoplastic extrusion, proteins and polysaccharides are melted at high pressure and temperature below the temperature region of their thermal decomposition. Dispersed particles of these systems can be deformed in flow. The mixed-melt anisotropic structure, formed in flow, is fixed by rapid conversion of the melt jet that lets the extruder die from a viscous state to a rubber-like state and then to a glassy state caused by cooling and drying. Incompatibility of proteins and polysaccharides in their water-plasticized melt mixtures impacts on structure formation and texturization during thermoplastic extrusion. Presented at the 20th ISF World Congress and 83rd AOCS Annual Meeting and Expo, May 10–14, 1992, Toronto, Ontario, Canada.