铁基形状记忆合金（待续）

简介形状记忆效应(SME)的基本概念和形状记忆合金的发展。评述了Fe-Mn-Si,Fe-Mn-Si-Cr-Ni,Fe-Ni-Co-Ti和Fe-Ni-C等系铁基形状记忆合金的生长背景,特性及其SME的机制。     

Cu-Ni-Si-Cr合金的时效析出与再结晶

研究了Cu-Ni-Si-Cr合金在时效过程中，析出与再结晶的交互作用及其对合金性能的影响。研究结果表明，形变使合金时效析出相更加细小、弥散，析出对再结晶的形核和长大过程产生阻碍作用。在再结晶的形成和长大过程中，析出相在晶界前沿快速粗化或重新溶解，并在再结晶区域中重新析出，导致更加弥散的析出相分布。     

Grain orientation effects on copper enrichment and oxygen generation during anodizing of an Al-1at.%Cu alloy

Anodizing of solid-solution Al-1at.%Cu alloy in ammonium pentaborate electrolyte is shown to develop two distinct types of amorphous film. On alloy grains of {1 0 0} orientation, the alumina film is of uniform thickness and relatively featureless. For other grains, the film is of non-uniform thickness and contains oxygen bubbles. In both cases, copper species are distributed throughout the film. Copper is enriched in the alloy to ∼5.8×10¹⁵ Cu atoms cm⁻² for bubble-free grains, with similar or slightly lower levels for other grains. Evidently, copper enrichment alone does not lead to generation of oxygen. Other factors suggested to be involved, each dependent upon grain orientation, are the structure of the enriched alloy layer, the cyclic nature of the oxidation of copper, and the generation of modulated film compositions.     

半固态金属流变成形模具失效与选材

半固态流变成形模具的研究是半固态成形技术的一个重要组成部分，目前还没有引起足够的重视。根据半固态流变成形模具的工作原理和黑色金属流变成形的工作条件，分析指出了其主要失效形式是热疲劳、熔蚀和变形，模具材料的关键性能指标是高温疲劳强度、抗氧化性以及较低的线膨胀系数等。通过对常用模具材料优缺点的分析，得出了以下结论：目前国内外还没有真正适合黑色金属半固态流变成形的模具材料，采用复合材料和表面处理技术是提高模具寿命的有效途径。     

中国压铸市场的机遇与挑战

评述了中国压铸市场的现状和发展前景。2002年，全国压铸件总产量为62．4万t，其中：铝合金压铸件产量为41．56万t，锌合金压铸件产量为19．82万t，镁合金压铸件产量为0．50万t，铜合金压铸件产量为0．53万t，分别占66．6％，31．87％，0．8％，0．8％；压铸机年销售量近1800台；2lD02年，全国模具总产值达到360亿元，其中压铸模约占10％；全国压铸行业中，外资企业、民营企业、乡镇企业以及私营企业合计已达到压铸企业总数的80％以上，特大型压铸企业集团开始涌现。     

7A04高强铝合金复合强韧化工艺

采用复合强韧化工艺，对7A04铝合金的组织和性能进行了研究。结果表明，通过熔体净化、晶粒细化、强化均匀化、锻造及分级固溶处理能明显改善和提高7A04高强铝合金的综合性能，而且可以大大减少均匀化处理的保温时间。     

稀有元素添加剂对TiC钢结硬质合金性能影响的研究

本文讨论了稀有元素添加剂对TiC钢结硬质含金性能的影响。试验表明：稀有元素对TiC钢结硬质合金的物理力学性能和烧结工艺性能有很大的影响．把少量稀有元素添加到TiC钢结硬质含金中可使合金中的脆性硬质点减少，孔隙度降低，从而明显地提高合金的横向断裂强度。同时合金的烧结温度区间也有所扩大。     

电磁搅拌技术在莱钢六号合金钢连铸机上的设计与应用

介绍结晶器电磁搅拌在矩形坯连铸机上的应用。采用内置式结晶器电磁搅拌后,连铸坯低倍组织大为改善,质量明显提高。     

Experimental investigations in powder mixed electric discharge machining of Ti–35Nb–7Ta–5Zrβ-titanium alloy

The present research is the first type of study in which the application of powder mixed electrical discharge machining (PMEDM) for the machining of β-phase titanium (β-Ti) alloy has been proposed. β-Ti alloys are new range of titanium alloys, which has a wide-spread application in dental, orthopedics, shape memory, and stents. The aim of the present study is to fabricate submicro- and nanoscale topography by PMEDM process to enhance the biocompatibility without affecting machining efficiency. The effect of Si powder concentration along with pulse current and duration on the surface and machining characteristics has been investigated. A significant decrease in surface crack density on the machined surface with 4 g/l Si powder concentration was observed. When β-Ti alloy was modified at 15 A pulse current, longer pulse interval with 8 g/l concentration of Si powder particles, the interconnected surface porosities with pore size 200–500 nm was observed. Moreover, at Si powder concentrations of 2 g/l and 4 g/l, the recast layer thickness is 8 µm and 2–3 µm, respectively. Elemental mapping analysis confirmed that PMEDM also generated carbides and oxides enriched surface, a favorable surface chemistry to enhance the biocompatibility of β-Ti alloy. Furthermore, PMEDM also enhances the machining performance by improving material removal rate and reducing tool wear rate.     

Tungsten wires and porous NiAl prepared through directional solidification and selective dissolution

The combination of directional solidification and selective dissolution was applied to fabricate tungsten (W) wires and porous NiAl matrix. A NiAl–W pseudobinary eutectic alloy with 1.5?at.% tungsten was directionally solidified in a Bridgman-type oven at 1700°C. Results confirmed that the relationships of the growth rate with the interfibrous spacing and diameter of W fibrous phases in the directionally solidified samples are in accordance with the Jackson and Hunt (J?H) model. Afterward, the NiAl matrix was selectively dissolved in an HCl:H₂O₂ solution to reveal W wires, which present various three-dimensional (3D) morphologies at different growth rates. The W fibrous phases in the NiAl–W alloy samples were then selectively removed with a mixed etchant of ammonium acetate to form a porous NiAl matrix at a constant potential. Dynamic corrosion curves revealed that etching W from the NiAl matrix was inhibited after 2–3?h. The porous structures of NiAl after removing W phases are linked to the 3D morphologies of W fibrous phases embedded in the NiAl matrix. The aspect ratio of W wires and the structures of porous NiAl can be adjusted by selecting the process parameters of this combined technology.