Fabrication and Characterization of Electrodeposited Ni-SiC-h/BN Composite Coatings

Ni—SiC—h/BN composite materials were prepared by electrodeposition technique with the dispersion of SiC（10 g/L） and h/BN nanosheets（10 g/L） in a nickel sulfamate electrolytic bath.Different ratio of sodium dodecyl sulfate（SDS） and cetyltrymethyl ammonium bromide（CTAB） surfactants were used to evaluate the effect of surfactants on the properties of the electrodeposited composite coatings.The coating samples were characterized by scanning electron microscopy,X-ray diffraction,Vickers microhardness test,scratch and tribology tests.The results revealed that the co-deposition of nanoparticles was significantly influenced by surfactants during electrodeposition process.Pyramidal or polyhedral nickel crystallites were observed at higher ratio of SDS/CTAB while smaller oval grains with refined surface morphologies were obtained at lower ratio of SDS/CTAB surfactants.In addition,wt%of particles co-deposition was increased,and Vickers microhardness,wear and coefficient of friction of the electrodeposited composite coatings were improved at increased CTAB and decreased SDS contents in the electrolyte during electrodeposition process.     

Rapidly Solidified Microstructure in Laser Alloyed Ni-Al Layer by TEM,STEM z-contrast and HRTEM Techniques

In the present study, laser alloying of electroless Nie P coating on aluminum substrate was conducted using Nd：YAG pulsed laser under the condition of 5.36 109W/m2 in power density and 3.0 mm/s in scanning speed. The rapidly solidified microstructure in the alloyed layer was studied. The results showed that the alloying element distributed in the alloyed layer is inhomogeneous. The dendrite containing relatively high Ni was identified as Al3Ni phase and the areas between the dendrites are rich in Al content. Featureless with cell structure in Al-rich areas was firstly displayed by z-contrast image. Amorphous structure was revealed to exist in Al-rich areas.     

Evolution of the Microstructure and Strength in the Nugget Zone of Friction Stir Welded SiCp/Al-Cu-Mg Composite简

A 6 mm-thick SiCp/2009AI composite plate was successfully joined by friction stir welding （FSW） using an ultrahard material tool to investigate the evolution of the microstructure and the strength in the nugget zone （NZ）. While some SiC particles were broken up during FSW, most of them rotated in the matrix. Large compound particles on the interfaces were broken off during FSW, whereas the amorphous layer and small compound particles remained on the interfaces. The dynamically recrystallized AI grains nucleated on the surface of fractured SiC particles during FSW, forming nano-sized grains around the SiC particles. The yield strength of the NZ decreased slightly due to the variation in the size, shape, and distribution of the SiC particles. The clean interfaces were beneficial to the load transfer between SiC particles and AI matrix and then increased the ultimate tensile strength of the NZ.     

Microstructural evolution and mechanical properties of high strength 3–9% Ni-steel alloys weld metals produced by electron beam welding

The microstructures and mechanical properties of weld metals of high strength steels having 3–9% Ni content have been investigated with getting a better insight into the role of retained austenite. The weld metals were produced autogenously by electron beam welding (EBW) process. The results showed that once Ni content exceeded 4% prior austenitic grains of the weld metals were rapidly coarsened and solidified into a cellular dendritic structure. The content of retained austenite increased with Ni addition and was preferentially distributed along the lath boundary, edges of coalesced bainite, cellular dendritic boundaries and at prior austenite grain boundaries. Retained austenite morphology was also changed on increasing nickel content from a discontinuous film into a continuous one. The impact toughness for half-size specimens has shown a significant drop from 126 J to 40 J when Ni content increased from 3% to 5%, while further addition of Ni partially recovered the toughness. Thorough investigation of fracture surface of weld metals, after impact test, elucidated that retained austenite was beneficial and has an effective role in reducing the detrimental effect of coalesced bainite that formed in the microstructure.     

Microstructure evolution and mechanical properties of GH984G alloy with different Ti/Al ratios during long-term thermal exposure

GH984G alloy is a low cost Ni–Fe based wrought superalloy designed for 700 °C advanced ultra-supercritical (A-USC) coal-fired power plants. In this paper, the microstructure evolution and tensile properties of GH984G alloy with different Ti/Al ratios during thermal exposure at different high temperatures are investigated. Detailed microstructure analysis reveals that the Microstructure of alloys with different Ti/Al ratios are similar after standard heat treatment, and the primary precipitates are γ′, MC, M₂₃C₆ and M₂B. However, η phase precipitates at grain boundary in the alloy with high Ti/Al ratio after thermal exposure at 750 °C for 570 h. By contrast, the microstructure stability of the alloy with lower Ti/Al ratio is excellent. There is no detrimental phase even if after thermal exposure at 750 °C for 5000 h in the alloy with lower Ti/Al ratio. γ′ coarsening plays a great role on the tensile strength, and the critical size range of γ′ could be defined as approximately 27–40 nm. The influence of η phase on tensile strength has close relationship with its volume fraction, the high volume fraction results in the decrease of tensile strength. The tensile strength of the alloy with lower Ti/Al ratio is obviously higher than the alloy with higher Ti/Al ratio and the yield strength has no obvious decrease during long-term thermal exposure at 700 °C. It is demonstrated that the thermal stability of microstructure and mechanical properties of GH984G alloy can be improved by moderately decreasing Ti/Al ratio to satisfy the requirement of A-USC plants.     

Effects of sleeve plunge depth on microstructures and mechanical properties of friction spot welded alclad 7B04-T74 aluminum alloy

Friction spot welding (FSpW) was applied to join the 7B04-T74 aluminum alloy successfully, and effects of sleeve plunge depth on weld appearance, microstructures and mechanical properties were investigated in detail. When the sleeve plunge depth was larger than 2 mm, a surface indentation with a depth of 0.2 mm should be applied in order to eliminate the defect of annular groove. The tensile shear properties of the joints were dependent on hook geometry, location of alclad layer, and hardness of stir zone (SZ). With increasing the sleeve plunge depth from 2 to 3.5 mm, the hook height increased, the alclad layer downward migrated further and the hardness of SZ decreased. The optimized FSpW joint was obtained when the sleeve plunge depth was 3 mm, and the corresponding tensile shear failure load was 11921 N. Two different failure modes, i.e. shear fracture mode and tensile-shear mixed fracture mode, were observed in the tensile shear tests.     

Effects of high-temperature annealing on the microstructure and properties of C/SiC–ZrB2 composites

C/SiC–ZrB₂ composites prepared via precursor infiltration and pyrolysis (PIP) were treated at high temperatures ranging from 1200 °C to 1800 °C. The mass loss rate of the composites increased with increasing annealing temperature and the flexural properties of the composites increased initially and then decreased reversely. Out of the four samples, the flexural strength and the modulus of the specimen treated at 1400 °C are maximal at 216.9 MPa and 35.5 GPa, suggesting the optimal annealing temperature for mechanical properties is 1400 °C. The fiber microstructure evolution during high-temperature annealing would not cause the decrease of fiber strength, and moderate annealing temperature enhanced the thermal stress whereas weakened the interface bonding, thus boosting the mechanical properties. However, once the annealing temperature exceeded 1600 °C, element diffusion and carbothermal reduction between ZrO₂ impurity and carbon fibers led to fiber erosion and a strong interface, jeopardizing the mechanical properties of the composites. The mass loss rate and linear recession rate of composites treated at 1800 °C are merely 0.0141 g/s and 0.0161 mm/s, respectively.     

Intermediate layer characterization and fracture behavior of laser-welded copper/aluminum metal joints

Copper and aluminum were welded using a continuous Nd:YAG laser, and the influence of the processing parameters on the intermediate layer was investigated. The intermediate layer along the interface was characterized, and the failure mechanism was identified. Four distinct zones with various intermetallic compounds and structures formed in the intermediate layer and determined the corresponding joint strength. Utilizing gradually increasing heat input produced different thicknesses for these four zones. A laser beam power of 1650 W and a welding speed of 95 mm/s were the optimized parameters. The thickness of the intermetallic compound γ₂-Cu₉Al₄ and the shear–tensile strength of the joint decreased with the increase of welding speed in the weld. The shear–tensile load of the dissimilar metal joint reached 539.52 N with the optimized parameters. Fracture during shear–tensile testing occurred in the zone with 20.08–54.65% Cu. It was concluded that eutectic and hypoeutectic structures containing a significant amount of θ-CuAl₂ led to a weak joint. The relationship between the mechanical properties and thickness of the different intermediate zones is thoroughly illustrated.     

Design and development of electronic- and micro-structures for multi-functional working electrodes in dye-sensitized solar cells

This paper outlines a new strategy to optimize the performance of electrodes in dye-sensitized solar cells (DSSCs), through the engineering of electronic structures in conjunction with the micro-structures of the devices. We propose a simple hydrolysis method for the fabrication of a family of quasi-core–shell TiO₂ (hydrolysis)/PbS composites for working electrodes. Measurements confirm a shift in absorption from the UV to visible range. We also measured cell performance, including short-circuit photocurrent, open-circuit photovoltage, and the power conversion efficiency (η) of DSSCs. The obtained η of DSSC (6.05%) with a TiO₂ (P-25)/TiO₂ (hydrolysis) + 0.005 M PbS electrode is substantially higher than that of the conventional DSSC (5.11%) with a TiO₂ (P-25) electrode, due to improved p–n junctions, light-scattering, and light absorption. Finally, the shell of TiO₂ (hydrolysis) protected the core of PbS from the corrosive effects of electrolytes, thereby prolonging the life span of the DSSC. This novel approach to electrode design could lead to advances in DSSC as well as other energy applications including photo-catalysis technology.